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Published in:
Introduction to Surface Instabilities and Wrinkle Formation Read chapter Read first chapter

2019 | OriginalPaper | Chapter

11. Wrinkling Labyrinth Patterns on Elastomeric Janus Particles

Authors : Ana Catarina Trindade, Pedro Patrício, Paulo Ivo Teixeira, Maria Helena Godinho

Published in: Wrinkled Polymer Surfaces

Publisher: Springer International Publishing

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Abstract

Static and dynamic periodic patterns (stripes, wrinkles, and dots) are ubiquitous in nature, ranging from small wrinkles in soft materials (such as pumpkins, melons, nuts, and dehydrated fruits or even on animal’s skin) to much larger wavelength buckles (such as in lava flows or in geological structures, as in the desert sand).
In our work, we developed a simple method to fabricate Janus particles (films, spheres, and fibers) from a single urethane/urea elastomeric material, with two different surfaces: one smooth and another wrinkled. Wrinkles were generated by selectively UV-irradiating one-half of the elastomeric particles and permanently imprinted by swelling and drying the particles in an appropriate solvent. More, the particle surface can develop diverse wrinkling wavelengths depending on the swelling conditions.
We are able to fabricate monodisperse Janus particles from a single elastomeric material with two different hemispheres: one “aged” (wrinkled) and another “young” (flat). The hierarchical tuneable surface features produced open new horizons for application of these particles as, for example, components in biosensors.

