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Published in:
Introduction to Surface Instabilities and Wrinkle Formation Read chapter Read first chapter

2019 | OriginalPaper | Chapter

3. Wrinkles Obtained by Frontal Polymerization/Vitrification

Authors : C. M. González-Henríquez, M. A. Sarabia Vallejos, Juan Rodríguez-Hernández

Published in: Wrinkled Polymer Surfaces

Publisher: Springer International Publishing

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Abstract

Frontal polymerization (FP) or vitrification consists in the generation of a reaction front, in a localized sector of the material, that travels in a particular direction. Their remarkable flexibility permits to controllably polymerize materials with different molecular weights and variable chemical nature. One of the advantages of FP is that it is possible to generate thin layers of a polymerized material over an unpolymerized composite, being suitable for creating wrinkled patterns in homogenous polymeric materials. In this chapter, the main types of frontal polymerization are described, as well as several examples and applications which take advantage of this methodology to form wrinkled patterns of variable materials.

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previous chapter Strategies for the Fabrication of Wrinkled Polymer Surfaces
next chapter Control of Wrinkled Structures on Surface-Reformed Elastomers via Ion Beam Bombardment
Literature
1.
N.M. Chechilo, R.J. Khvilivitskii, N.S. Enikolopyan, Phenomenon of polymerization reaction spreading. Dokl. Akad. Nauk SSSR 204, 1180 (1972)
2.
J.A. Pojman, Frontal Polymerization, vol 4 (Elsevier B.V, Amsterdam, 2012)
3.
C. Nason, T. Roper, C. Hoyle, et al., UV-induced frontal polymerization of multifunctional (Meth)acrylates. Macromolecules 38, 5506–5512 (2005)CrossRef
4.
S.J. Ma, S.J. Mannino, N.J. Wagner, et al., Photodirected formation and control of wrinkles on a Thiol−ene elastomer. ACS Macro Lett. 2, 474–477 (2013)CrossRef
5.
M. Nania, F. Foglia, O.K. Matar, et al., Sub-100 nm wrinkling of polydimethylsiloxane by double frontal oxidation. Nanoscale 9, 2030–2037 (2017)CrossRef
6.
J.A. Pojman, V.M. Ilyashenko, A.M. Khan, Free-radical frontal polymerization: Self-propagating thermal reaction waves. J. Chem. Soc. Faraday Trans. 92, 2825 (1996)CrossRef
7.
Y.A. Chekanov, J.A. Pojman, Preparation of functionally gradient materials via frontal polymerization. J. Appl. Polym. Sci. 78, 2398–2404 (2000)CrossRef
8.
C. Nason, J.A. Pojman, C. Hoyle, The effect of a trithiol and inorganic fillers on the photo-induced thermal frontal polymerization of a triacrylate. J. Polym. Sci. Part A Polym. Chem. 46, 8091–8096 (2008)CrossRef
9.
M. Nania, O.K. Matar, J.T. Cabral, Frontal vitrification of PDMS using air plasma and consequences for surface wrinkling. Soft Matter 11, 3067–3075 (2015)CrossRef
10.
D. Bomze, P. Knaack, R. Liska, Successful radical induced cationic frontal polymerization of epoxy-based monomers by C–C labile compounds. Polym. Chem. 6, 8161–8167 (2015)CrossRef
11.
J.V. Crivello, U. Bulut, Dual photo- and thermally initiated cationic polymerization of epoxy monomers. J. Polym. Sci. Part A Polym. Chem. 44, 6750–6764 (2006)CrossRef
12.
J.V. Crivello, B. Falk, M.R. Zonca, Photoinduced cationic ring-opening frontal polymerizations of oxetanes and oxiranes. J. Polym. Sci. Part A Polym. Chem. 42, 1630–1646 (2004)CrossRef
13.
J.V. Crivello, Hybrid free radical/cationic frontal photopolymerizations. J. Polym. Sci. Part A Polym. Chem. 45, 4331–4340 (2007)CrossRef
14.
J. Rodríguez-Hernández, Wrinkled interfaces: Taking advantage of surface instabilities to pattern polymer surfaces. Prog. Polym. Sci. 42, 1–41 (2015)CrossRef
15.
M. He, X. Huang, Z. Zeng, et al., Photo-triggered redox frontal polymerization: A new tool for synthesizing thermally sensitive materials. J. Polym. Sci. Part A Polym. Chem 51, 4515–4521 (2013)
16.
C. Decker, The use of UV irradiation in polymerization. Polym. Int. 45, 133–141 (1998)CrossRef
17.
C. Decker, Light-induced crosslinking polymerization. Polym. Int. 51, 1141–1150 (2002)CrossRef
18.
J.T. Cabral, S.D. Hudson, C. Harrison, et al., Frontal photopolymerization for microfluidic applications. Langmuir 20, 10020–10029 (2004)CrossRef
19.
Y. Ohtsuka, Y. Koike, Studies on the light-focusing plastic rod 16: Mechanism of gradient-index formation in photocopolymerization of multiple monomer systems. Appl. Opt. 23, 1774 (1984)CrossRef
20.
