Skip to main content
Erschienen in: Colloid and Polymer Science 3/2017

26.01.2017 | Original Contribution

Facile preparation and self-aggregate of amphiphilic block nanoparticles

verfasst von: Linlin Song, Yixuan Du, Changqing Teng, Yunbo Li

Erschienen in: Colloid and Polymer Science | Ausgabe 3/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Amphiphilic block nanoparticles PEO-AuNP-PS (polyethylene oxide-AuNP-polystyrene) were prepared using “grafting-to” method and the multi-level nanostructure had been obtained by self-driven aggregation. The results show that Janus AuNP-PEO nanoparticles and PEO-AuNP-PS block nanoparticles had been successfully prepared via shielding method, respectively. The extinction peak has a red shift of 15 nm that suggests that AuNPs graft to PEO-SH single crystal. In addition, the multi-level aggregate of Janus nanoparticles was formed on the basis of the hydrophilic and hydrophobic polymer in selective solvents. It will provide an avenue for the self-aggregate of nanoparticles and the exploration of new materials and nano-composite materials.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Murphy CJ, Gole AM, Hunyadi SE, Stone JW, Sisco PN, Alkilany A, Kinard BE, Hankins P (2008) Chemical sensing and imaging with metallic nanorods. Chem Comm 544-557 Murphy CJ, Gole AM, Hunyadi SE, Stone JW, Sisco PN, Alkilany A, Kinard BE, Hankins P (2008) Chemical sensing and imaging with metallic nanorods. Chem Comm 544-557
2.
Zurück zum Zitat Cai W, Wang W, Lu L, Chen T (2013) Coating sulfonated polystyrene microspheres with highly dense gold nanoparticle shell for SERS application. Colloid Polym Sci 291:2023–2029CrossRef Cai W, Wang W, Lu L, Chen T (2013) Coating sulfonated polystyrene microspheres with highly dense gold nanoparticle shell for SERS application. Colloid Polym Sci 291:2023–2029CrossRef
3.
Zurück zum Zitat Kanahara M, Shimomura M, Yabu H (2014) Preparation of Au nanoparticles and end-functionalized poly (butadiene) composites via electrostatic interaction. Macromol Mater Eng 299:478–484CrossRef Kanahara M, Shimomura M, Yabu H (2014) Preparation of Au nanoparticles and end-functionalized poly (butadiene) composites via electrostatic interaction. Macromol Mater Eng 299:478–484CrossRef
4.
Zurück zum Zitat Grzelczak M, Pérez-Juste J, Mulvaney P, Liz-Marzán LM (2008) Shape control in gold nanoparticle synthesis. Chem Soc Rev 37:1783–1791CrossRef Grzelczak M, Pérez-Juste J, Mulvaney P, Liz-Marzán LM (2008) Shape control in gold nanoparticle synthesis. Chem Soc Rev 37:1783–1791CrossRef
5.
Zurück zum Zitat Gong J, Zu X, Mu W, Deng Y (2013) In situ self-assembly synthesis of gold nanoparticle arrays on polystyrene microspheres and their surface plasmon resonance. Colloid Polym Sci 291:239–244CrossRef Gong J, Zu X, Mu W, Deng Y (2013) In situ self-assembly synthesis of gold nanoparticle arrays on polystyrene microspheres and their surface plasmon resonance. Colloid Polym Sci 291:239–244CrossRef
6.
Zurück zum Zitat Jiang S, Chen Q, Tripathy M, Luijten E, Schweizer KS, Granick S (2010) Janus particle synthesis and assembly. Adv Mater 22:1060–1071CrossRef Jiang S, Chen Q, Tripathy M, Luijten E, Schweizer KS, Granick S (2010) Janus particle synthesis and assembly. Adv Mater 22:1060–1071CrossRef
7.
Zurück zum Zitat Higuchi T, Tajima A, Motoyoshi K, Yabu H, Shimomura M (2009) Suprapolymer structures from nanostructured polymer particles. Angew Chem 48:5125–5128CrossRef Higuchi T, Tajima A, Motoyoshi K, Yabu H, Shimomura M (2009) Suprapolymer structures from nanostructured polymer particles. Angew Chem 48:5125–5128CrossRef
8.
