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22-07-2019 | Original Research

Viscometric behavior of hydroxyethyl cellulose in aqueous solutions of some imidazolium ionic liquids

Authors: Abbas Mehrdad, Maryam Taleb-Abbasi

Published in: Cellulose | Issue 13-14/2019

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Abstract

In this work, viscosity of hydroxyethyl cellulose in aqueous solutions of ionic liquids, 1-butyl-3-methyl imidazolium bromide, 1-hexyl-3-methyl imidazolium bromide and 1-octyl-3-methyl imidazolium bromide were measured at temperature range of T = 288.15–308.15 K. Some hydrodynamic and thermodynamic parameters such as intrinsic viscosity, polymer–solvent interaction parameter and second virial coefficient were calculated using viscosity data. Obtained results reveal that thermodynamic quality of aqueous solutions of ionic liquids for hydroxyethyl cellulose decreases with increasing temperature and addition of ionic liquids. The flow activation energy was found from the linearization of Arrhenius equation and correlated in terms of polymer concentration. From sign of the initial slope of the activation energy versus polymer concentration at zero concentration, it is concluded that thermodynamic quality of aqueous solutions of ionic liquids are reduced by increasing temperature.

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Archer WL (1991) Determination of hansen solubility parameters for selected cellulose ether derivatives. Ind Eng Chem Res 30:2292–2298CrossRef

Asker D, Weiss J, McClements DJ (2009) Analysis of the interactions of a cationic surfactant (Lauric arginate) with an anionic biopolymer (Pectin): isothermal titration calorimetry, light scattering, and microelectrophoresis. Langmuir 25:116–122CrossRefPubMed

Blazkova A, Hrivikova J, Lapcik L (1990) Viscosity properties of aqueous solutions of hydroxyethylcellulose. Chem Pap 44:301

Brandrup J, Immergut EH, Grulke EA (1990) Polymer handbook. Wiley, Berlin

Brown RA, Pollet P, McKoon E, Eckert CA, Liotta CL, Jessop PG (2001) Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide. J Am Chem Soc 123:1254–1255CrossRefPubMed

Chen X, Chen J, You T, Wang K, Xu F (2015) Effects of polymorphs on dissolution of cellulose in NaOH/urea aqueous solution. Carbohyd Polym 125:85–91CrossRef

Desbrieres J (2002) Viscosity of semiflexible chitosan solutions: influence of concentration, temperature, and role of intermolecular interactions. Biomacromolecules 3:342–349CrossRefPubMed

Dondos A, Benoit H (1969) On the existence of two theta points for polymers in binary mixtures. J Polym Sci Part C Polym Lett 7:335–341CrossRef

Dondos A, Patterson D (1969) Intrinsic viscosities of polymers in mixed solvents. J Polym Sci Part A2 Polym Phys 7:209–217CrossRef

Eastman NC, Rose JK (1968) [In: Davidson RL, Sittings M (eds)] Hydroxyethyl cellulose in water soluble resins. Reinhold, New York, pp 63–90

Fang D, Cheng J, Gong K, Shi QR, Zhou XL, Liu ZL (2008) A green and novel procedure for the preparation of ionic liquid. J Fluor Chem 129:108–111CrossRef

Fang Z, Smith RL, Qi X (eds) (2014) Production of biofuels and chemicals with ionic liquids. Springer, Dordrecht

Ficke LE, Brennecke JF (2010) Interactions of ionic liquids and water. J Phys Chem B 121:599–609

Flory PJ, Fox TG (1951) Treatment of intrinsic viscosities. J Am Chem Soc 73:1904–1908CrossRef

Gericke M, Schlufter K, Liebert T, Heinze T, Budtova T (2009) Rheological properties of cellulose/ionic liquid solutions: from dilute to concentrated states. Biomacromolecules 10:1188–1194CrossRefPubMed

Inoue T (2009) Micelle formation of polyoxyethylene-type nonionic surfactants in bmimBF₄ studied by 1H NMR and dynamic light-scattering. J Colloid Interface Sci 337:240–246CrossRefPubMed

Inoue T, Aburai K, Sakai H, Abe M (2012) Surface adsorption and vesicle formation of dilauroylphosphatidylcholine in room temperature ionic liquids. J Colloid Interface Sci 377:262–268CrossRefPubMed

Kalashnikov VN (1994) Shear-rate dependent viscosity of dilute polymer solutions. J Rheol 38:1385–1403CrossRef

Kim BS, Fan TH, Lebedeva OV, Vinogradova OI (2005) Superswollen ultrasoft polyelectrolyte microcapsules. Macromolecules 38:8066–8070CrossRef

Leonov AP, Zheng J, Clogston JD, Stern ST, Patri AK, Wei A (2008) Detoxification of gold nanorods by treatment with polystyrenesulfonate. ACS Nano 2:2481–2488CrossRefPubMedPubMedCentral

Liao WX, Song J, Cheng BW, Mei J (2012) Dissolution of cellulose in [Amim] Cl/lithium salts solvents system. Adv Mater Res 535:1100–1103CrossRef