Y. Koike, H. Hatanaka, Y. Ohtsuka, Studies on the light-focusing plastic rod 17: Plastic GRIN rod Lens prepared by photocopolymerization of a ternary monomer system. Appl. Opt. 23, 1779 (1984)CrossRef
21.
G. Terrones, A.J. Pearlstein, Effects of optical attenuation and consumption of a photobleaching initiator on local initiation rates in photopolymerizations. Macromolecules 34, 3195–3204 (2001)CrossRef
22.
Z.-F. Zhou, C. Yu, X.-Q. Wang, et al., Facile access to poly(NMA-Co-VCL) hydrogels via long range laser ignited frontal polymerization. J. Mater. Chem. A 1, 7326 (2013)CrossRef
23.
W.Q. Tang, L.H. Mao, Z.F. Zhou, et al., Facile synthesis of 4-vinylpyridine-based hydrogels via laser-ignited frontal polymerization and their performance on ion removal. Colloid Polym. Sci. 292, 2529–2537 (2014)CrossRef
24.
J. Zhou, H. Shao, J. Tu, et al., Available plasma-ignited frontal polymerization approach toward facile fabrication of functional polymer hydrogels. Chem. Mater. 22, 5653–5659 (2010)CrossRef
25.
C. Yu, J. Zhou, C.F. Wang, et al., Rapid synthesis of poly(HPA-Co-VeoVa 10) amphiphilic gels toward removal of toxic solvents via plasma-ignited frontal polymerization. J. Polym. Sci. Part A Polym. Chem. 49, 5217–5226 (2011)CrossRef
26.
H. Shao, C.F. Wang, S. Chen, et al., Fast fabrication of superabsorbent polyampholytic nanocomposite hydrogels via plasma-ignited frontal polymerization. J. Polym. Sci. Part A Polym. Chem. 52, 912–920 (2014)CrossRef
27.
Y. Gan, J. Yin, X. Jiang, Self-wrinkling induced by the photopolymerization and self-assembly of fluorinated polymer at air/liquid interface. J. Mater. Chem. A 2, 18574–18582 (2014)CrossRef
28.
D. Chandra, A.J. Crosby, Self-wrinkling of UV-cured polymer films. Adv. Mater. 23, 3441–3445 (2011)CrossRef
29.
T. Takeshima, W.Y. Liao, Y. Nagashima, et al., Photoresponsive surface wrinkle morphologies in liquid crystalline polymer films. Macromolecules 48, 6378–6384 (2015)CrossRef
30.
S.K. Park, Y.-J. Kwark, S. Nam, et al., A variation in wrinkle structures of UV-cured films with chemical structures of prepolymers. Mater. Lett. 199, 105–109 (2017)CrossRef
31.
A. del Campo, A. Nogales, T.A. Ezquerra, et al., Modification of poly(dimethylsiloxane) as a basis for surface wrinkle formation: Chemical and mechanical characterization. Polymer (Guildf). 98, 327–335 (2016)CrossRef
32.
L. Qi, C. Ruck, G. Spychalski, et al., Writing wrinkles on poly(dimethylsiloxane) (PDMS) by surface oxidation with a CO2 laser engraver. ACS Appl. Mater. Interfaces 10, 4295–4304 (2018)CrossRef
33.
J.M. Katzenstein, C.B. Kim, N.A. Prisco, et al., A photochemical approach to directing flow and stabilizing topography in polymer films. Macromolecules 47, 6804–6812 (2014)CrossRef
34.
H. Hou, F. Li, Z. Su, et al., Light-reversible hierarchical patterns by dynamic photo-dimerization induced wrinkles. J. Mater. Chem. C 5, 8765–8773 (2017)CrossRef
35.
S.J. Ma, N.J. Wagner, C.J. Kloxin, Rapid and controlled photo-induced thiol–ene wrinkle formation via flowcoating. Mater. Horizons, 5:514–520 (2018)CrossRef
36.
F.A. Bayley, J.L. Liao, P.N. Stavrinou, et al., Wavefront kinetics of plasma oxidation of polydimethylsiloxane: Limits for sub-μm wrinkling. Soft Matter 10, 1155–1166 (2014)CrossRef
37.
Y. Yang, X. Han, W. Ding, et al., Controlled free edge effects in surface wrinkling via combination of external straining and selective O2 plasma exposure. Langmuir 29, 7170–7177 (2013)CrossRef
38.
H.T. Evensen, H. Jiang, K.W. Gotrik, et al., Transformations in wrinkle patterns: Cooperation between nanoscale cross-linked surface layers and the submicrometer bulk in wafer-spun, plasma-treated polydimethylsiloxane. Nano Lett. 9, 2884–2890 (2009)CrossRef
39.
S. Nagashima, T. Hasebe, D. Tsuya, et al., Controlled formation of wrinkled diamond-like carbon (DLC) film on grooved poly(dimethylsiloxane) substrate. Diam. Relat. Mater. 22, 48–51 (2012)CrossRef
40.
M.-W. Moon, A. Vaziri, Surface modification of polymers using a multi-step plasma treatment. Scr. Mater. 60, 44–47 (2009)CrossRef
41.
Q. Li, X. Han, J. Hou, et al., Patterning poly(dimethylsiloxane) microspheres via combination of oxygen plasma exposure and solvent treatment. J. Phys. Chem. B 119, 13450–13461 (2015)CrossRef
Metadata
Title
Wrinkles Obtained by Frontal Polymerization/Vitrification
Authors
C. M. González-Henríquez
M. A. Sarabia Vallejos
Juan Rodríguez-Hernández
Copyright Year
2019
Book
Wrinkled Polymer Surfaces

Print ISBN: 978-3-030-05122-8

Electronic ISBN: 978-3-030-05123-5

Copyright Year: 2019

DOI
https://doi.org/10.1007/978-3-030-05123-5_3

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