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Published in: Journal of Coatings Technology and Research 3/2020

10-03-2020

UV-curable fluorinated polycarbonate polyurethane with improved surface properties

Authors: Yan Yuan, Jihang Li, Yanmao Dong, Hui Miao

Published in: Journal of Coatings Technology and Research | Issue 3/2020

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Abstract

A series of UV-curable fluorinated polycarbonate polyurethanes (FCPUAs) were synthesized by modifying polycarbonate polyurethane with 2-(perfluorohexyl)ethanol (PFHE) and glycidyl methacrylate (GMA). The structures of FCPUAs were analyzed with 1H NMR and FTIR. Different contents of FCPUAs were blended into non-fluorinated polycarbonate polyurethane as fluorinated additives. The water and oil contact angles of the films were investigated by contact angle measurement, and the results indicated that an extremely low concentration of FCPUAs could produce a highly hydrophobic and oleophobic coating. The X-ray photoelectron spectroscopic analysis showed that the coating surface was rich in fluorinated species. Besides, the films containing FCPUAs also had great tensile strength, hardness and adhesion.

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Metadata
Title
UV-curable fluorinated polycarbonate polyurethane with improved surface properties
Authors
Yan Yuan
Jihang Li
Yanmao Dong
Hui Miao
Publication date
10-03-2020
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 3/2020
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-020-00329-0

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