Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 16/2017

04.05.2017

Facile synthesis of α-Fe2O3@graphene oxide nanocomposites for enhanced gas-sensing performance to ethanol

verfasst von: Xiaohua Jia, Dandan Lian, Bing Shi, Rongrong Dai, Changchao Li, Xiangyang Wu

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 16/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A simple and eco-friendly approach was used to prepare α-Fe2O3@graphene oxide (α-Fe2O3@GO) nanocomposites with different iron oxide content in lower temperature. The nanocomposites were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and nitrogen adsorption–desorption techniques. The results show that α-Fe2O3 nanoparticles with particle sizes of 60–100 nm are uniformly anchored on the surface of GO nanosheets at lower hydrothermal reaction. The specific surface area of α-Fe2O3@GO (114.57 m2/g) was about threefold larger than that of pure iron oxide (33.37 m2/g). Moreover, α-Fe2O3@GO nanocomposites with optimal mass ratio (8:1) between iron oxide and GO, which exhibited enhanced response to 100 ppm ethanol (14.82) in comparison with pure α-Fe2O3 (3.48) at 260 °C. The improved sensitive performance is in contact with larger surface area and incremental active sites in interface owing to introducing GO. The results reveal that GO is crucial to improve gas sensing performance.
Vorheriger Artikel Synthesis, structural and optical properties of Fe-doped nanocrystalline SnO2
Nächster Artikel Electrospinning poly(l-lactic acid) piezoelectric ordered porous nanofibers for strain sensing and energy harvesting

