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17.05.2017 | Original Paper

Ensemble evaluation of polydisperse nanocellulose dimensions: rheology, electron microscopy, X-ray scattering and turbidimetry

verfasst von: Reina Tanaka, Tomoko Kuribayashi, Yu Ogawa, Tsuguyuki Saito, Akira Isogai, Yoshiharu Nishiyama

Erschienen in: Cellulose | Ausgabe 8/2017

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Abstract

Six types of CNCs with different sizes were prepared from tunicins by sulfuric acid hydrolysis and subsequent sonication in water. The size distributions of CNCs were comprehensively evaluated by turbidimetry, small angle X-ray scattering, and microscopy to predict their intrinsic viscosities. Experimental intrinsic viscosities [η] of the CNC dispersions were evaluated by shear viscosity measurement, and then compared with their theoretical [η] values based on theories for rotational motions of rigid rods. The experimental [η] values for the straight CNCs were in good agreement with their theoretical [η] values, irrespective of the size and distributions. On the other hand, the experimental [η] value of the kinked CNC was higher than the theoretical [η] value, in agreement with a theoretical calculation giving higher intrinsic viscosities for bent fibers.

Vorheriger Artikel Green and combinational method towards clickable alkynylated cellulose fibers (ACFs)

Nächster Artikel Facile one-step extraction and oxidative carboxylation of cellulose nanocrystals through hydrothermal reaction by using mixed inorganic acids

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Azizi Samir MAS, Alloin F, Dufresne A (2005) Review of recent research into cellulosic whiskers, their properties and their application in nanocomposite field. Biomacromol 6(2):612–626CrossRef

Boluk Y, Lahiji R, Zhao L, McDermott MT (2011) Suspension viscosities and shape parameter of cellulose nanocrystals (CNC). Colloids Surf A 377(1–3):297–303CrossRef

Broersma S (1960) Rotational diffusion constant of a cylindrical particle. J Chem Phys 32(6):1626–1631CrossRef

Carr ME Jr, Hermans J (1978) Size and density of fibrin fibers from turbidity. Macromolecules 11(1):46–50CrossRef

de Souza Lima M, Wong J, Paillet M, Borsali R, Pecora R (2003) Translational and rotational dynamics of rodlike cellulose whiskers. Langmuir 19(1):24–29CrossRef

Doi M, Edwards SF (1986) The theory of polymer dynamics. Oxford University Press, New York

Dong XM, Gray DG (1997) Effect of counterions on ordered phase formation in suspensions of charged rodlike cellulose crystallites. Langmuir 13(8):2404–2409CrossRef

Dong XM, Kimura T, Revol J-F, Gray DG (1996) Effects of ionic strength on the isotropic–chiral nematic phase transition of suspensions of cellulose crystallites. Langmuir 12(8):2076–2082CrossRef

Dong XM, Revol J-F, Gray DG (1998) Effect of microcrystallite preparation conditions on the formation of colloid crystals of cellulose. Cellulose 5(1):19–32CrossRef

Eichhorn SJ (2011) Cellulose nanowhiskers: promising materials for advanced applications. Soft Matter 7(2):303–315CrossRef

Elazzouzi-Hafraoui S, Nishiyama Y, Putaux J-L, Heux L, Dubreuil F, Rochas C (2007) The shape and size distribution of crystalline nanoparticles prepared by acid hydrolysis of native cellulose. Biomacromol 9(1):57–65CrossRef

Favier V, Chanzy H, Cavaille J (1995) Polymer nanocomposites reinforced by cellulose whiskers. Macromolecules 28(18):6365–6367CrossRef

Fedors RF (1979) An equation suitable for describing the viscosity of dilute to moderately concentrated polymer solutions. Polymer 20(2):225–228CrossRef

Furuta T, Yamahara E, Konishi T, Ise N (1996) Ordering in aqueous cellulose hydrolysate dispersions: an ultra-small-angle X-ray scattering study. Macromolecules 29(27):8994–8995CrossRef

Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110(6):3479–3500CrossRef

Helbert W, Nishiyama Y, Okano T, Sugiyama J (1998) Molecular imaging ofhalocynthia papillosacellulose. J Struct Biol 124(1):42–50CrossRef

