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Erschienen in: Journal of Materials Science 14/2020

06.02.2020 | Composites & nanocomposites

Facile and green synthesis of Au nanorods/graphene oxide nanocomposite with excellent catalytic properties for reduction of 4-nitrophenol

verfasst von: Jiali Fang, Xin Chen, Yulian Wu, Haiyang Liu

Erschienen in: Journal of Materials Science | Ausgabe 14/2020

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Abstract

In this paper, we report a facile and green method to synthesize Au nanorods (AuNRs)/graphene oxide (GO) nanocomposites. In this approach, cetyltrimethylammonium bromide (CTAB) acted not only as a shape-directing agent but also as an assembling agent. The AuNRs/GO nanocomposites were prepared through electrostatic self-assembly between CTAB-capped positively charged AuNRs and negatively charged GO in an aqueous solution without introducing other assembling agents or surfactants. The catalytic performance of the obtained catalysts is evaluated with TOF, TOF1/2 and kapp values. Due to the increased effectiveness from the charge-mediated assembly, these AuNRs/GO nanocomposites showed high performance in the catalytic reduction of 4-nitrophenol to 4-aminophenol. The AuNRs/GO ratio was optimized, and the nanocomposite with a mass ratio 1:0.4 showed the best catalytic activity, achieving a kapp value of 1.69 min−1, which was not only 19.7 times better than the AuNRs, but also significantly better than the catalytic performance of Au/graphene and Au/GO composites reported in the literature.

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Zurück zum Zitat Li J, Liu C, Liu Y (2012) Au/graphene hydrogel: synthesis, characterization and its use for catalytic reduction of 4-nitrophenol. J Mater Chem 22:8426–8430 Li J, Liu C, Liu Y (2012) Au/graphene hydrogel: synthesis, characterization and its use for catalytic reduction of 4-nitrophenol. J Mater Chem 22:8426–8430
Metadaten
Titel
Facile and green synthesis of Au nanorods/graphene oxide nanocomposite with excellent catalytic properties for reduction of 4-nitrophenol
verfasst von
Jiali Fang
Xin Chen
Yulian Wu
Haiyang Liu
Publikationsdatum
06.02.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 14/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04410-2

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