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
E. Comini, Metal oxide nano-crystals for gas sensing. Anal. Chim. Acta. 568, 28–40 (2006)CrossRef
2.
Y.F. Sun, S.B. Liu, F.L. Meng, J.Y. Liu, Z. Jin, L.T. Kong, J.H. Liu, Metal oxide nanostructures and their gas sensing properties: a review. Sensors 12, 2610–2631 (2012)CrossRef
3.
P.S. Cho, K.W. Kim, J.H. Lee, NO2 sensing characteristics of ZnO nanorods prepared by hydrothermal method. J. Electroceram. 17, 975–978 (2006)CrossRef
4.
H. Wang, Q.Q. Liang, W.J. Wang, Y.R. An, J.H. Li, L. Guo, Preparation of flower-like SnO2 nanostructures and their applications in gas-sensing and lithium storage. Cryst. Growth Des. 11, 2942–2947 (2011)CrossRef
5.
N.N. Ba, L.J. Zhu, G.Z. Zhang, J.F. Li, H.J. Li, Facile synthesis of 3D CuO nanowire bundle and its excellent gas sensing and electrochemical sensing properties. Sens. Actuators B 227, 142–148 (2016)CrossRef
6.
A. Gurlo, M. Sahm, A. Oprea, N. Barsan, U. Weimar, A p- to n-transition on α-Fe2O3-based thick film sensors studied by conductance and work function change measurements. Sens. Actuators B 102, 291–298 (2004)CrossRef
7.
H. Kheel, G.J. Sun, J.K. Lee, S. Lee, R.P. Dwivedi, C. Lee, Enhanced H2S sensing performance of TiO2-decorated α-Fe2O3 nanorod sensor. Ceram. Int. 42, 1–8 (2016)CrossRef
8.
S. Liang, J.P. Li, F. Wang, J.L. Qin, X.Y. Lai, X.M. Jiang, Highly sensitive acetone gas sensor based on ultrafine α-Fe2O3 nanoparticles. Sens. Actuators B 238, 923–927 (2017)CrossRef
9.
P. Poizot, S. Laruelle, S. Grugeon, L. Dupont, J. Tarascon, Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407, 496–499 (2000)CrossRef
10.
W.X. Jin, S.Y. Ma, Z.Z. Tie, X.H. Jiang, W.Q. Li, J. Luo, X.L. Xu, T.T. Wang, Hydrothermal synthesis of monodisperse porous cube, cake and spheroid-like α-Fe2O3 particles and their high gas-sensing properties. Sens. Actuators B 220, 243–254 (2015)CrossRef
11.
Y. Wang, J. Cao, S. Wang, X. Guo, J. Zhang, X. Xia, S. Zhang, S. Wu, Facile synthesis of porous α-Fe2O3 nanorods and their application in ethanol sensors. J. Phys. Chem. C 112, 17804–17808 (2008)CrossRef
12.
S.Y. Zeng, K.B. Tang, T.W. Li, Z.H. Liang, D. Wang, Y.K. Wang, Y.X. Qi, W.W. Zhou, Facile route for the fabrication of porous hematite nanoflowers: its synthesis growth mechanism, application in the lithium ion battery, and magnetic and photocatalytic properties. J. Phys. Chem. C 112, 4834–4836 (2008)
13.
S. Mitra, S. Das, K. Mandal, S. Chuadhari, Synthesis of α-Fe2O3 nanocrystal in its different morphological attributes: growth mechanism, optical and magnetic properties. Nanotechnology 18, 275608 (2007)CrossRef
14.
P. Li, Y. Cai, H.Q. Fan, Porous thin sheet-based α-Fe2O3-doped In2O3 structures: hydrothermal synthesis and enhanced Cl2 sensing performance. RSC Adv. 3, 22239–22245 (2013)CrossRef
15.
L.M. Huang, H.Q. Fan, Room-temperature solid state synthesis of ZnO/α-Fe2O3 hierarchical nanostructures and their enhanced gas-sensing properties. Sens. Actuators B 171–172, 1257–1263 (2012)CrossRef
16.
W. Yan, H.Q. Fan, Y.C. Zhai, C. Yang, P.R. Ren, L.M. Huang, Low temperature solution-based synthesis of porous flower-like α-Fe2O3 superstructures and their excellent gas-sensing properties. Sens. Actuators B 160, 1372–1379 (2011)CrossRef
17.
P.C. Wu, W.S. Wang, Y.T. Huang, H.S. Sheu, Y. Lo, T.L. Tsai, D.B. Shieh, C.S. Yeh, Porous iron oxide based nanorods developed as delivery nanocapsules. Chem. Eur. J. 13, 3878–3885 (2007)CrossRef
18.
H.M. Chen, Y.Q. Zhao, M.Q. Yang, J.H. He, P.K. Chu, J. Zhang, S.W. Wu, Glycine-assisted hydrothermal synthesis of peculiar porous α-Fe2O3 nanospheres with excellent gas-sensing properties. Anal. Chim. Acta. 659, 266–273 (2010)CrossRef
19.
G.K. Pradhan, K.M. Parida, Fabrication, growth mechanism, and characterization of α-Fe2O3 nanorods. ACS Appl. Mater. Interfaces 3, 317–323 (2011)CrossRef
20.
H.Z. Wang, X.T. Zhang, B. Liu, H.L. Zhao, Y.C. Li, Y.B. Huang, Z.L. Du, Synthesis and characterization of single crystal α-Fe2O3 nanobelts. Chem. Lett. 34, 184–185 (2005)CrossRef
21.
Y.L. Chueh, M.W. Lai, J.Q. Liang, L.J. Chou, Z.L. Wang, Systematic study of the growth of aligned arrays of α-Fe2O3 and Fe3O4 nanowires by a vapor-solid process. Adv. Funct. Mater. 16, 2243–2251 (2006)CrossRef