Hirai A, Inui O, Horii F, Tsuji M (2008) Phase separation behavior in aqueous suspensions of bacterial cellulose nanocrystals prepared by sulfuric acid treatment. Langmuir 25(1):497–502CrossRef

Iwamoto S, Kai W, Isogai A, Iwata T (2009) Elastic modulus of single cellulose microfibrils from tunicate measured by atomic force microscopy. Biomacromol 10(9):2571–2576CrossRef

Marchessault R, Morehead F, Koch MJ (1961) Some hydrodynamic properties of neutral suspensions of cellulose crystallites as related to size and shape. J Colloid Sci 16(4):327–344CrossRef

Parra-Vasquez ANG, Stepanek I, Davis VA, Moore VC, Haroz EH, Shaver J, Hauge RH, Smalley RE, Pasquali M (2007) Simple length determination of single-walled carbon nanotubes by viscosity measurements in dilute suspensions. Macromolecules 40(11):4043–4047CrossRef

Revol J-F, Bradford H, Giasson J, Marchessault R, Gray D (1992) Helicoidal self-ordering of cellulose microfibrils in aqueous suspension. Int J Biol Macromol 14(3):170–172CrossRef

Saito T, Kuramae R, Wohlert J, Berglund LA, Isogai A (2013) An ultrastrong nanofibrillar biomaterial: the strength of single cellulose nanofibrils revealed via sonication-induced fragmentation. Biomacromol 14(1):248–253CrossRef

Sakurada I, Nukushina Y, Ito T (1962) Experimental determination of the elastic modulus of crystalline regions in oriented polymers. J Polym Sci 57(165):651–660CrossRef

Shimizu M, Saito T, Nishiyama Y, Iwamoto S, Yano H, Isogai A, Endo T (2016) Fast and robust nanocellulose width estimation using turbidimetry. Macromol Rapid Commun 37:1581–1586CrossRef

Šturcová A, Davies GR, Eichhorn SJ (2005) Elastic modulus and stress-transfer properties of tunicate cellulose whiskers. Biomacromol 6(2):1055–1061CrossRef

Sugiyama J, Vuong R, Chanzy H (1991) Electron diffraction study on the two crystalline phases occurring in native cellulose from an algal cell wall. Macromolecules 24(14):4168–4175CrossRef

Tanaka R, Saito T, Ishii D, Isogai A (2014) Determination of nanocellulose fibril length by shear viscosity measurement. Cellulose 21(3):1581–1589CrossRef

Tanaka R, Saito T, Hondo H, Isogai A (2015) Influence of flexibility and dimensions of nanocelluloses on the flow properties of their aqueous dispersions. Biomacromol 16(7):2127–2131CrossRef

Tanaka R, Saito T, Hänninen T, Ono Y, Hakalahti M, Tammelin T, Isogai A (2016) Viscoelastic properties of core–shell-structured, hemicellulose-rich nanofibrillated cellulose in dispersion and wet-film states. Biomacromol 17(6):2104–2111CrossRef

Terech P, Chazeau L, Cavaille J (1999) A small-angle scattering study of cellulose whiskers in aqueous suspensions. Macromolecules 32(6):1872–1875CrossRef

Tozzi EJ, Klingenberg DJ, Scott CT (2008) Correlation of fiber shape measures with dilute suspension properties. Nord Pulp Pap Res J 23(4):369–373CrossRef

Wierenga AM, Philipse AP (1996) Low-shear viscosities of dilute dispersions of colloidal rodlike silica particles in cyclohexane. J Colloid Interface Sci 180(2):360–370CrossRef

Wohlert J, Bergenstråhle-Wohlert M, Berglund LA (2012) Deformation of cellulose nanocrystals: entropy, internal energy and temperature dependence. Cellulose 19(6):1821–1836CrossRef

Titel: Ensemble evaluation of polydisperse nanocellulose dimensions: rheology, electron microscopy, X-ray scattering and turbidimetry
verfasst von: Reina Tanaka
Tomoko Kuribayashi
Yu Ogawa
Tsuguyuki Saito
Akira Isogai
Yoshiharu Nishiyama
Publikationsdatum: 17.05.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 8/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1334-6

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