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2020 | Buch

Frontiers in Water-Energy-Nexus—Nature-Based Solutions, Advanced Technologies and Best Practices for Environmental Sustainability

Proceedings of the 2nd WaterEnergyNEXUS Conference, November 2018, Salerno, Italy

herausgegeben von: Prof. Dr. Vincenzo Naddeo, Dr. Malini Balakrishnan, Prof. Dr. Kwang-Ho Choo

Verlag: Springer International Publishing

Buchreihe : Advances in Science, Technology & Innovation

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Über dieses Buch

This volume includes selected contributions presented during the 2nd edition of the international conference on WaterEnergyNEXUS which was held in Salerno, Italy in November 2018. This conference was organized by the Sanitary Environmental Engineering Division (SEED) of the University of Salerno (Italy) in cooperation with Advanced Institute of Water Industry at Kyungpook National University (Korea) and with The Energy and Resources Institute, TERI (India). The initiative received the patronage of UNESCO – World Water Association Programme (WWAP) and of the International Water Association (IWA) and was organized with the support of Springer (MENA Publishing Program), Arab Water Council (AWC), Korean Society of Environmental Engineering (KSEE) and Italian Society of Sanitary Environmental Engineering Professors (GITISA). With the support of international experts invited as plenary and keynote speakers, the conference aimed to give a platform for Euro-Mediterranean countries to share and discuss key topics on such water-energy issues through the presentation of nature-based solutions, advanced technologies and best practices for a more sustainable environment. This volume gives a general and brief overview on current research focusing on emerging Water-Energy-Nexus issues and challenges and its potential applications to a variety of environmental problems that are impacting the Euro-Mediterranean zone and surrounding regions. A selection of novel and alternative solutions applied worldwide are included. The volume contains over about one hundred carefully refereed contributions from 44 countries worldwide selected for the conference. Topics covered include (1) Nexus framework and governance, (2) Environmental solutions for the sustainable development of the water sector, (3) future clean energy technologies and systems under water constraints, (4) environmental engineering and management, (5) Implementation and best practices Intended for researchers in environmental engineering, environmental science, chemistry, and civil engineering. This volume is also an invaluable guide for industry professionals working in both water and energy sectors.

Inhaltsverzeichnis

Frontmatter

Nexus Framework and Governance

Frontmatter
Approaching Bioelectrochemical Systems to Real Facilities Within the Framework of CO2 Valorization and Biogas Upgrading

Biogas production within wastewater treatment plants plays a decisive role in the water–energy nexus. Biogas obtained from sewage sludge digestion can be converted into biomethane as CO2 emissions are reduced. Techno-economic assessment of the process is presented. Anodic valorization through chlorine production is performed. Potential impacts of this technology in a wastewater treatment plant are discussed.

Laura Rovira, Pau Batlle-Vilanova, Sebastià Puig, Maria Dolors Balaguer, Pilar Icaran, Victor M. Monsalvo, Frank Rogalla, Jesús Colprim
Water-Energy Nexus in the Gulf: A Complex Network of Multi-level Interdependencies

The Persian/Arabian Gulf plays a critical role in the sustenance of its surrounding countries, home to over two-thirds of the world’s proven oil reserves. With minimal rainfall and natural water sources, these countries rely heavily on desalination of the Gulf for potable water. A new industry is now emerging in the region: nuclear power. This adds another layer of complexity to the preservation of the already stressed Gulf water.

Ghena Alhanaee, Najmedin Meshkati
A Risk Assessment Approach for Water-Energy Systems

Projects aimed at reducing water and/or energy consumption present technical and economic complexity profiles that require the analysis of the many components of investment risk. Risk analysis is essential to express judgements on the economic convenience of projects in the water-energy sectors. It is important to study actions for the mitigation of investment risk, so as to report the residual risk within tolerability limits. The integration of the as low as reasonably practicable (ALARP) logic with the cost-benefit analysis allows to define a protocol for the acceptance of the residual investment risk.

Antonio Nesticò, Gianluigi De Mare, Gabriella Maselli
Estimating the Declining Discount Rate for the Economic Evaluation of Projects in the Energy and Water Sectors

In the cost-benefit analysis (CBA), the declining discount rate (DDR) certainly allows to assign the right weight for the long-term effects of investment projects. The DDR gives the opportunity to properly evaluate projects for sustainable development in the water and energy sectors. The estimation model of the DDR based on probabilistic logic solves the problem of the excessive contraction of the project cash flows that occur in temporal instants that are distant from the evaluation one.

Antonio Nesticò, Gabriella Maselli
Towards Resilience-Informed Decision-Making in Critical Infrastructure Networks

Resilience-informed decision-making is crucial for infrastructure interdependencies management; infrastructure interdependencies management requires shared interventions; resilience-informed interdependency management will support investments’ prioritization for infrastructure improvement.

