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Journal of Materials Science
Erschienen in: Journal of Materials Science 24/2021

25.05.2021 | Electronic materials

Free-standing In2O3(ZnO)m superlattice microplates grown by optical vapor supersaturated precipitation

verfasst von: Yimin Liao, Yinzhou Yan, Lixue Yang, Yongman Pan, Yue Lu, Fei Chen, Qiang Wang, Yijian Jiang

Erschienen in: Journal of Materials Science | Ausgabe 24/2021

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Abstract

Here, we fabricated In2O3(ZnO)m (IZO) superlattice microplates with hexagon morphologies by the substrate-free optical vapor supersaturated precipitation. The IZO microplates possessed a superlattice structure with a large m number, i.e., m = 23, consisting of layered alternating stacks of octahedral InO2− as inversion boundaries and layered InZnmOm+1+ as a zig-zag modulated pattern. The Raman peak at 613 cm−1 confirmed the superlattice of the IZO microplates. The broad asymmetric excitonic photoluminescence (PL) emission with the photon energy of 3.236 eV indicated the heavy doping of indium in the IZO, resulting a redshift of ~ 32 meV from the near-band-edge emission. The unusual negative thermal quenching of PL intensity was also observed. Moreover, the anisotropic electrical properties of the IZO superlattice microplates were manifested, for the first time, where the in-plane conductivity was two orders of magnitude higher than out-plane one. The present work provided new insight into the free-standing IZO superlattice microdevices for future optoelectronic applications.
Vorheriger Artikel Optimization of the thermoelectric performance of α-MgAgSb-based materials by Zn-doping
Nächster Artikel Ligand-free Au nanoclusters/g-C3N4 ultra-thin nanosheets composite photocatalysts for efficient visible-light-driven photocatalytic H2 generation

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Metadaten
Titel
Free-standing In2O3(ZnO)m superlattice microplates grown by optical vapor supersaturated precipitation
verfasst von
Yimin Liao
Yinzhou Yan
Lixue Yang
Yongman Pan
Yue Lu
Fei Chen
Qiang Wang
Yijian Jiang
Publikationsdatum
25.05.2021
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 24/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-021-06175-8

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