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Erschienen in:
2001 | OriginalPaper | Buchkapitel
Ensembles, Partition Functions, and Thermodynamic Functions
verfasst von : Dr. Andrei Koudriavtsev, Dr. Reginald F. Jameson, Prof. Dr. Dipl.-Ing. Ing. Wolfgang Linert
Erschienen in: The Law of Mass Action
Verlag: Springer Berlin Heidelberg
Enthalten in: Professional Book Archive
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Maxwell — Boltzmann statistics, with corrections for the quantum character of energy changes and the indistinguishable nature of molecules, works perfectly well when we consider systems of non-interacting molecules. If particles are interacting with each other, then the description of such systems by Maxwell — Boltzmann statistics becomes extremely difficult if not impossible. For example, consider a system of positive and negative ions interacting in pairs. The potential energy of such a system is: 2.1$$ U = \sum\limits_i {\sum\limits_j {\frac{{e_i e_j }} {{2r_{ij} }}} } $$