9.
Zurück zum Zitat Yabu H, Sato S, Higuchi T, Jinnai H, Shimomura M (2012) Creating suprapolymer assemblies: nanowires, nanorings, and nanospheres prepared from symmetric block-copolymers confined in spherical particles. J Mater Chem 22:7672–7675CrossRef Yabu H, Sato S, Higuchi T, Jinnai H, Shimomura M (2012) Creating suprapolymer assemblies: nanowires, nanorings, and nanospheres prepared from symmetric block-copolymers confined in spherical particles. J Mater Chem 22:7672–7675CrossRef
10.
Zurück zum Zitat Cheng L, Zhang G, Zhu L, Chen D, Jiang M (2008) Nanoscale tubular and sheetlike superstructures from hierarchical self-assembly of polymeric Janus particles. Angew Chem 120:10325–10328CrossRef Cheng L, Zhang G, Zhu L, Chen D, Jiang M (2008) Nanoscale tubular and sheetlike superstructures from hierarchical self-assembly of polymeric Janus particles. Angew Chem 120:10325–10328CrossRef
11.
Zurück zum Zitat Rauh A, Honold T, Karg M (2015) Seeded precipitation polymerization for the synthesis of gold-hydrogel core-shell particles: the role of surface functionalization and seed concentration. Colloid Polym Sci 294:1–11 Rauh A, Honold T, Karg M (2015) Seeded precipitation polymerization for the synthesis of gold-hydrogel core-shell particles: the role of surface functionalization and seed concentration. Colloid Polym Sci 294:1–11
12.
Zurück zum Zitat Zhao Z, Liang F, Zhang G, Ji X, Wang Q, Qu X, Song X, Yang Z (2015) Dually responsive Janus composite nanosheets. Macromolecules 48:3598–3603CrossRef Zhao Z, Liang F, Zhang G, Ji X, Wang Q, Qu X, Song X, Yang Z (2015) Dually responsive Janus composite nanosheets. Macromolecules 48:3598–3603CrossRef
13.
Zurück zum Zitat Pereira SO, Barros-Timmons A, Trindade T (2013) Biofunctionalisation of colloidal gold nanoparticles via polyelectrolytes assemblies. Colloid Polym Sci 292:33–50CrossRef Pereira SO, Barros-Timmons A, Trindade T (2013) Biofunctionalisation of colloidal gold nanoparticles via polyelectrolytes assemblies. Colloid Polym Sci 292:33–50CrossRef
14.
Zurück zum Zitat Zhou T, Dong B, Qi H, Mei S, Li CY (2014) Janus hybrid hairy nanoparticles. J Polym Sci Polym Phys 52:1620–1640CrossRef Zhou T, Dong B, Qi H, Mei S, Li CY (2014) Janus hybrid hairy nanoparticles. J Polym Sci Polym Phys 52:1620–1640CrossRef
15.
Zurück zum Zitat ten Hagen B, van Teeffelen S, Löwen H (2011) Brownian motion of a self-propelled particle. J Phys Condens Mat 23:194119CrossRef ten Hagen B, van Teeffelen S, Löwen H (2011) Brownian motion of a self-propelled particle. J Phys Condens Mat 23:194119CrossRef
16.
Zurück zum Zitat Chen Y, Liang F, Yang H, Zhang C, Wang Q, Qu X, Li J, Cai Y, Qiu D, Yang Z (2012) Janus nanosheets of polymer–inorganic layered composites. Macromolecules 45:1460–1467CrossRef Chen Y, Liang F, Yang H, Zhang C, Wang Q, Qu X, Li J, Cai Y, Qiu D, Yang Z (2012) Janus nanosheets of polymer–inorganic layered composites. Macromolecules 45:1460–1467CrossRef
17.
Zurück zum Zitat Cheung DL, Bon SAF (2009) Stability of Janus nanoparticles at fluid interfaces. Soft Matter 5:3969–3976CrossRef Cheung DL, Bon SAF (2009) Stability of Janus nanoparticles at fluid interfaces. Soft Matter 5:3969–3976CrossRef
18.
