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Erschienen in: Polymer Bulletin 11/2020

07.12.2019 | Original Paper

From starch to oligoetherols and polyurethane foams

verfasst von: Renata Lubczak, Dominik Szczęch, Jacek Lubczak

Erschienen in: Polymer Bulletin | Ausgabe 11/2020

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Abstract

The method of oligoetherols synthesis from starch, glycidol, and alkylene carbonates in water was described. The composition and structure of oligoetherols were determined, and these oligoetherols were used to obtain rigid polyurethane foams (PUFs). The obtained PUFs showed apparent density, water uptake, and polymerization shrinkage similar to classic rigid PUFs, and some of them had considerably improved thermal resistance. Their compression strength was observed to increase upon thermal exposure, which offers useful polymeric materials.

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Literatur
2.
Zurück zum Zitat Wirpsza Z (1991) Polyurethanes, chemistry, technology, application. WNT, Warsaw Wirpsza Z (1991) Polyurethanes, chemistry, technology, application. WNT, Warsaw
3.
Zurück zum Zitat Prociak A, Rokicki G, Ryszkowska J (2014) Polyurethane materials. Scientific Publisher PWN, Warszaw Prociak A, Rokicki G, Ryszkowska J (2014) Polyurethane materials. Scientific Publisher PWN, Warszaw
4.
Zurück zum Zitat Ionescu M (2008) Chemistry and technology of polyols for polyurethanes. Rapra Technology Ltd., Shawbury Ionescu M (2008) Chemistry and technology of polyols for polyurethanes. Rapra Technology Ltd., Shawbury
5.
Zurück zum Zitat Szycher M (1999) Szycher’s handbook of polyurethanes. CRC Press, Boca Raton Szycher M (1999) Szycher’s handbook of polyurethanes. CRC Press, Boca Raton
6.
Zurück zum Zitat Florjańczyk Z, Penczek S (1999) Polymer chemistry. Part III. Natural polymers and polymers with special properties. Warsaw University of Technology Publishing House, Warsaw Florjańczyk Z, Penczek S (1999) Polymer chemistry. Part III. Natural polymers and polymers with special properties. Warsaw University of Technology Publishing House, Warsaw
7.
Zurück zum Zitat Richter M, Augustat S, Schierbaum F (1968) Ausgewählte Methoden der Stärkechemie. VEB Fachbuchverlag, Leipzig Richter M, Augustat S, Schierbaum F (1968) Ausgewählte Methoden der Stärkechemie. VEB Fachbuchverlag, Leipzig
8.
Zurück zum Zitat Kesler C, Hjermstad E (1958) Hydroxyalkylation of ungelatinized starches and dextrins I aqueous, water-miscible alcohols. US Patent Pat. 2845417 Kesler C, Hjermstad E (1958) Hydroxyalkylation of ungelatinized starches and dextrins I aqueous, water-miscible alcohols. US Patent Pat. 2845417
9.
Zurück zum Zitat Grayi J, BeMiller J (2005) Influence of reaction conditions on the location of reactions in waxy maize starch granules reacted with a propylene oxide analog at low substitution levels. Carbohydr Polym 60:147–162CrossRef Grayi J, BeMiller J (2005) Influence of reaction conditions on the location of reactions in waxy maize starch granules reacted with a propylene oxide analog at low substitution levels. Carbohydr Polym 60:147–162CrossRef
10.
Zurück zum Zitat Jarowenko W (1978) Method of preparing hydroxypropylated starch derivatives. US Patent 4112222 Jarowenko W (1978) Method of preparing hydroxypropylated starch derivatives. US Patent 4112222
11.
Zurück zum Zitat Bien F, Wiege B, Warwel S (2001) Hydrophobic modification of starch by alkali-catalyzed addition of 1,2-epoxyalkanes. Starch Starke 53:555–559CrossRef Bien F, Wiege B, Warwel S (2001) Hydrophobic modification of starch by alkali-catalyzed addition of 1,2-epoxyalkanes. Starch Starke 53:555–559CrossRef
12.
Zurück zum Zitat Funke U, Lindhauer MG (2001) Effect of reaction conditions and alkyl chain lengths on the properties of hydroxyalkyl starch ethers. Starch Starke 53:547–554CrossRef Funke U, Lindhauer MG (2001) Effect of reaction conditions and alkyl chain lengths on the properties of hydroxyalkyl starch ethers. Starch Starke 53:547–554CrossRef
13.