Liebert T (2010) Cellulose solvents-remarkable history, bright future. ACS Symp Ser 1033:3–54CrossRef

Liu J, Zhao M, Zhang Q, Sun D, Wei X, Zheng L (2011) Interaction between two homologues of cationic surface active ionic liquids and the PEO–PPO–PEO triblock copolymers in aqueous solutions. Colloid Polym Sci 289:1711–1718CrossRef

Liu J, Sun D, Wei X, Wang S, Yu L, Zheng L (2012a) Interaction between 1-dodecyl-3-methylimidazolium bromide and sodium carboxymethylcellulose in aqueous solution: effect of polymer concentration. J Dispers Sci Technol 33:5–14CrossRef

Liu J, Zhang Q, Huo Y, Zhao M, Sun D, Wei X (2012b) Interactions of two homologues of cationic surface active ionic liquids with sodium carboxymethylcellulose in aqueous solution. Colloid Polym Sci 290:1721–1730CrossRef

Mehrdad A, Shekaaei H, Niknam Z (2013) Effect of ionic liquid on the intrinsic viscosity of polyvinyl pyrrolidone in aqueous solutions. Fluid Phase Equilib 353:69–75CrossRef

Mehrdad A, Shekaaei H, Niknam Z (2014) Viscometric studies of interactions between ionic liquid 1-octyl-3-methyl-imidazolium bromide and polyvinyl pyrrolidone in aqueous solutions. J Chem Thermodyn 79:1–7CrossRef

Najdanovic-Visak V, Esperanca JM, Rebelo LP, Nunes da Ponte M, Guedes HJ, Seddon KR, de Sousa HC, Szydlowski J (2003) Pressure, isotope, and water co-solvent effects in liquid–liquid equilibria of (ionic liquid + alcohol) systems. J Phys Chem B 107:12797–12807CrossRef

Pinkert A, Marsh KN, Pang S, Staiger MP (2009) Ionic liquids and their interaction with cellulose. Chem Rev 109:6712–6728CrossRefPubMed

Reid JESJ, Gammons RJ, Slattery JM, Walker AJ, Shimizu S (2017) Interactions in water–ionic liquid mixtures: comparing protic and aprotic systems. J Phys Chem B 107:12797–12807

Rudaz C, Budtova T (2013) Rheological and hydrodynamic properties of cellulose acetate/ionic liquid solutions. Carbohyd Polym 92:1966–1971CrossRef

Sashina ES, Kashirskii DA, Busygin KN (2016) Dissolution of cellulose with pyridinium-based ionic liquids: effect of chemical structure and interaction mechanism. Cellul Chem Technol 50:199–211

Sowmiah S, Srinivasadesikan V, Tseng MC, Chu YH (2009) On the chemical stabilities of ionic liquids. Molecules 14:3780–3813CrossRefPubMedPubMedCentral

Stark A, Sellin M, Ondruschka B, Massonne K (2012) The effect of hydrogen bond acceptor properties of ionic liquids on their cellulose solubility. Sci China Chem 55:1663–1670CrossRef

Sun SF (2004) Physical chemistry of macromolecules: basic principles and issues. Wiley, BerlinCrossRef

Takegawa A, Murakami MA, Kaneko Y, Kadokawa JI (2010) Preparation of chitin/cellulose composite gels and films with ionic liquids. Carbohyd Polym 79:85–90CrossRef

Wang J, Tian Y, Zhao Y, Zhuo K (2003) A volumetric and viscosity study for the mixtures of 1-n-butyl-3-methylimidazolium tetrafluoroborate ionic liquid with acetonitrile, dichloromethane, 2-butanone and N,N-dimethylformamide. Green Chem 5:618–622CrossRef

Wang W, Li F, Yu J, Navard P, Budtova T (2015) Influence of substitution on the rheological properties and gelation of hydroxyethyl cellulose solution in NaOH–water solvent. Carbohyd Polym 124:85–89CrossRef

Wasserscheid P, Keim W (2000) Ionic liquids new solutions for transition metal catalysis. Angew Chem 39:3772–3789CrossRef

Wasserscheid P, Welton T (2008) Ionic liquids in synthesis. Wiley, Berlin

Widegren JA, Saurer EM, Marsh KN, Magee JW (2005) Electrolytic conductivity of four imidazolium-based room-temperature ionic liquids and the effect of a water impurity. J Chem Thermodyn 37:569–575CrossRef

Yang JT (1962) The viscosity of macromolecules in relation to molecular conformation. Adv Protein Chem 16:323–400CrossRef

Zhao Y, Gao S, Wang J, Tang J (2008) Aggregation of ionic liquids [C(n)mim]Br (n = 4, 6, 8, 10, 12) in D₂O: a NMR study. J Phys Chem B 112:2031–2039CrossRefPubMed

Title: Viscometric behavior of hydroxyethyl cellulose in aqueous solutions of some imidazolium ionic liquids
Authors: Abbas Mehrdad
Maryam Taleb-Abbasi
Publication date: 22-07-2019
Publisher: Springer Netherlands
Published in: Cellulose / Issue 13-14/2019
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02632-5

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