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Cellulose

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06.03.2019 | Original Research

Enhanced heavy metal adsorption ability of lignocellulosic hydrogel adsorbents by the structural support effect of lignin

verfasst von: Xiaoping Shen, Yanjun Xie, Qingwen Wang, Xin Yi, Julia L. Shamshina, Robin D. Rogers

Erschienen in: Cellulose | Ausgabe 6/2019

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Abstract

Cellulose beads possess some adsorption capacities for heavy metal ions, but the effect of lignin remaining in the beads on the adsorption behavior is not clear yet. In this study, lignocellulosic and cellulosic hydrogel beads were prepared by ionic liquid (IL) dissolution and reconstitution in water and further functionalization through magnetization and carboxymethylation. Compared to pure cellulosic beads made from Kraft pulp and microcrystalline cellulose, the presence of lignin in the lignocellulosic beads from IL-extracted cellulose-rich material (CRM) helped support the porous structure, leading to a higher hydroxyl number and porosity, and thus higher efficacy in magnetization and carboxymethylation. CRM beads, therefore, exhibited greater Cu²⁺ and Pb²⁺ uptake than the cellulosic beads both before and after modification. However, excessive lignin in the beads prepared directly from poplar wood powder caused negative effects on the adsorption capacity due to agglomeration and occlusion of the adsorptive sites.

Graphical abstract

Vorheriger Artikel Synthesis, microstructure transformations, and long-distance inductive effect of poly(acrylethyltrimethylammonium chloride) cotton with super-high adsorption ability for purifying dyeing wastewater

Nächster Artikel Fabrication of hydrophobic cellulosic materials via gas–solid silylation reaction for oil/water separation

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Titel: Enhanced heavy metal adsorption ability of lignocellulosic hydrogel adsorbents by the structural support effect of lignin
verfasst von: Xiaoping Shen
Yanjun Xie
Qingwen Wang
Xin Yi
Julia L. Shamshina
Robin D. Rogers
Publikationsdatum: 06.03.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 6/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02328-w

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