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Journal of Materials Science
Erschienen in: Journal of Materials Science 17/2021

08.03.2021 | Chemical routes to materials

Facile synthesis of Mg-formate MOF-derived mesoporous carbon for fast capacitive deionization

verfasst von: Taimoor Hussain, Pengfei Nie, Bin Hu, Xiaohong Shang, Jianmao Yang, Jianyun Liu

Erschienen in: Journal of Materials Science | Ausgabe 17/2021

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Abstract

Alkaline-earth metal-based MOF has many merits such as light weight, environmental friendliness and low cost, but it has rarely been used in energy storage and capacitive deionization (CDI). This paper presents a facile method for the fast synthesis of small-size magnesium formate MOF (Mg-MOF) under mild conditions by linker-free incubation in the presence of Mg(CH3COO)2⋅ 4H2O and dimethylformamide. The formic acid was in situ formed as ligand to facilitate the formation of Mg-MOF. The effect of incubation time on the morphology of MOF crystals was investigated. The small and well-defined Mg-MOF particles with the size of ~ 18 nm were formed in 1 h incubation, characterized by scanning electron microscopy and X-ray diffraction. Following carbonization, the Mg-MOF-derived mesoporous carbon was obtained. N2-sorption isotherm confirmed the mesoporous structure. Cyclic voltammetry test indicated the good electric double-layer feature of the Mg-MOF-derived carbon electrode, and the impedance results showed the excellent conductivity. As a capacitor electrode material, it delivered the specific capacitances of 102 F/g by GCD (0.2 A/g). The Mg-MOF-derived carbon electrode was applied successfully for capacitive deionization (CDI) with a desalination capacity of 8.0 mg/g in a CDI device. A supper fast desalination rate of 1.1 mg/g/min was achieved due to the abundant mesoporous structure. The work provides a cost effective and environmentally friendly way for the synthesis of MOF-based carbon materials free of transition metal, and the prospects for CDI application have been demonstrated.
Vorheriger Artikel Numerical study of thermal effect in silicone rubber filled with carbonyl iron powder under microwave radiation
Nächster Artikel Adjusting shell composition and content of Co-based bimetal core–shell microspheres toward the broadband microwave absorption

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Metadaten
Titel
Facile synthesis of Mg-formate MOF-derived mesoporous carbon for fast capacitive deionization
verfasst von
Taimoor Hussain
Pengfei Nie
Bin Hu
Xiaohong Shang
Jianmao Yang
Jianyun Liu
Publikationsdatum
08.03.2021
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 17/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-021-05962-7

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