Maryam Imani, Donya Hajializadeh, Vasos Christodoulides
Short-Term Forecasting of Tank Water Levels Serving Urban Water Distribution Networks with ARIMA Models

Urban water demand forecasting is a powerful supporting tool for specific water utility decision making problems. Among the others, ARIMA is one of the possible approaches to achieve an efficient short-term forecasting.

Claudio Guarnaccia, Carmine Tepedino, Giacomo Viccione, Joseph Quartieri
Energy Balance in the Water Cycle in Italy: State of the Art and Perspectives

Energy consumption for water withdrawal is the main contribution to energy consumption in drinking water supply systems. Energy consumption in large Italian WWTPs should be lower than about 25 kWh PE−1 y−1. Energy recovery in Italian WWTPs takes place mostly by the exploitation of biogas from anaerobic digestion of sewage sludge.

Giorgio Bertanza, Sabrina Sorlini, Mentore Vaccari
Water–Energy Nexus: Evaluation of the Environmental Impact on the National and International Scenarios

Water and energy are two essential resources for our future since these two resources are strongly interconnected. The identification of the future scenarios and the evaluation of the possible impact on the water sector due the production of electricity are essential actions to be performed in order to obtain a picture of possible developments that could affect the national and the international energy scenarios.

Alessia Murena, Laura Borea, Tiziano Zarra, Joanna Boguniewicz-Zablocka, Vincenzo Belgiorno, Vincenzo Naddeo
Water Scarcity and Shale Gas Prospects in Tunisia—Potential Impacts of Hydraulic Fracturing on Regional Water Stress

Hydraulic fracturing of shale plays requires large quantities of water and could pollute water resources, which is especially problematic in the water-scarce North African context. This study investigates the potential impacts of fracking on regional water stress in Tunisia by forecasting shale development and water stress for two key regions. To also understand the political economy of shale gas in Tunisia, experts from different backgrounds were interviewed. The results show that fracking could add important volumes to regional water demand, especially in peak drilling years. However, water concerns are of secondary importance to decision-makers, and the promise of economic benefits weighs heavier, increasing the likelihood of shale gas development.

Lisa Murken
Energy Performance of Italian Urban Water Systems

Relationships between energy consumption and characteristic data of the urban water system in Italy have been researched.

L. Mancusi, M. Volonterio, E. Garofalo
Analysis of the Economic Net Benefit of Green Infrastructure by Comparing the Water-Retentive Block and the Normal Block

Evaluation of water-retentive block and normal block to derive the net benefit of green infrastructure.

Kyeonjae Woo, Bae Woo Bin, Ko Jong Hwan, Kim Sang Rae, Kim Yong Gil
Levering Industry and Professional Qualifications Over Water Efficiency and Water–Energy Nexus in Buildings

Skills for water efficiency and water–energy nexus in building construction and retrofit; skill upgrading of construction and green professionals on water efficiency and water–energy nexus.

Ana Poças, Pedro Cardoso, Filipa Newton, Diogo Beirão, Charalampos Malamatenios, Georgia Veziryiani, Esther Rodriguez, Javier González, Rossella Martino, Diego De Gisi
WEFSiM: A Model for Water–Energy–Food Nexus Simulation and Optimization

A Water-Energy-Food Nexus Simulation Model (WEFSiM) is proposed to quantify the nation-wide resources sustainability. WEFSiM considers the feedback connections between water, energy, and food sectors in a single framework. The optimization module provides more alternatives for resource management planning. The effect of a new energy plan in South Korea (Energy 2030) is simulated in a nexus perspective.

Albert Wicaksono, Gimoon Jeong, Doosun Kang
Assessment of Rain Harvesting and RES Desalination for Meeting Water Needs in an Island in Greece

Three different scenarios for meeting domestic water demand in a small island in Greece were examined and compared. Life-cycle cost analysis was performed in order to evaluate each scenario from an economic point of view.

Konstantinos Kotsifakis, Ioannis Kourtis, Elissavet Feloni, Evangelos Baltas
Grounding Nexus Governance: De-Nexused Developments in Nepal

There appears to be little agreement on the precise meaning of the nexus, whether it only complements existing environmental governance approaches or how it can be enhanced in national contexts. Technical solutions for improving coherence and governance within the nexus may have unintended and negative impacts in other policy areas, such as poverty alleviation. The nexus is yet to be extensively grounded, into national policies and practices, and broad-based local demand for nexus-framed policies is currently limited. Through a mini-case study in Nepal, this article seeks to analyse what is the local understanding and practice around the relationship between food, energy and water to inform nexus thinking and practice. These mini-case studies will inform us on the interaction between formal and informal institutional arrangement and how these interactions form the basis of a nexus system.

Dipak Gyawali, Jeremy Allouche
Maximizing Water–Food–Energy Nexus Synergies at Basin Scale

In this short paper, we show how solutions for mitigating resource security in one sector can be found in another. We demonstrate—by means of a case study in Burkina Faso and Ghana—how investing in the electricity grid in the south leads to increase food security in the north. A new nexus framework was developed (‘MAXUS’) which was built to understand, simulate and optimize intersectoral (and international) development strategies in the water, food and energy sectors. We believe this new type of geospatial integral resource management, supported by the exponential increase of data availability of the twenty-first century, could finally turn nexus models into decision support tools.