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previous chapter Ripples and Wrinkles in Graphene: Beyond Continuum Mechanics
next chapter Wrinkled Surfaces Designed for Biorelated Applications
Literature
1.
2.
F. Schlesener, Colloidal Particles in Critical Fluids (Cuvillier Verlag Gottinger, Gottingen, 2004)
3.
R.S. Krishnan, On the depolarisation of Tyndall scattering in colloids. Proceedings of the Indian Academy of Sciences – Section A 1(10), 717–722 (1935)CrossRef
4.
G. Schmid, Clusters and Colloids: From Theory to Applications (VCH Verlagsgesellschaft mbH, Weinheim/New York, 2008)
5.
I. Cho, K.W. Lee, Morphology of latex particles formed by poly(methyl methacrylate)-seeded emulsion polymerization of styrene. J. Appl. Polym. Sci. 30(5), 1903–1926 (1985)CrossRef
6.
C. Casagrande, P. Fabre, E. Raphael, M. Veyssie, Janus Beads – Realization and Behavior at Water Oil Interfaces. Europhys. Lett. 9, 251–255 (1989)CrossRef
7.
C. Casagrande, M.J. Veyssie, Beads – realization and 1st observation of interfacial properties. C. R. Acad. Sci. (Paris) 306, 1423–1425 (1988)
8.
9.
A. Walther, A.H.E. Muller, Janus particles. Soft Matter 4, 663–668 (2008)CrossRef
10.
H.J. Hektor, K. Scholtmeijer, Hydrophobins: Proteins with potential. Curr. Opin. Biotechnol. 16(4), 434–439 (2005)CrossRef
11.
L. Hong, S. Jiang, S. Granick, Simple method to produce Janus colloidal particles in large quantity. Langmuir 22(23), 9495–9499 (2006)CrossRef
12.
S. Jiang, Q. Chen, M. Tripathy, E. Luijten, K.S. Schweizer, S. Granick, Janus particle synthesis and assembly. Adv. Mater. 22(10), 1060–1071 (2010)CrossRef
13.
F. Liang, B. Liu, Z. Cao, Z. Yang, Janus colloids toward interfacial engineering. Langmuir 34(14), 4123-4131 (2018)CrossRef
14.
A.-H. Lu, E.L. Salabas, F. Schuth, Magnetic nanoparticles: Synthesis, protection, functionalization, and application. Angew. Chem. Int. Ed. Engl. 46, 1222–1244 (2007)CrossRef
15.
J. Gao, H. Gu, B. Xu, Multifunctional magnetic nanoparticles: Design, synthesis, and biomedical applications. Acc. Chem. Res. 42(8), 1097–1107 (2009)CrossRef
16.
U. Jeong, X. Teng, Y. Wang, H. Yang, Y. Xia, Superparamagnetic colloids: Controlled synthesis and niche applications. Adv. Mater. 19(1), 33–60 (2006)CrossRef
17.
N. Zhao, M. Gao, Magnetic Janus particles prepared by a flame synthetic approach: Synthesis, characterizations and properties. Adv. Mater. 21(2), 184–187 (2009)CrossRef
18.
Y. Li, W.-B. Zhang, I.F. Hsieh, G. Zhang, Y. Cao, X. Li, C. Wesdemiotis, B. Lotz, H. Xiong, S.Z.D. Cheng, Breaking symmetry toward nonspherical Janus particles based on polyhedral oligomeric silsesquioxanes: Molecular design, “Click” synthesis, and hierarchical structure. J. Am. Chem. Soc. 133(28), 10712–10715 (2011)CrossRef
19.
X. Feng, R. Zhang, Y. Li, Y.-l. Hong, D. Guo, K. Lang, K.-Y. Wu, M. Huang, J. Mao, C. Wesdemiotis, Y. Nishiyama, W.-B. Zhang, T. Miyoshi, T. Li, S.Z.D. Cheng, Hierarchical self-organization of ABn Dendron-like molecules into a supramolecular lattice sequence. ACS Cent. Sci. 3(8), 860–867 (2017)CrossRef
20.
H. Wu, Y.-Q. Zhang, M.-B. Hu, L.-J. Ren, Y. Lin, W. Wang, Creating quasi two-dimensional cluster-assembled materials through self-assembly of a Janus Polyoxometalate-Silsesquioxane co-cluster. Langmuir 33(21), 5283–5290 (2017)CrossRef
21.
C. Ohm, N. Kapernaum, D. Nonnenmacher, F. Giesselmann, C. Serra, R. Zentel, Microfluidic synthesis of highly shape-anisotropic particles from liquid crystalline elastomers with defined director field configurations. J. Am. Chem. Soc. 133(14), 5305–5311 (2011)CrossRef
22.
T. Hessberger, L.B. Braun, F. Henrich, C. Muller, F. Giesselmann, C. Serra, R. Zentel, Co-flow microfluidic synthesis of liquid crystalline actuating Janus particles. J. Mater. Chem. C 4, 8778–8786 (2016)CrossRef
23.
V.B. Varma, R.G. Wu, Z.P. Wang, R.V. Ramanujan, Magnetic Janus particles synthesized using droplet micro-magnetofluidic techniques for protein detection. Lab Chip 17(20), 3514–3525 (2017)CrossRef
