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Journal of Materials Science

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12-01-2018 | Energy materials

ZnO/rGO/C composites derived from metal–organic framework as advanced anode materials for Li-ion and Na-ion batteries

Authors: Yuan Wang, Qijiu Deng, Weidong Xue, Zou Jian, Rui Zhao, Juanjuan Wang

Published in: Journal of Materials Science | Issue 9/2018

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Abstract

A novel ZnO/reduced graphene oxide/carbon (ZnO/rGO/C) composite is synthesized by pyrolysis of Zn-based metal–organic framework where graphene oxide and the glucose are imported as carbon sources. As a result, ZnO nanoparticles dispersing on a uniform reduced graphene sheet with a thin carbon layer construct a unique structure, which can prevent the aggregation of ZnO, enhance the electronic conductivity, and offer a robust scaffold during electrochemical processes. Compared to the bare ZnO and ZnO/rGO, the obtained ZnO/rGO/C composite can exhibit a high reversible capacity (~ 830 mA h g⁻¹ after 100 cycles, approximately 85% of theoretical capacity), and superior rate capability as anodes for Li-ion battery. Additionally, the electrochemical property of ZnO-based materials for Na-ion batteries is also proposed for the first time. It demonstrates that the as-synthesized ZnO/rGO/C composite also delivers an outperformance cyclic stability and considerable reversible capacity (~ 300 mA h g⁻¹ after 100 cycles). This simple methodology can be further extended to other energy storage applications.

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Title: ZnO/rGO/C composites derived from metal–organic framework as advanced anode materials for Li-ion and Na-ion batteries
Authors: Yuan Wang
Qijiu Deng
Weidong Xue
Zou Jian
Rui Zhao
Juanjuan Wang
Publication date: 12-01-2018
Publisher: Springer US
Published in: Journal of Materials Science / Issue 9/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-018-2003-3

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