22.
S.K. Mohapatra, S.E. John, S. Banerjee, M. Misra, Water photo oxidation by smooth and ultrathin α-Fe2O3 nanotube arrays. Chem. Mater. 21, 3048–3055 (2009)CrossRef
23.
W. Yan, H. Fan, Y. Zhai, C. Yang, P. Ren, L. Huang, Low temperature solution-based synthesis of porous flower-like α-Fe2O3 superstructures and their excellent gas-sensing properties. Sens. Actuators B 160, 1372–1379 (2011)CrossRef
24.
Q. Yu, J. Zhu, Z. Xu, X. Huang, Facile synthesis of α-Fe2O3@SnO2 core–shell heterostructure nanotubes for high performance gas sensors. Sens. Actuators B 213, 27–34 (2015)CrossRef
25.
Y.M. Zhao, Y.H. Li, R.Z. Ma, M.J. Roe, D.G. McCartney, Y.Q. Zhu, Growth and characterization of iron oxide nanorods/nanobelts prepared by a simple iron–water reaction. Small 2, 422–427 (2006)CrossRef
26.
J.F. Tan, J.H. Chen, K. Liu, X.T. Huang, Synthesis of porous α-Fe2O3 microrods via in situ decomposition of FeC2O4 precursor for ultra-fast responding and recovering ethanol gas sensor. Sens. Actuators B 230, 46–53 (2016)CrossRef
27.
A. Mirzaei, K. Janghorban, B. Hashemi, M. Bonyani, S.G. Leonardi, G. Neri, A novel gas sensor based on Ag/Fe2O3 core-shell nanocomposites. Ceram. Int. 42, 1–9 (2016)CrossRef
28.
S.G. Chatterjeea, S. Chatterjeeb, A.K. Ray, A.K. Chakraborty, Graphene–metal oxide nanohybrids for toxic gas sensor: a review. Sens. Actuators B 221, 1170–1181 (2015)CrossRef
29.
S. Liu, B. Yu, H. Zhang, T. Fei, T. Zhang, Enhancing NO2 gas sensing performances at room temperature based on reduced graphene oxide-ZnO nanoparticles hybrids. Sens. Actuators B 202, 272–278 (2014)CrossRef
30.
Q.Q. Lin, Y. Li, M.J. Yang, Tin oxide/graphene composite fabricated via a hydrothermal method for gas sensors working at room temperature, Sens. Actuators B, 173, 139–147 (2012)CrossRef
31.
X.F. Chu, T. Hu, F. Gao, Y.P. Dong, W.Q. Sun, L.S. Bai, Gas sensing properties of graphene–WO3 composites prepared by hydrothermal method. Mater. Sci. Eng. B 193, 97–104 (2015)CrossRef
32.
L. Zhou, F. Shen, X. Tian, D. Wang, T. Zhang, W. Chen, Stable Cu2O nano-crystals grown on functionalized graphene sheets and room temperature H2S gas sensing with ultrahigh sensitivity. Nanoscale 5, 1564–1569 (2013)CrossRef
33.
Y. Yang, L. Sun, X.T. Dong, H. Yu, T.T. Wang, J.X. Wang, R.H. Wang, W.S. Yu, G.X. Liu, Fe3O4/rGO nanocomposite: synthesis and enhanced NO x gas-sensing properties at room temperature. RSC Adv. 43, 37085–37092 (2016)CrossRef
34.
S.M. Liang, J.Z. Zhu, C. Wang, S.T. Yu, H.P. Bi, X.H. Liu, X. Wang, Fabrication of α-Fe2O3@graphene nanostructures for enhanced gas-sensing property to ethanol. Appl. Surf. Sci. 292, 278–284 (2014)CrossRef
35.
H. Zhang, L. Yu, Q. Li, Y. Du, S.C. Ruan, Reduced graphene oxide/α-Fe2O3 hybrid nanocomposites for room temperature NO2 sensing. Sens. Actuators B 241, 109–115 (2017)CrossRef
36.
B. Ghammraoui, V. Rebuffel, J. Tabaryeral, C. Paulus, L. Verger, P. Duvauchelle, Effect of grain size on stability of X-ray diffraction patterns used for threat detection. Nucl. Instrum. Methods Phys. Res. Sect. A 683, 1–7 (2012)CrossRef
37.
S. Dubin, S. Gilje, K. Wang, V.C. Tung, K. Cha, A.S. Hall, J. Farrar, R. Varshneya, Y. Yang, R.B. Kaner, A one-step solvothermal reduction method for producing reduced graphene oxide dispersions in organic solvents. Acs Nano. 4, 3845–3852 (2010)CrossRef
38.
B. Zhang, J. Liu, X.B. Cui, Y.L. Wang, Y. Gao, P. Sun, F.M. Liu, K. Shimanoe, N. Yamazoe, G. Lu, Enhanced gas sensing properties to acetone vapor achieved by α-Fe2O3 particles ameliorated with reduced graphene oxide sheets. Sens. Actuators B 241, 904–914 (2017)CrossRef
39.
Y. Zhou, Q.L. Bao, L.A.L. Tang, Y.L. Zhong, K.P. Loh, Hydrothermal dehydration for the “Green” reduction of exfoliated graphene oxide to graphene and demonstration of tunable optical limiting properties. Chem. Mater. 21, 2950–2956 (2009)CrossRef
40.
C. Xu, X. Wang, J.W. Zhu, Graphene–metal particle nanocomposites. J. Phys. Chem. C 112, 19841–19845 (2008)CrossRef
41.