24.
P.-F. Jin, Y. Shao, G.-Z. Yin, S. Yang, J. He, P. Ni, W.-B. Zhang, Janus Polystyrene–Polydimethylsiloxane star polymers with a cubic core. Macromolecules 51(2), 419–427 (2018)CrossRef
25.
F. Wurm, A.F.M. Kilbinger, Polymeric Janus particles. Angew. Chem. Int. Ed. 48(45), 8412–8421 (2009)CrossRef
26.
S. Lone, I.W. Cheong, Fabrication of polymeric Janus particles by droplet microfluidics. RSC Adv. 4(26), 13322–13333 (2014)CrossRef
27.
H. Yabu, M. Kanahara, M. Shimomura, T. Arita, K. Harano, E. Nakamura, T. Higuchi, H. Jinnai, Polymer Janus particles containing block-copolymer stabilized magnetic nanoparticles. ACS Appl. Mater. Interfaces 5(8), 3262–3266 (2013)CrossRef
28.
Y. Yi, L. Sanchez, Y. Gao, Y. Yu, Janus particles for biological imaging and sensing. Analyst 141(12), 3526–3539 (2016)CrossRef
29.
G. Luo, L. Du, Y. Wang, Y. Lu, J. Xu, Controllable preparation of particles with microfluidics. Particuology 9(6), 545–558 (2011)CrossRef
30.
X.-T. Sun, M. Liu, Z.-R. Xu, Microfluidic fabrication of multifunctional particles and their analytical applications. Talanta 121, 163–177 (2014)CrossRef
31.
T. Nisisako, Recent advances in microfluidic production of Janus droplets and particles. Curr. Opin. Colloid Interface Sci. 25, 1–12 (2016)CrossRef
32.
Z. Nie, W. Li, M. Seo, S. Xu, E. Kumacheva, Janus and ternary particles generated by microfluidic synthesis: Design, synthesis, and self-assembly. J. Am. Chem. Soc. 128(29), 9408–9412 (2006)CrossRef
33.
K.-H. Roh, D.C. Martin, J. Lahann, Biphasic Janus particles with nanoscale anisotropy. Nat. Mater. 4, 759–763 (2005)CrossRef
34.
S. Rahmani, C.H. Villa, A.F. Dishman, M.E. Grabowski, D.C. Pan, H. Durmaz, A.C. Misra, L. Colón-Meléndez, M.J. Solomon, V.R. Muzykantov, J. Lahann, Long-circulating Janus nanoparticles made by electrohydrodynamic co-jetting for systemic drug delivery applications. J. Drug Target. 23(7–8), 750–758 (2015)CrossRef
35.
Z. Cao, Q. Bian, Y. Chen, F. Liang, G. Wang, Light-responsive janus-particle-based coatings for cell capture and release. ACS Macro Lett. 6(10), 1124–1128 (2017)CrossRef
36.
A. Walther, A.H.E. Müller, Janus particles: Synthesis, self-assembly, physical properties, and applications. Chem. Rev. 113(7), 5194–5261 (2013)CrossRef
37.
S. Sacanna, M. Korpics, K. Rodriguez, L. Colón-Meléndez, S.-H. Kim, D.J. Pine, G.-R. Yi, Shaping colloids for self-assembly. Nat. Commun. 4(1688), 1–6 (2013)
38.
J. Zhang, B.A. Grzybowski, S. Granick, Janus particle synthesis, assembly, and application. Langmuir 33, 6964–6977 (2017)CrossRef
39.
A. Walther, M. Hoffmann, H.E. Müller Axel, Emulsion polymerization using Janus particles as stabilizers. Angew. Chem. 120(4), 723–726 (2007)CrossRef
40.
X. Pei, Y. Tan, K. Xu, C. Liu, C. Lu, P. Wang, Pickering polymerization of styrene stabilized by starch-based nanospheres. Polym. Chem. 7(19), 3325–3333 (2016)CrossRef
41.
J. Tang, P.J. Quinlan, K.C. Tam, Stimuli-responsive Pickering emulsions: Recent advances and potential applications. Soft Matter 11(18), 3512–3529 (2015)CrossRef
42.
Y. Gao, Y. Yu, How half-coated Janus particles enter cells. J. Am. Chem. Soc. 135(51), 19091–19094 (2013)CrossRef
43.
F. Khan, M. Tanaka, Designing smart biomaterials for tissue engineering. Int. J. Mol. Sci. 19, 17 (2018)CrossRef
44.
J.A. Champion, Y.K. Katare, S. Mitragotri, Particle shape: A new design parameter for micro- and nanoscale drug delivery carriers. J. Control. Release 121(1), 3–9 (2007)CrossRef
45.
Y. Zhang, H.F. Chan, K.W. Leong, Advanced materials and processing for drug delivery: The past and the future. Adv. Drug Deliv. Rev. 65(1), 104–120 (2013)CrossRef
46.
H. Xie, Z.-G. She, S. Wang, G. Sharma, J.W. Smith, One-step fabrication of polymeric Janus nanoparticles for drug delivery. Langmuir 28(9), 4459–4463 (2012)CrossRef
47.
S. Hwang, J. Lahann, Differentially degradable Janus particles for controlled release applications. Macromol. Rapid Commun. 33(14), 1178–1183 (2012)CrossRef
