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Colloid and Polymer Science

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01.08.2013 | Original Contribution

Evolution of nanopolar phases, interfaces, and increased dielectric energy storage capacity in photoinitiated cross-linked poly(vinylidene fluoride)-based copolymers

verfasst von: Xiang-Zhong Chen, Zhao-Xi Cheng, Lu Liu, Xiao-Di Yang, Qun-Dong Shen, Wen-Bing Hu, Hai-Tao Li

Erschienen in: Colloid and Polymer Science | Ausgabe 8/2013

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Abstract

Photoinitiated cross-linking of poly(vinylidene fluoride-co-chlorotrifluoroethylene) can offer a significant increase in electric energy storage capacity. This improvement is related to the structural changes in the copolymer crystals brought by cross-linking. Cross-linking favors formation of polar crystalline phase, drastic reduction of spherulite sizes, and increase in copolymer inner interface area. This copolymer case demonstrates the greatly enhanced energy storage behavior, including increased discharge energy density at reduced field strength, and improved capacitor efficiency at relatively high degree of cross-linking, which may facilitate a better design for polymer dielectric materials in their application of high energy density capacitors.

Vorheriger Artikel Stability, rheological, magnetorheological and volumetric characterizations of polymer based magnetic nanofluids

Nächster Artikel Acidic ionic liquids catalyst in homo and graft polymerization of ε-caprolactone

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Titel: Evolution of nanopolar phases, interfaces, and increased dielectric energy storage capacity in photoinitiated cross-linked poly(vinylidene fluoride)-based copolymers
verfasst von: Xiang-Zhong Chen
Zhao-Xi Cheng
Lu Liu
Xiao-Di Yang
Qun-Dong Shen
Wen-Bing Hu
Hai-Tao Li
Publikationsdatum: 01.08.2013
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 8/2013
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-013-2939-4

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