Zurück zum Zitat Monson N, Dickson W (1958) Process for preparing oxyalkylated derivatives. US Patent 2854449 Monson N, Dickson W (1958) Process for preparing oxyalkylated derivatives. US Patent 2854449
14.
Zurück zum Zitat Harris G, Leonard R, Weisgerber C (1965) Improvements in an relating to starch derivatives. GB Patent 990886 Harris G, Leonard R, Weisgerber C (1965) Improvements in an relating to starch derivatives. GB Patent 990886
15.
16.
Zurück zum Zitat Lauplaise D, Proverb R, Komarowska K (2001) Use of hydroxyalkylated starches for improved emulsification of sizing agents. US Patent 6210475B1 Lauplaise D, Proverb R, Komarowska K (2001) Use of hydroxyalkylated starches for improved emulsification of sizing agents. US Patent 6210475B1
17.
Zurück zum Zitat Kim HS, Huber KC (2010) Impact of A/B-type granule ratio on reactivity, swelling, gelatinization, and pasting properties of modified wheat starch. Part I. Hydroxypropylation. Carbohydr Polym 80:94–104CrossRef Kim HS, Huber KC (2010) Impact of A/B-type granule ratio on reactivity, swelling, gelatinization, and pasting properties of modified wheat starch. Part I. Hydroxypropylation. Carbohydr Polym 80:94–104CrossRef
18.
Zurück zum Zitat Fuzesi S, Klahs L (1970) Polyurethane foams prepared from starch-based polyether polyols. US Patent 3541034a Fuzesi S, Klahs L (1970) Polyurethane foams prepared from starch-based polyether polyols. US Patent 3541034a
19.
Zurück zum Zitat Fuzesi S, Lapkin M (1970) Polyurethane foams prepared from oxypropylated and higher oxyalkylated starch-phosphorus-containing polyethers. US Patent 3699060 Fuzesi S, Lapkin M (1970) Polyurethane foams prepared from oxypropylated and higher oxyalkylated starch-phosphorus-containing polyethers. US Patent 3699060
20.
Zurück zum Zitat Molotsky H (1986) Starch-based polyether polyols. US Patent 4585858 Molotsky H (1986) Starch-based polyether polyols. US Patent 4585858
21.
Zurück zum Zitat Kwon OJ, Yang SR, Kim DH, Park JS (2007) Characterization of polyurethane foam prepared by using starch as polyol. J Appl Polym Sci 103:1544–1553CrossRef Kwon OJ, Yang SR, Kim DH, Park JS (2007) Characterization of polyurethane foam prepared by using starch as polyol. J Appl Polym Sci 103:1544–1553CrossRef
22.
Zurück zum Zitat Shi X, BeMiller JN (2000) Effect of sulfate and citrate salts on derivatization of amylose and amylopectin during hydroxypropylation of corn starch. Carbohydr Polym 43:333–336CrossRef Shi X, BeMiller JN (2000) Effect of sulfate and citrate salts on derivatization of amylose and amylopectin during hydroxypropylation of corn starch. Carbohydr Polym 43:333–336CrossRef
23.
Zurück zum Zitat Ge J, Zhong W, Guo Z, Li W, Sakai K (2000) Biodegradable polyurethane materials from bark and starch. I. Highly resilient foams. J Appl Polym Sci 77:2575–2580CrossRef Ge J, Zhong W, Guo Z, Li W, Sakai K (2000) Biodegradable polyurethane materials from bark and starch. I. Highly resilient foams. J Appl Polym Sci 77:2575–2580CrossRef
24.
Zurück zum Zitat Cunningham L, Carr ME, Bagleyl EB (1991) Polyurethane foams extended with corn flour. Cereal Chem 68:258–261 Cunningham L, Carr ME, Bagleyl EB (1991) Polyurethane foams extended with corn flour. Cereal Chem 68:258–261
25.
Zurück zum Zitat Brojer Z, Hertz Z, Penczek P (1972) Epoxy resins. WNT, Warsaw (in Polish) Brojer Z, Hertz Z, Penczek P (1972) Epoxy resins. WNT, Warsaw (in Polish)
26.
Zurück zum Zitat Kijowska D, Wołowiec S, Lubczak J (2004) Kinetics and mechanism of initial steps of synthesis of polyetherols from melamine and ethylene carbonate. J Appl Polym Sci 93:294–300CrossRef Kijowska D, Wołowiec S, Lubczak J (2004) Kinetics and mechanism of initial steps of synthesis of polyetherols from melamine and ethylene carbonate. J Appl Polym Sci 93:294–300CrossRef
27.
Zurück zum Zitat PN-93/C-89052.03. Polyethers for polyurethanes. Test methods. Determination of the hydroxyl number. Standards: Ed. Polish Committee for Standardization PN-93/C-89052.03. Polyethers for polyurethanes. Test methods. Determination of the hydroxyl number. Standards: Ed. Polish Committee for Standardization
28.