Zurück zum Zitat Luu X-C, Yu J, Striolo A (2013) Ellipsoidal Janus nanoparticles adsorbed at the water–oil interface: some evidence of emergent behavior. J Phys Chem B 117:13922–13929CrossRef Luu X-C, Yu J, Striolo A (2013) Ellipsoidal Janus nanoparticles adsorbed at the water–oil interface: some evidence of emergent behavior. J Phys Chem B 117:13922–13929CrossRef
19.
Zurück zum Zitat Wang B, Li B, Zhao B, Li CY (2008) Amphiphilic Janus gold nanoparticles via combining “solid-state grafting-to” and “grafting-from” methods. J Am Chem Soc 130:11594–11595CrossRef Wang B, Li B, Zhao B, Li CY (2008) Amphiphilic Janus gold nanoparticles via combining “solid-state grafting-to” and “grafting-from” methods. J Am Chem Soc 130:11594–11595CrossRef
20.
Zurück zum Zitat Song L, Qiao Y, Du Y, Li Y (2016) Shape control synthesis of polymeric hybrid nanoparticles via surface-initiated atom-transfer radical polymerization. J Appl Polym Sci. doi:10.1002/app.43584 Song L, Qiao Y, Du Y, Li Y (2016) Shape control synthesis of polymeric hybrid nanoparticles via surface-initiated atom-transfer radical polymerization. J Appl Polym Sci. doi:10.​1002/​app.​43584
21.
Zurück zum Zitat Song L, Qiao Y, Liu Z, Li Y (2014) One-step synthesis of Janus hybrid nanoparticles using reverse atom transfer radical polymerization in emulsion. Polym Chem 6:896–899CrossRef Song L, Qiao Y, Liu Z, Li Y (2014) One-step synthesis of Janus hybrid nanoparticles using reverse atom transfer radical polymerization in emulsion. Polym Chem 6:896–899CrossRef
22.
Zurück zum Zitat Li B, Ni C, Li CY (2008) Poly(ethylene oxide) single crystals as templates for Au nanoparticle patterning and asymmetrical functionalization. Macromolecules 41:149–155CrossRef Li B, Ni C, Li CY (2008) Poly(ethylene oxide) single crystals as templates for Au nanoparticle patterning and asymmetrical functionalization. Macromolecules 41:149–155CrossRef
23.
Zurück zum Zitat Yonezawa T, Yasui K, Kimizuka N (2001) Controlled formation of smaller gold nanoparticles by the use of four-chained disulfide stabilizer. Langmuir 17:271–273CrossRef Yonezawa T, Yasui K, Kimizuka N (2001) Controlled formation of smaller gold nanoparticles by the use of four-chained disulfide stabilizer. Langmuir 17:271–273CrossRef
24.
Zurück zum Zitat Chow M, Zukoski C (1994) Gold sol formation mechanisms: role of colloidal stability. J Colloid Interf Sci 165:97–109CrossRef Chow M, Zukoski C (1994) Gold sol formation mechanisms: role of colloidal stability. J Colloid Interf Sci 165:97–109CrossRef
25.
Zurück zum Zitat Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D. J.; Whyman, R. (1994) Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid–liquid system. J. Chem. Soc. 801–802. Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D. J.; Whyman, R. (1994) Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid–liquid system. J. Chem. Soc. 801–802.
26.
Zurück zum Zitat Qiao Y, Du Y, Liu Y, Li Y (2016) Synthesis and optoelectronics properties of diblock copolymer of P3HT containing thiol-side chains and its hybrid nanocomposite. RSC Adv 6:110686–110694CrossRef Qiao Y, Du Y, Liu Y, Li Y (2016) Synthesis and optoelectronics properties of diblock copolymer of P3HT containing thiol-side chains and its hybrid nanocomposite. RSC Adv 6:110686–110694CrossRef
27.
Zurück zum Zitat Li B, Li CY (2007) Immobilizing Au nanoparticles with polymer single crystals, patterning and asymmetric functionalization. J Am Chem Soc 129:12–13CrossRef Li B, Li CY (2007) Immobilizing Au nanoparticles with polymer single crystals, patterning and asymmetric functionalization. J Am Chem Soc 129:12–13CrossRef
28.
