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Erschienen in: Journal of Materials Science: Materials in Electronics 8/2020

06.03.2020

Facile solvent deficient synthesis of mesoporous Co3O4 nanoparticles for electrochemical energy storage

verfasst von: R. M. Kore, B. J. Lokhande

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 8/2020

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Abstract

High surface area, mesoporous metal oxide nanoparticles play a significant role in the electrochemical charge storage applications. A facile solvent-deficient approach has been reported for synthesis of high surface area, mesoporous Co3O4 nanoparticles for the electrochemical energy storage. A precursor is obtained by grinding hydrated cobalt nitrate salt with ammonium bicarbonate for 25 min without addition of any true solvent. Further, the precursor is annealed at 300 ℃ to obtain Co3O4 from as prepared untreated precursor and after rinsing using deionized water. The XRD, Raman and FTIR spectra revealed the single-phase formation of Co3O4. SEM shows granular-type morphologies with two distinct size for two different samples. The BET analysis confirms mesoporous nature with specific surface area of 135 and 193 m2g−1 for samples obtained from untreated and rinsed precursors. The maximum specific capacitance of Co3O4 obtained from untreated and rinsed samples are 184 and 349 Fg−1. A very fewer equivalent series resistance of 2.24 Ω and 1.91 Ω has been observed, respectively.

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Metadaten
Titel
Facile solvent deficient synthesis of mesoporous Co3O4 nanoparticles for electrochemical energy storage
verfasst von
R. M. Kore
B. J. Lokhande
Publikationsdatum
06.03.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 8/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-03170-8

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