Y. Yuan, W. Jiang, Y.J. Wang, P. Shen, F.S. Li, P.Y. Li, F.Q. Zhao, H.X. Gao, Hydrothermal preparation of Fe2O3/graphene nanocomposite and its enhanced catalytic activity on the thermal decomposition of ammonium perchlorate. Appl. Surf. Sci. 303, 354–359 (2014)CrossRef
42.
M. Abaker, A. Umar, S. Baskoutas, G.N. Dar, S.A. Zaidi, S.A. Al-Sayari, A. Al-Hajry, S.H. Kim, S.W. Hwang, A highly sensitive ammonia chemical sensor based on α-Fe2O3 nanoellipsoids. J. Phys. D 44, 401–425 (2011)
43.
Y.T. Ngo, S.H. Hur, Low-temperature NO2 gas sensor fabricated with NiO and reduced graphene oxide hybrid structure. Mater. Res. Bull. 84, 168–176 (2016)CrossRef
44.
S. Stankovich, D.A. Dikin, R.D. Pinera, K.A. Kohlhaasa, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen, R.S. Ruoff, Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45, 1558–1565 (2007)CrossRef
45.
Y.J. Chen, G. Xiao, T.S. Wang, Q.Y. Ouyang, L.H. Qi, Y. Ma, P. Gao, C.L. Zhu, M.S. Cao, H.B. Jin, Porous Fe3O4/Carbon core/shell nanorods: synthesis and electromagnetic properties. J. Phys. Chem. C 115, 13603–13608 (2011)CrossRef
46.
M. Kruk, M. Jaroniec, Gas adsorption characterization of ordered organic-inorganic nanocomposite materials. Chem. Mater. 13, 3169–3183 (2001)CrossRef
47.
X.B. Wang, Y.Y. Wang, F. Tian, H.J.M. Liang, K. Wang, X.H. Zhao, Z.S. Lu, K. Jiang, L. Yang, X.D. Lou, From the surface reaction control to gas-diffusion control: the synthesis of hierarchical porous SnO2 microspheres and their gas-sensing mechanism. J. Phys. Chem. C 119, 15963–15976 (2015)CrossRef
48.
F. Ren, L.P. Gao, Y.W. Yuan, Y. Zhang, A. Alqrni, O.M. Al-Dossary, J.Q. Xu, Enhanced BTEX gas-sensing performance of CuO/SnO2 composite. Sens. Actuators B 223, 914–920 (2016)CrossRef
49.
P. Wang, X.F. Zhang, S. Gao, X.L. Cheng, L.L. Sui, Y.M. Xu, X. Zhao, H. Zhao, L.H. Huo, Superior acetone sensor based on single-crystalline α-Fe2O3 mesoporous nanospheres via [C12mim][BF4]-assistant synthesis. Sens. Actuators B 241, 967–977 (2017)CrossRef
50.
G. Sun, H.L. Chen, Y.W. Li, G.Z. Ma, S.S. Zhang, T.K. Jia, J.L. Cao, X.D. Wang, H. Bala, Z.Y. Zhang, Synthesis and triethylamine sensing properties of mesoporous α-Fe2O3 microrods. Mater. Lett. 178, 213–216 (2016)CrossRef
51.
P. Sun, W.N. Wang, Y.P. Liu, Y.F. Sun, J. Ma, G.Y. Lu, Hydrothermal synthesis of 3D urchin-like α-Fe2O3 nanostructure for gas sensor. Sens. Actuators B, 173, 52–57 (2012)CrossRef
52.
D.Y. Zheng, H. H, X.J. Liu, S.H. Hu, Application of graphene in elctrochemical sensing. Curr. Opin. Colloid Interface Sci. 20, 383–405 (2015)CrossRef
53.
J.H. Lee, Gas sensors using hierarchical and hollow oxide nanostructures: overview. Sens. Actuators B 140, 319–336 (2009)CrossRef
54.
Z.J. Li, Z.J. Lin, N.N. Wang, Y.W. Huang, J.Q. Wang, W. Liu, Y.Q. Fu, Z.G. Wang, N.N. Wang, Facile synthesis of α-Fe2O3 micro-ellipsoids by surfactant-free hydrothermal method for sub-ppm level H2S detection. Mater. Des. 110, 532–539 (2016)CrossRef
Metadaten
Titel
Facile synthesis of α-Fe2O3@graphene oxide nanocomposites for enhanced gas-sensing performance to ethanol
verfasst von
Xiaohua Jia
Dandan Lian
Bing Shi
Rongrong Dai
Changchao Li
Xiangyang Wu
Publikationsdatum
04.05.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 16/2017
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-7019-y

Weitere Artikel der Ausgabe 16/2017

Journal of Materials Science: Materials in Electronics 16/2017 Zur Ausgabe

OriginalPaper

Preparation of yolk–shell Fe3O4@N-doped carbon nanocomposite particles as anode in lithium ion batteries

Erratum

Erratum to: Dielectric behavior of La2O3-modified 0.4(Ba0.8Ca0.2)TiO3–0.6Bi(Mg0.5Ti0.5)O3 lead-free ceramics

OriginalPaper

Luminescence properties of novel double perovskite Gd2MgTiO6:Eu3+ phosphors prepared by solid state method

OriginalPaper

Fabrication of Ce2S3/MoS2 composites via recrystallization-sulfurization method and their improved electrochemical performance for lithium-ion batteries

OriginalPaper

Influence of Mn dopant concentration on film thickness, structural, morphological, compositional and optical properties of zinc oxide thin films

OriginalPaper

Laser ablated lead free (Na, K) NbO3 thin films with excess alkali-content

Neuer Inhalt

    Bildnachweise