48.
P. Johal, S. Chaudhary, Electronic paper technology. Int. J. Adv. Res. Sci. Eng. 2(9), 106-110 (2013)
49.
Y. Komazakia, H. Hirama, T. Torii, Electrically and magnetically dual-driven Janus particles for handwriting-enabled electronic paper. J. Appl. Phys. 117, 154506 (2015)CrossRef
50.
Y. Komazaki, T. Torii, Memory effect canceling and novel driving scheme of twisting-ball display via space-charge polarization. J. Soc. Inf. Disp. 25(5), 295–301 (2017)CrossRef
51.
X. Ma, A. Jannasch, U.-R. Albrecht, K. Hahn, A. Miguel-López, E. Schäffer, S. Sánchez, Enzyme-powered hollow mesoporous Janus nanomotors. Nano Lett. 15(10), 7043–7050 (2015)CrossRef
52.
P.S. Schattling, M.A. Ramos-Docampo, V. Salgueiriño, B. Städler, Double-fueled Janus swimmers with magnetotactic behavior. ACS Nano 11(4), 3973–3983 (2017)CrossRef
53.
M. Guix, S.M. Weiz, O.G. Schmidt, M. Medina-Sánchez, Self-propelled micro/nanoparticle motors. Part. Part. Syst. Charact. 35(2), 1700382 (2018)CrossRef
54.
J. Zhang, J. Yan, S. Granick, Directed self-assembly pathways of active colloidal clusters. Angew. Chem. Int. Ed. 55(17), 5166–5169 (2016)CrossRef
55.
J. Yan, M. Han, J. Zhang, C. Xu, E. Luijten, S. Granick, Reconfiguring active particles by electrostatic imbalance. Nat. Mater. 15, 1095–1099 (2016)CrossRef
56.
K.-H. Roh, M. Yoshida, J. Lahann, Water-stable biphasic nanocolloids with potential use as anisotropic imaging probes. Langmuir 23(10), 5683–5688 (2007)CrossRef
57.
J. Jiang, H. Gu, H. Shao, E. Devlin, G.C. Papaefthymiou, J.Y. Ying, Bifunctional Fe3O4–Ag heterodimer nanoparticles for two-photon fluorescence imaging and magnetic manipulation. Adv. Mater. 20, 4403–4407 (2008)CrossRef
58.
S.H. Hu, X. Gao, Nanocomposites with spatially separated functionalities for combined imaging and magnetolytic therapy. J. Am. Chem. Soc. 132, 7234–7237 (2010)CrossRef
59.
L.Y. Wu, B.M. Ross, S. Hong, L.P. Lee, Bioinspired nanocorals with decoupled cellular targeting and sensing functionality. Small 6, 503–507 (2010)CrossRef
60.
A. Kirillova, C. Schliebe, G. Stoychev, A. Jakob, H. Lang, A. Synytska, Hybrid hairy Janus particles decorated with metallic nanoparticles for catalytic applications. ACS Appl. Mater. Interfaces 7(38), 21218–21225 (2015)CrossRef
61.
J. Faria, M.P. Ruiz, D.E. Resasco, Phase-selective catalysis in emulsions stabilized by Janus silica-nanoparticles. Adv. Synth. Catal. 352(14–15), 2359–2364 (2010)CrossRef
62.
L. Baraban, D. Makarov, R. Streubel, I. Mönch, D. Grimm, S. Sanchez, O.G. Schmidt, Catalytic Janus motors on microfluidic chip: Deterministic motion for targeted cargo delivery. ACS Nano 6(4), 3383–3389 (2012)CrossRef
63.
S. Jiang, Q. Chen, M. Tripathy, E. Luijten, K.S. Schweizer, S. Steve Granick, Janus particle synthesis and assembly. Adv. Mater. 22, 1060–1071 (2010)CrossRef
64.
J.-W. Kim, R.J. Larsen, D.A. Weitz, Synthesis of nonspherical colloidal particles with anisotropic properties. J. Am. Chem. Soc. 128(44), 14374–14377 (2006)CrossRef
65.
J. Genzer, J. Groenewold, Soft matter with hard skin: From skin wrinkles to templating and material characterization. Soft Matter 2(4), 310–323 (2006)CrossRef
66.
Y. Xuan, X. Guo, Y. Cui, Crack-free controlled wrinkling of a bilayer film with a gradient interface. Soft Matter 8(37), 9603–9609 (2012)CrossRef
67.
T. Okayasu, H.L. Zhang, D.G. Bucknall, Spontaneous formation of ordered lateral patterns in polymer thin-film structures. Adv. Funct. Mater. 14(11), 1081–1088 (2004)CrossRef
68.
A.F. Miller, Materials science: Exploiting wrinkle formation. Science 317(5838), 605–606 (2007)CrossRef
69.
M.H. Godinho, A.C. Trindade, J.L. Figueirinhas, L.V. Melo, P. Brogueira, A.M. Deus, P.I.C. Teixeira, Tuneable micro-and nano-periodic structures in a free-standing flexible urethane/urea elastomer film. Eur. Phys. J. E Soft Matter 21, 319–330 (2006)CrossRef
70.
