nach oben

Erschienen in:

2021 | OriginalPaper | Buchkapitel

Enhanced Electrocatalytic Activity of Poly (Trans-2,3-Dimethylacrylic Acid) Modified Electrode for Hydrazine Sensing

verfasst von : Rajasree G. Krishnan, Beena Saraswathyamma, S. Gopika, P. Vibhooshann, Anjitha Aravind, M. G. Gopika

Erschienen in: Advances in Materials and Mechanical Engineering

Verlag: Springer Singapore

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In this research work, authors have used poly (trans-2,3-dimethylacrylic acid) modified electrode as a novel electrocatalyst for the electrochemical sensing of environmental pollutant and group 2B carcinogen hydrazine. The modification was attained using potentiodynamic electropolymerization in phosphate buffer medium. Morphological analysis of the electropolymerized electrode was conducted using field-emission scanning electron microscope, and the catalytic effect was studied using cyclic voltammetry. A much lowered overpotential of +0.252 V versus Ag/AgCl (1 M KCl) was obtained for the electrochemical oxidation of hydrazine at the poly (trans-2,3-dimethylacrylic acid) film casted electrode. Differential pulse voltammetry was applied to measure the hydrazine concentrations varying from 20 µM to 4 mM. Moreover, the sensor exhibited good selectivity, sensitivity, and repeatability. Practical usage of the sensor was tested in different kinds of water samples.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Synthesis and Stability of Al2O3/Water Nanofluids

Nächstes Kapitel Effect of Temperature on the Sliding Wear Behavior of HVOF Sprayed Al2O3 Composite Coating

Sudha V, Kumar SMS, Thangamuthu R (2020) NiCo2O4 nanorod: synthesis and electrochemical sensing of carcinogenic hydrazine. Inorg Chem Commun 107927

Pei Y, Hu M, Xia Y, Huang W, Li Z, Chen S (2020) Electrochemical preparation of Pt nanoparticles modified nanoporous gold electrode with highly rough surface for efficient determination of hydrazine. Sens Actuators B Chem 304:127416CrossRef

Lyon F (1994) IARC monographs on the evaluation of carcinogenic risks to humans. Some Ind Chem 60:389–433

Taei M, Salavati H, Banitaba SH, Shahidi L (2017) A novel hydrazine electrochemical sensor based on gold nanoparticles decorated redox-active 2-amino-4H-chromene-3-carbonitrile. IEEE Sens J 17:7325–7331CrossRef

George GD, Stewart JT (1990) HPLC determination of trace hydrazine levels in phenelzine sulfate drug substance. Anal Lett 23:1417–1429CrossRef

Kosyakov D, Amosov A, Ul’yanovskii N, Ladesov A, Khabarov YG, Shpigun O (2017) Spectrophotometric determination of hydrazine, methylhydrazine, and 1, 1-dimethylhydrazine with preliminary derivatization by 5-nitro-2-furaldehyde. J Anal Chem 72:171–177

Cao S, Zheng S, Pang H (2020) Ultrathin nanosheet-assembled accordion-like Ni-MOF for hydrazine hydrate amperometric sensing. Microchim Acta 187:1–9CrossRef

Santhy A, Beena S, Namboothiri UK, Anupriya S, Sreeranjini C (2020) A pencil graphite electrode modified with poly nicotinamide as a framework for the electrochemical detection of propranolol hydrochloride. In: IOP conference series: materials science and engineering. IOP Publishing, p 012125

Krishnan RG, Greeshma D, Morris DS, Rameshan SS, Beena S (2019) Morphological studies of disposable graphite and its effective utilization for vitamin B12 analysis in pharmaceutical formulations. Mater Today Proc 18:3314–3320CrossRef

10.

Krishnan RG, Rejithamol R, Saraswathyamma B (2020) Non-enzymatic electrochemical sensor for the simultaneous determination of adenosine, adenine and uric acid in whole blood and urine. Microchem J 104745

11.

Krishnan RG, Saraswathyamma B, Raj TA, Gopika M (2020) Poly (riboflavin) modified pencil graphite for the simultaneous electrochemical determination of serotonin and dopamine. In: AIP conference proceedings. AIP Publishing LLC, p 020007

12.

Golabi S, Zare H, Hamzehloo M (2001) Electrocatalytic oxidation of hydrazine at a pyrocatechol violet (PCV) chemically modified electrode. Microchem J 69:13–23CrossRef

13.

Krishnan RG, Saraswathyamma B (2020) Disposable electrochemical sensor for coumarin induced milk toxicity in raw milk samples. Measurement 108709

14.

Habibi E (2019) Mesoporous Pd| β-SiCNW-nC based home made screen printed electrode for high sensitive detection of hydrazine. Microchem J 149:104004CrossRef

15.

Tan C, Xu X, Wang F, Li Z, Liu J, Ji J (2013) Carbon black supported ultra-high loading silver nanoparticle catalyst for electro-oxidation and determination of hydrazine. Science China Chem 56:911–916CrossRef

16.

Babu KJ, Zahoor A, Nahm KS, Aziz MA, Vengadesh P, Kumar GG (2016) Manganese dioxide–vulcan carbon@ silver nanocomposites for the application of highly sensitive and selective hydrazine sensors. New J Chem 40:7711–7720CrossRef

17.

Vijeth H, Ashokkumar S, Yesappa L, Vandana M, Devendrappa H (2020) Camphor sulfonic acid surfactant assisted polythiophene nanocomposite for efficient electrochemical hydrazine sensor. Mater Res Express 6:125375CrossRef

18.

Chen W, Wang H, Tang H, Yang C, Guan X, Li Y (2019) Amperometric sensing of hydrazine by using single gold nanopore electrodes filled with Prussian blue and coated with polypyrrole and carbon dots. Microchim Acta 186:350CrossRef

19.

Kaladevi G, Wilson P, Pandian K (2020) Silver nanoparticle–decorated PANI/reduced graphene oxide for sensing of hydrazine in water and inhibition studies on microorganism, Ionics 1–11

20.

Beduk T, Bihar E, Surya SG, Castillo AN, Inal S, Salama KN (2020) A paper-based inkjet-printed PEDOT: PSS/ZnO sol-gel hydrazine sensor. Sens Actuators B Chem 306:127539CrossRef

21.

Haque AMJ, Kumar S, Del Río JS, Cho YK (2020) Highly sensitive detection of hydrazine by a disposable, poly (tannic acid)-coated carbon electrode. Biosens Bioelectron 150:111927CrossRef

Titel: Enhanced Electrocatalytic Activity of Poly (Trans-2,3-Dimethylacrylic Acid) Modified Electrode for Hydrazine Sensing
verfasst von: Rajasree G. Krishnan
Beena Saraswathyamma
S. Gopika
P. Vibhooshann
Anjitha Aravind
M. G. Gopika
Verlag: Springer Singapore
Buch: Advances in Materials and Mechanical Engineering
Print ISBN: 978-981-16-0672-4

Electronic ISBN: 978-981-16-0673-1

Copyright-Jahr: 2021
DOI: https://doi.org/10.1007/978-981-16-0673-1_2

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht