Skip to main content
Erschienen in: Journal of Coatings Technology and Research 1/2017

04.11.2016

Fabrication, and characterization of polydimethylsiloxane/glycidol-grafted gelatin film

verfasst von: Lei Yue, Jing Li, Wei-Yue Zhu, Jing Xu, Tian-Duo Li

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 1/2017

Einloggen

Aktivieren Sie unsere intelligente Suche um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Polydimethylsiloxane or glycidol-grafted gelatin films with excellent flexibility and strong hydrophobicity were fabricated by mono epoxy-terminated polydimethylsiloxane (PDMS-E)-grafted gelatin (PGG) and glycidol-grafted gelatin (GGG). Mixed reactive aqueous solutions of PGG and GGG were poured into a Teflon mold. The solutions were dried slowly and eight films were obtained with a thickness of around 200 μm, including gelatin film, PGG film, GGG film, and resulting films at gelatin/PGG/GGG ratios of 2.5:0.5:1.0, 5.0:1.0:1.0, 7.5:1.5:1.0, 10.0:2.0:1.0, and 5.0:1.0:3.0 (weight percentage). The microstructures of these films were confirmed by scanning electron microscopy, attenuated total reflection-Fourier transform infrared spectroscopy, atomic force microscopy, and small-angle X-ray scattering. The influence of the gelatin/PGG/GGG ratios was studied with respect to the hydrophobicity and the mechanical property of the films. The results showed that the contact angle of gelatin-based film increased from 76° to 126° after blending with gelatin, PGG, and GGG at 5.0:1.0:1.0 (weight percentage). Moreover, the elongation at break value of the film reached 3400%. The resulting films showed high flexibility and strong hydrophobicity, which is promising for high-performance coatings.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Zurück zum Zitat Kester, JJ, Fennema, O, Kester, JJ, “Edible Films and Coatings: A Review.” Food Technol., 40 47–59 (1986) Kester, JJ, Fennema, O, Kester, JJ, “Edible Films and Coatings: A Review.” Food Technol., 40 47–59 (1986)
2.
Zurück zum Zitat Miller, KS, Krochta, JM, “Oxygen and Aroma Barrier Properties of Edible Films: A Review.” Trends Food Sci. Technol., 8 228–237 (1997)CrossRef Miller, KS, Krochta, JM, “Oxygen and Aroma Barrier Properties of Edible Films: A Review.” Trends Food Sci. Technol., 8 228–237 (1997)CrossRef
3.
Zurück zum Zitat Cosgrove, T, Hone, JHE, “A Small-angle Neutron Scattering Study of the Structure of Gelatin at the Surface of Polystyrene Latex Particles.” Langmuir, 14 5376–5382 (1998)CrossRef Cosgrove, T, Hone, JHE, “A Small-angle Neutron Scattering Study of the Structure of Gelatin at the Surface of Polystyrene Latex Particles.” Langmuir, 14 5376–5382 (1998)CrossRef
4.
Zurück zum Zitat Ward, AG, Courts, A, The Science and Technology of Gelatin. Academic Press, London (1977) Ward, AG, Courts, A, The Science and Technology of Gelatin. Academic Press, London (1977)
5.
Zurück zum Zitat Liang, G, Colby, RH, Lusignan, CP, Howe, AM, “Physical Gelation of Gelatin Studied With Rheo-Optics.” Macromolecules, 36 10009–10020 (2003)CrossRef Liang, G, Colby, RH, Lusignan, CP, Howe, AM, “Physical Gelation of Gelatin Studied With Rheo-Optics.” Macromolecules, 36 10009–10020 (2003)CrossRef
6.
Zurück zum Zitat Veis, A, The Macromolecular Chemistry of Gelatin. Academic Press, New York (1964) Veis, A, The Macromolecular Chemistry of Gelatin. Academic Press, New York (1964)
7.
Zurück zum Zitat Hastings, GW, Ducheyne, P, Macromolecular Biomaterials. CRC Press, Boca Raton (1984) Hastings, GW, Ducheyne, P, Macromolecular Biomaterials. CRC Press, Boca Raton (1984)
8.
Zurück zum Zitat Esposito, E, Cortesi, R, Nastruzzi, C, “Gelatin Microspheres: Influence of Preparation Parameters and Thermal Treatment on Chemico-Physical and Biopharmaceutical Properties.” Biomaterials, 17 2009–2020 (1996)CrossRef Esposito, E, Cortesi, R, Nastruzzi, C, “Gelatin Microspheres: Influence of Preparation Parameters and Thermal Treatment on Chemico-Physical and Biopharmaceutical Properties.” Biomaterials, 17 2009–2020 (1996)CrossRef
9.
Zurück zum Zitat Arvanitoyannis, I, Psomiadou, E, Nakayama, A, Aiba, S, Yamamoto, N, “Edible Films Made from Gelatin, Soluble Starch and Polyols, Part 3.” Food Chem., 60 593–604 (1997)CrossRef Arvanitoyannis, I, Psomiadou, E, Nakayama, A, Aiba, S, Yamamoto, N, “Edible Films Made from Gelatin, Soluble Starch and Polyols, Part 3.” Food Chem., 60 593–604 (1997)CrossRef
10.
Zurück zum Zitat Sobral, PJA, Menegalli, FC, Hubinger, MD, Roques, MA, “Mechanical, Water Vapor Barrier and Thermal Properties of Gelatinbased Edible Films.” Food Hydrocoll., 15 423–432 (2001)CrossRef Sobral, PJA, Menegalli, FC, Hubinger, MD, Roques, MA, “Mechanical, Water Vapor Barrier and Thermal Properties of Gelatinbased Edible Films.” Food Hydrocoll., 15 423–432 (2001)CrossRef
11.
Zurück zum Zitat Yakimets, I, Wellner, N, Smith, AC, Wilson, RH, Farhat, IJM, “Mechanical Properties with Respect to Water Content of Gelatin Films in Glassy State.” Polymer, 46 12577–12585 (2005)CrossRef Yakimets, I, Wellner, N, Smith, AC, Wilson, RH, Farhat, IJM, “Mechanical Properties with Respect to Water Content of Gelatin Films in Glassy State.” Polymer, 46 12577–12585 (2005)CrossRef
12.
Zurück zum Zitat Dominique, HS, Madeleine, D, “Gelatin Hydrogels Cross-Linked with Bisvinyl Sulfonemethyl. 2. The Physical and Chemical Networks.” Langmuir, 22 8516–8522 (2006)CrossRef Dominique, HS, Madeleine, D, “Gelatin Hydrogels Cross-Linked with Bisvinyl Sulfonemethyl. 2. The Physical and Chemical Networks.” Langmuir, 22 8516–8522 (2006)CrossRef
13.
Zurück zum Zitat Lusiana, K, Qiao, GG, Zhang, XQ, “Chemical Modification of Wheat Protein-Based Natural Polymers: Grafting and Cross-Linking Reactions with Poly(ethylene oxide) Diglycidyl Ether and Ethyl Diamine.” Biomacromolecules, 8 2909–2915 (2007)CrossRef Lusiana, K, Qiao, GG, Zhang, XQ, “Chemical Modification of Wheat Protein-Based Natural Polymers: Grafting and Cross-Linking Reactions with Poly(ethylene oxide) Diglycidyl Ether and Ethyl Diamine.” Biomacromolecules, 8 2909–2915 (2007)CrossRef
14.
Zurück zum Zitat Farris, S, Song, JH, Huang, QR, “Alternative Reaction Mechanism for the Cross-Linking of Gelatin with Glutaraldehyde.” J. Agric. Food Chem., 58 998–1003 (2010)CrossRef Farris, S, Song, JH, Huang, QR, “Alternative Reaction Mechanism for the Cross-Linking of Gelatin with Glutaraldehyde.” J. Agric. Food Chem., 58 998–1003 (2010)CrossRef
15.
Zurück zum Zitat Sivakumar, M, Radhakrishnan, PRG, Kothandaraman, H, “Grafting of Glycidyl Methacrylate onto Gelatin.” J. Appl. Polym. Sci., 43 1789–1794 (1991)CrossRef Sivakumar, M, Radhakrishnan, PRG, Kothandaraman, H, “Grafting of Glycidyl Methacrylate onto Gelatin.” J. Appl. Polym. Sci., 43 1789–1794 (1991)CrossRef
16.
Zurück zum Zitat Cao, N, Fu, Y, He, J, “Mechanical Properties of Gelatin Films Cross-Linked, Respectively, by Ferulic Acid and Tannin Acid.” Food Hydrocoll., 21 575–584 (2007)CrossRef Cao, N, Fu, Y, He, J, “Mechanical Properties of Gelatin Films Cross-Linked, Respectively, by Ferulic Acid and Tannin Acid.” Food Hydrocoll., 21 575–584 (2007)CrossRef
17.
Zurück zum Zitat Moraes, ICF, Carvalho, RA, “Film Forming Solutions Based on Gelatin and Poly(vinyl alcohol) Blends: Thermal and Rheological Characterizations.” J. Food Eng., 95 588–596 (2009)CrossRef Moraes, ICF, Carvalho, RA, “Film Forming Solutions Based on Gelatin and Poly(vinyl alcohol) Blends: Thermal and Rheological Characterizations.” J. Food Eng., 95 588–596 (2009)CrossRef
18.
Zurück zum Zitat Carvalho, RA, Maria, TMC, Moraes, ICF, “Study of Some Physical Properties of Biodegradable Films Based on Blends of Gelatin and Poly(vinyl alcohol) Using Aresponse-Surface Methodology.” Mater. Sci. Eng. C, 29 485–491 (2009)CrossRef Carvalho, RA, Maria, TMC, Moraes, ICF, “Study of Some Physical Properties of Biodegradable Films Based on Blends of Gelatin and Poly(vinyl alcohol) Using Aresponse-Surface Methodology.” Mater. Sci. Eng. C, 29 485–491 (2009)CrossRef
19.
Zurück zum Zitat Kim, S, Yang, NZ, “Chitosan/Gelatin-Based Films Crosslinked by Proanthocyanidin.” J. Biomed. Mater. Res. Part B Appl. Biomater., 75 442–450 (2005)CrossRef Kim, S, Yang, NZ, “Chitosan/Gelatin-Based Films Crosslinked by Proanthocyanidin.” J. Biomed. Mater. Res. Part B Appl. Biomater., 75 442–450 (2005)CrossRef
20.
Zurück zum Zitat Zheng, SX, Liu, YC, Fabio, P, “Disulfide-Crosslinked Hyaluronan-Gelatin Hydrogel Films: A Covalent Mimic of The Extracellular Matrix for in Vitro Cell Growth.” Biomaterials, 24 3825–3834 (2003)CrossRef Zheng, SX, Liu, YC, Fabio, P, “Disulfide-Crosslinked Hyaluronan-Gelatin Hydrogel Films: A Covalent Mimic of The Extracellular Matrix for in Vitro Cell Growth.” Biomaterials, 24 3825–3834 (2003)CrossRef
21.
Zurück zum Zitat Chiellini, E, Cinelli, P, Corti, A, “Films Based on Waste Gelatin: Thermal-Mechanical Properties and Biodegradation Testing.” Polym. Degrad. Stab., 73 549–555 (2001)CrossRef Chiellini, E, Cinelli, P, Corti, A, “Films Based on Waste Gelatin: Thermal-Mechanical Properties and Biodegradation Testing.” Polym. Degrad. Stab., 73 549–555 (2001)CrossRef
22.
Zurück zum Zitat Goswami, TH, Maiti, MM, “Biodegradability of Gelatin—PF Resin Blends by Soil Burial Method.” Polym. Degrad. Stab., 61 355–359 (1998)CrossRef Goswami, TH, Maiti, MM, “Biodegradability of Gelatin—PF Resin Blends by Soil Burial Method.” Polym. Degrad. Stab., 61 355–359 (1998)CrossRef