Zurück zum Zitat Wang B, Li B, Ferrier R, Li CY (2010) Polymer single crystal templated Janus nanoparticles. Macromol Rapid Comm 31:169–175 Wang B, Li B, Ferrier R, Li CY (2010) Polymer single crystal templated Janus nanoparticles. Macromol Rapid Comm 31:169–175
29.
Zurück zum Zitat Ghosh SK, Nath S, Kundu S, Esumi K, Pal T (2004) Solvent and ligand effects on the localized surface plasmon resonance (LSPR) of gold colloids. J Phys Chem B 108:13963–13971CrossRef Ghosh SK, Nath S, Kundu S, Esumi K, Pal T (2004) Solvent and ligand effects on the localized surface plasmon resonance (LSPR) of gold colloids. J Phys Chem B 108:13963–13971CrossRef
30.
Zurück zum Zitat Li B, Wang B, Ferrier Jr RC, Li CY (2009) Programmable nanoparticle assembly via polymer single crystals. Macromolecules 42:9394–9399CrossRef Li B, Wang B, Ferrier Jr RC, Li CY (2009) Programmable nanoparticle assembly via polymer single crystals. Macromolecules 42:9394–9399CrossRef
31.
Zurück zum Zitat Bhargava P, Zheng JX, Li P, Quirk RP, Harris FW, Cheng SZ (2006) Self-assembled polystyrene-block-poly (ethylene oxide) micelle morphologies in solution. Macromolecules 39:4880–4888CrossRef Bhargava P, Zheng JX, Li P, Quirk RP, Harris FW, Cheng SZ (2006) Self-assembled polystyrene-block-poly (ethylene oxide) micelle morphologies in solution. Macromolecules 39:4880–4888CrossRef
32.
Zurück zum Zitat Bhargava P, Zheng JX, Quirk RP, Cheng SZ (2006) Self-assembled, wormlike-cylinder network of polystyrene-block-poly (ethylene oxide) micelles in solution. J Polym Sci Polym Phys 44:3605–3611CrossRef Bhargava P, Zheng JX, Quirk RP, Cheng SZ (2006) Self-assembled, wormlike-cylinder network of polystyrene-block-poly (ethylene oxide) micelles in solution. J Polym Sci Polym Phys 44:3605–3611CrossRef
33.
Zurück zum Zitat Bhargava P, Tu Y, Zheng JX, Xiong H, Quirk RP, Cheng SZ (2007) Temperature-induced reversible morphological changes of polystyrene-block-poly (ethylene oxide) micelles in solution. J Am Chem Soc 129:1113–1121CrossRef Bhargava P, Tu Y, Zheng JX, Xiong H, Quirk RP, Cheng SZ (2007) Temperature-induced reversible morphological changes of polystyrene-block-poly (ethylene oxide) micelles in solution. J Am Chem Soc 129:1113–1121CrossRef
34.
Zurück zum Zitat Wang X, Guerin G, Wang H, Wang Y, Manners I, Winnik MA (2007) Cylindrical block copolymer micelles and co-micelles of controlled length and architecture. Science 317:644–647CrossRef Wang X, Guerin G, Wang H, Wang Y, Manners I, Winnik MA (2007) Cylindrical block copolymer micelles and co-micelles of controlled length and architecture. Science 317:644–647CrossRef
35.
Zurück zum Zitat He W-D, Sun X-L, Wan W-M, Pan C-Y (2011) Multiple morphologies of PAA-b-PSt assemblies throughout RAFT dispersion polymerization of styrene with PAA Macro-CTA. Macromolecules 44:3358–3365CrossRef He W-D, Sun X-L, Wan W-M, Pan C-Y (2011) Multiple morphologies of PAA-b-PSt assemblies throughout RAFT dispersion polymerization of styrene with PAA Macro-CTA. Macromolecules 44:3358–3365CrossRef
Metadaten
Titel
Facile preparation and self-aggregate of amphiphilic block nanoparticles
verfasst von
Linlin Song
Yixuan Du
Changqing Teng
Yunbo Li
Publikationsdatum
26.01.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 3/2017
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4021-0

Weitere Artikel der Ausgabe 3/2017

Colloid and Polymer Science 3/2017 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.