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Erschienen in: Journal of Materials Engineering and Performance 1/2015

01.01.2015

Formation of Porous Anodic Oxide Film on Titanium in Phosphoric Acid Electrolyte

verfasst von: Z. Liu, G. E. Thompson

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 1/2015

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Abstract

A sequential breakdown anodizing conditions on cp-Ti in phosphoric acid has been investigated in the present study. Anodic oxide films were formed at 100, 150, and 200 V, examined by scanning electron microscopy, Raman spectroscopy, glow discharge optical emission spectrometry, and electrochemical impedance spectroscopy. A porous oxide texture was formed at each voltage. The thickness of anodic porous oxide increased with the increase of anodic voltage. Nano-particulates were formed around and within the pores, and the size of pores increased with increased voltage due to the expansion of particulates. The amorphous-to-crystalline transition was initiated during the film growth. The degree of crystallinity in the anodic oxide film fabricated at 200 V is more abundant than 150 and 100 V. Increased content of the phosphorus species was incorporated into the porous film with the increase of anodic voltage, stabilizing for the nanocrystals developed within the oxide.

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Metadaten
Titel
Formation of Porous Anodic Oxide Film on Titanium in Phosphoric Acid Electrolyte
verfasst von
Z. Liu
G. E. Thompson
Publikationsdatum
01.01.2015
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 1/2015
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-014-1262-7

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