23.
Zurück zum Zitat Huang, Y, Onyeri, S, Siewe, M, “In Vitro Characterization of Chitosan-Gelatin Scaffolds for Tissue Engineering.” Biomaterials, 26 7616–7627 (2005)CrossRef Huang, Y, Onyeri, S, Siewe, M, “In Vitro Characterization of Chitosan-Gelatin Scaffolds for Tissue Engineering.” Biomaterials, 26 7616–7627 (2005)CrossRef
24.
Zurück zum Zitat Galow, TH, Boal, AK, Rotello, VM, “A “Building Block” Approach to Mixed-Colloid Systems Through Electrostatic Self-organization.” Adv. Mater., 12 576–579 (2000)CrossRef Galow, TH, Boal, AK, Rotello, VM, “A “Building Block” Approach to Mixed-Colloid Systems Through Electrostatic Self-organization.” Adv. Mater., 12 576–579 (2000)CrossRef
25.
Zurück zum Zitat Tan, P, Jackson, JB, Halas, NJ, Lee, TR, “Preparation and Characterization of Gold Nanoshells Coated with Self-Assembled Monolayers.” Langmuir, 18 4915–4920 (2002)CrossRef Tan, P, Jackson, JB, Halas, NJ, Lee, TR, “Preparation and Characterization of Gold Nanoshells Coated with Self-Assembled Monolayers.” Langmuir, 18 4915–4920 (2002)CrossRef
26.
Zurück zum Zitat Boal, AK, Ilhan, F, DeRouchey, JE, Thurn-Albrecht, T, Russell, TP, Rotello, VM, “Self-Assembly of Nanoparticles into Structured Spherical and Network Aggregates.” Nature (London), 404 746–748 (2000)CrossRef Boal, AK, Ilhan, F, DeRouchey, JE, Thurn-Albrecht, T, Russell, TP, Rotello, VM, “Self-Assembly of Nanoparticles into Structured Spherical and Network Aggregates.” Nature (London), 404 746–748 (2000)CrossRef
27.
Zurück zum Zitat Xu, J, Zhen, X, Qiao, CD, Li, TD, “Effect of Anionic Surfactants on Grafting Density of Gelatin Modified with PDMS-E.” Colloid Surf. B, 114 310–315 (2014)CrossRef Xu, J, Zhen, X, Qiao, CD, Li, TD, “Effect of Anionic Surfactants on Grafting Density of Gelatin Modified with PDMS-E.” Colloid Surf. B, 114 310–315 (2014)CrossRef
28.
Zurück zum Zitat Xu, J, Li, TD, Tang, XL, Qiao, CD, Jiang, QW, “Effect of Aggregation Behavior of Gelatin in Aqueous Solution on the Grafting Density of Gelatin Modified with Glycidol.” Colloid Surf. B, 95 201–207 (2012)CrossRef Xu, J, Li, TD, Tang, XL, Qiao, CD, Jiang, QW, “Effect of Aggregation Behavior of Gelatin in Aqueous Solution on the Grafting Density of Gelatin Modified with Glycidol.” Colloid Surf. B, 95 201–207 (2012)CrossRef
29.
Zurück zum Zitat Díaz-Calderón, P, Caballero, L, Melo, F, Enrione, J, “Molecular Configuration of Gelatin-Water Suspensions at Low Concentration.” Food Hydrocoll., 39 171–179 (2014)CrossRef Díaz-Calderón, P, Caballero, L, Melo, F, Enrione, J, “Molecular Configuration of Gelatin-Water Suspensions at Low Concentration.” Food Hydrocoll., 39 171–179 (2014)CrossRef
Metadaten
Titel
Fabrication, and characterization of polydimethylsiloxane/glycidol-grafted gelatin film
verfasst von
Lei Yue
Jing Li
Wei-Yue Zhu
Jing Xu
Tian-Duo Li
Publikationsdatum
04.11.2016
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 1/2017
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-016-9846-9

Weitere Artikel der Ausgabe 1/2017

Journal of Coatings Technology and Research 1/2017 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.