Zurück zum Zitat Nizioł J, Zieliński Z, Rode W, Ruman T (2013) Matrix-free laser desorption-ionization with silver nanoparticle enhanced steel targets. Int J Mass Spectrom 335:22–32CrossRef Nizioł J, Zieliński Z, Rode W, Ruman T (2013) Matrix-free laser desorption-ionization with silver nanoparticle enhanced steel targets. Int J Mass Spectrom 335:22–32CrossRef
29.
Zurück zum Zitat Broniewski T, Iwasiewicz A, Kapko J, Płaczek W (1967) Test methods and evaluation of plastics properties. WNT, Warsaw Broniewski T, Iwasiewicz A, Kapko J, Płaczek W (1967) Test methods and evaluation of plastics properties. WNT, Warsaw
30.
Zurück zum Zitat Dryński T (1967) Laboratory exercises in physics. PWN, Warsaw Dryński T (1967) Laboratory exercises in physics. PWN, Warsaw
31.
Zurück zum Zitat Cellular Plastics and Rubbers. Determination of apparent (bulk) density, Polish (European) Standards PN-EN ISO 845-2000. Ed. Polish Committee for Standardization Cellular Plastics and Rubbers. Determination of apparent (bulk) density, Polish (European) Standards PN-EN ISO 845-2000. Ed. Polish Committee for Standardization
32.
Zurück zum Zitat Cellular Plastics, Rigid. Determination of water absorption. Polish (European) Standards PN-EN ISO 2896-1986. Ed. Polish Committee for Standardization Cellular Plastics, Rigid. Determination of water absorption. Polish (European) Standards PN-EN ISO 2896-1986. Ed. Polish Committee for Standardization
33.
Zurück zum Zitat Cellular Plastics, Rigid. Test of dimensional stability. Polish (European) Standards PN-EN ISO 2796-1986. Ed. Polish Committee for Standardization Cellular Plastics, Rigid. Test of dimensional stability. Polish (European) Standards PN-EN ISO 2796-1986. Ed. Polish Committee for Standardization
34.
Zurück zum Zitat Cellular Plastics, Compression test for rigid materials. Polish (European) Standards PN-EN ISO 844-1978, Ed. Polish Committee for Standardization Cellular Plastics, Compression test for rigid materials. Polish (European) Standards PN-EN ISO 844-1978, Ed. Polish Committee for Standardization
36.
Zurück zum Zitat Lubczak J, Chmiel-Szukiewicz E, Duliban J, Głowacz-Czerwonka D, Lubczak R, Łukasiewicz B, Zarzyka I, Łodyga A, Tyński P, Minda-Data D, Kozioł M, Majerczyk Z (2014) Polyurethane foams with 1,3,5-triazine ring of improved thermal stability. Przemysł Chemiczny 10:1690–1697 Lubczak J, Chmiel-Szukiewicz E, Duliban J, Głowacz-Czerwonka D, Lubczak R, Łukasiewicz B, Zarzyka I, Łodyga A, Tyński P, Minda-Data D, Kozioł M, Majerczyk Z (2014) Polyurethane foams with 1,3,5-triazine ring of improved thermal stability. Przemysł Chemiczny 10:1690–1697
37.
Zurück zum Zitat Lubczak J (2011) Polyhydroxyalkyl derivatives and polyetherols obtained from azacyclic compounds. Part I. Reactions with oxiranes. Polimery 56:360–368CrossRef Lubczak J (2011) Polyhydroxyalkyl derivatives and polyetherols obtained from azacyclic compounds. Part I. Reactions with oxiranes. Polimery 56:360–368CrossRef
38.
Zurück zum Zitat Lubczak R (2012) Trifuntional oligoetherols and polyurethane foams with carbazole ring. OJOMP 2:1–6 Lubczak R (2012) Trifuntional oligoetherols and polyurethane foams with carbazole ring. OJOMP 2:1–6
39.
Zurück zum Zitat Lubczak R (2012) Oligoetherols and polyurethane foams with carbazole ring. E-Polymers 070:1–11 Lubczak R (2012) Oligoetherols and polyurethane foams with carbazole ring. E-Polymers 070:1–11
40.
Zurück zum Zitat Lubczak R (2015) Polyurethane foams with carbazole ring. Cell Polym 34:15–25CrossRef Lubczak R (2015) Polyurethane foams with carbazole ring. Cell Polym 34:15–25CrossRef
41.
Zurück zum Zitat Lubczak R (2016) Multifunctional oligoetherols and polyurethane foams with carbazole ring. Pol J Chem Technol 18:120–126CrossRef Lubczak R (2016) Multifunctional oligoetherols and polyurethane foams with carbazole ring. Pol J Chem Technol 18:120–126CrossRef
Metadaten
Titel
From starch to oligoetherols and polyurethane foams
verfasst von
Renata Lubczak
Dominik Szczęch
Jacek Lubczak
Publikationsdatum
07.12.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 11/2020
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-019-03052-y

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