C. Zhao, M.N. de Pinho, Design of polypropylene oxide/polybutadiene bi-soft segment urethane/urea polymer for pervaporation membranes. Polymer 40(22), 6089–6097 (1999)CrossRef
71.
A.C. Trindade, M.H. Godinho, J.L. Figueirinhas, Shear induced finite orientational order in urethane/urea elastomers. Polymer 45(16), 5551–5555 (2004)CrossRef
72.
N. Bowden, S. Brittain, A.G. Evans, J.W. Hutchinson, G.M. Whitesides, Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer. Nature 393, 146–149 (1998)CrossRef
73.
A.C. Trindade, A.P.C. Almeida, J.P. Canejo, P. Patrício, P. Pieranski, M.H. Godinho, Elastomeric patterns probed by a nematic liquid crystal. Mol. Cryst. Liq. Cryst. 657(11), 136-146 (2017)CrossRef
74.
J. Yin, C. Lu, Hierarchical surface wrinkles directed by wrinkled templates. Soft Matter 8(24), 6528–6534 (2012)CrossRef
75.
L. Liu, M. Ren, W. Yang, Preparation of polymeric Janus particles by directional UV-directed reactions. Langmuir 25, 11048–11053 (2009)CrossRef
76.
X. Cai, Y. Wang, X. Wang, J. Ji, J. Hong, H. Pan, J. Chen, M. Xue, Fabrication of ultrafine soft-matter arrays by selective contact thermochemical reaction. Sci. Rep. 3, 1780 (2013)CrossRef
77.
J. Yin, Z. Cao, I. Sheinman, X. Chen, Stress-driven buckling patterns in spheroidal core/shell structures. Proc. Natl. Acad. Sci. 105(49), 19132–19135 (2008)CrossRef
78.
M. Li, N. Hakimi, R. Perez, S. Waldman, A. Kozinski Janusz, K. Hwang Dae, Microarchitecture for a three-dimensional wrinkled surface platform. Adv. Mater. 27(11), 1880–1886 (2015)CrossRef
79.
D. Terwagne, M. Brojan, M. Reis Pedro, Smart morphable surfaces for aerodynamic drag control. Adv. Mater. 26(38), 6608–6611 (2014)CrossRef
80.
B. Liu, W. Wei, X. Qu, Z. Yang, Janus colloids formed by biphasic grafting at a pickering emulsion interface. Angew. Chem. 120(21), 4037–4039 (2008)CrossRef
81.
Y. Yang, X. Han, W. Ding, S. Jiang, Y. Cao, C. Lu, Controlled free edge effects in surface wrinkling via combination of external straining and selective O2 plasma exposure. Langmuir 29(23), 7170–7177 (2013)CrossRef
82.
M. Watanabe, K. Mizukami, Well-ordered wrinkling patterns on chemically oxidized poly(dimethylsiloxane) surfaces. Macromolecules 45(17), 7128–7134 (2012)CrossRef
83.
J. Ji, M. Fuji, H. Watanabe, T. Shirai, Partially functionalized Janus ZnO spheres prepared by protecting mask techniques. Colloids Surf. A Physicochem. Eng. Asp. 393, 6–10 (2012)CrossRef
84.
S.-W. Choi, I.W. Cheong, J.-H. Kim, Y. Xia, Preparation of uniform microspheres using a simple fluidic device and their crystallization into close-packed lattices. Small 5, 454–459 (2009)CrossRef
85.
A.C. Trindade, J.P. Canejo, P. Patrício, P. Brogueira, P.I.C. Teixeira, M.H. Godinho, Hierarchical wrinkling on elastomeric Janus spheres. J. Mater. Chem. 22, 22044 (2012)CrossRef
86.
A.C. Trindade, J.P. Canejo, L.F.V. Pinto, P. Patrício, P. Brogueira, P.I.C. Teixeira, M.H. Godinho, Wrinkling labyrinth patterns on elastomeric janus particles. Macromolecules 44(7), 2220–2228 (2011)CrossRef
87.
G. Cao, X. Chen, C. Li, Z. Cao, lf- assembled gular and labyrinth buckling patterns of thin films on spherical subtes. Phys. Rev. Let. 100, 036102 (2008)CrossRef
88.
A.C. Trindade, J.P. Canejo, P.I.C. Teixeira, P. Patrício, M.H. Godinho, First curl, then wrinkle. Macromol. Rapid Commun. 34(20), 1618–1622 (2013)CrossRef
89.
P. Teixeira, A.C. Trindade, M.H. Godinho, J. Azeredo, R. Oliveira, J.G. Fonseca, Staphylococcus epidermidis adhesion on modified urea/urethane elastomers. J. Biomater. Sci. Polym. Ed. 17(1-2), 239-246 (2006)CrossRef
Metadata
Title
Wrinkling Labyrinth Patterns on Elastomeric Janus Particles
Authors
Ana Catarina Trindade
Pedro Patrício
Paulo Ivo Teixeira
Maria Helena Godinho
Copyright Year
2019
Book
Wrinkled Polymer Surfaces

Print ISBN: 978-3-030-05122-8

Electronic ISBN: 978-3-030-05123-5

Copyright Year: 2019

DOI
https://doi.org/10.1007/978-3-030-05123-5_11

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