Rogier E. A. Burger, Edo Abraham
Visualizing CO2 to Account for Emission Obligation in Power Systems

The electricity use is a significant part of human’s environmental footprint. Fossil energy is still used as the major energy resource for power generation. Policy makers seek a remedy to mitigate carbon emissions of fossil fuels. A virtual carbon emission tracing method is discussed in this paper. This paper facilitates allotting carbon obligation in power systems.

Mahdi Rouholamini, Carol Miller, Caisheng Wang, Mohsen Mohammadian, Mohammadamin Moghbeli
Selection of Key Characteristics for Crops to Deal with Climate Change Through Quality Function Deployment

The use of genetically modified (GM) varieties represents the best strategy to adapt to climate change. The use of quality function deployment (QFD) provides a simple tool for decision taking. The characteristics of water, soil, chemical fertilizers, pesticides, and herbicides are indispensable criteria in the selection of adaptation alternatives.

A. Robayo Avendaño, D. Prato Garcia
Combined Electrodialysis and Photo-Electro-Chlorination for Energy Efficient Control of Brine Water

A combined electrodialysis and photo-electro-chlorination process was evaluated. The current efficiency of the chlorine evolution reaction increased with the [Cl−]. UV/Chlorine boost the oxidation rate of recalcitrant organic compounds.

Hyeonjeong Kim, Wonyong Choi, Kangwoo Cho

Advanced Technologies or Nature-Based Solutions for the Environmental Sustainability of the Water Sector

Frontmatter
Hydrogen Production in Electro Membrane Bioreactors

Reduction of organic and nutrient compounds. Membrane fouling control through the decrease of membrane fouling precursors and quorum sensing. Energy production in terms of hydrogen.

Laura Borea, Fabiano Castrogiovanni, Giovanna Ferro, Shadi Wajih Hasan, Vincenzo Belgiorno, Vincenzo Naddeo
Use of High-Valent Metal Species Produced by the Fenton (-like) Reactions in Water Treatment

The iron- and copper-based Fenton (-like) reactions produce high-valent metal species (ferryl and cupryl ions). Ferryl and cupryl ions as reactive oxidants are capable of oxidizing refractory organic compounds in water. Ferryl and cupryl ions can be used for the inactivation of microorganisms in both planktonic and biofilm states.

Changha Lee
Photocatalytic Oxidation of Organic Compounds by Visible Light-Illuminated g-C3N4-AQ in Combination with Fe(III)

A visible light-responsive photocatalyst (g-C3N4-AQ) has been synthesized. g-C3N4-AQ produces hydrogen peroxide with the response to visible light. g-C3N4-AQ in combination with Fe(III) produces hydroxyl radical by Fenton-like reaction. Fe(III) accelerates the hole oxidation reaction at the valence band (VB) by capturing electrons at the conduction band (CB).

Jiwon Seo, Soo Yeon Park, Hak-Hyeon Kim, Changha Lee
Microalgae-Based Processes as an Energy Efficient Platform for Water Reclamation and Resource Recovery

Microalgae provide a low-cost and environmentally friendly oxygenation. Enhanced nutrient recovery as a result of the dual photoautotrophic and heterotrophic metabolism. Microalgae can turn the energy balance of conventional wastewater treatment into positive. Microalgae-based processes can be engineered into multiple configurations. Wastewater treatment and biogas upgrading can be combined in algal-bacterial photobioreactors.

María del Rosario Rodero, Roxana Ángeles, Victor Pérez, Juan Gancedo, Silvia Bolado, Raquel Lebrero, Raúl Muñoz
Ozonation in the Framework of Sustainable Future Water Management

A resourceful and continuously operating ozonation-biofiltration column experimental set-up was built and tested. The set-up is useful for predictions on the fate of ozonation products under different conditions and process configurations. Computational fluid dynamics (CFD) modelling helps to better understand and quantify the membrane-facilitated mass transfer of ozone into water. Modelling and experimental approaches provide the basis for establishing more efficient membrane ozonation processes.

Jannis Wenk, Garyfalia A. Zoumpouli, John Y. M. Chew
Pilot Study for Spiral Wound-PVDF Supported UF Membranes for Brackish Water Desalination System

Groundwater availability in Egypt and its quality. RO pretreatment of groundwater to secure drinking water. Large-scale production of flat sheet UF membranes and its evaluation. Spiral wound 4040 modules preparation and its application in the real continuous system.

M. S. Shalaby, H. Abdallah, Ahmed M. H. Shaban
Energy Monitoring of a Wastewater Treatment Plant in Salerno, Campania Region (Southern Italy)

Results of an energy audit on a large wastewater treatment plant (wwtp) are shown; critical issues related to the use of energy resources in this plant are identified; parasitic inflows negatively affect the plant performances and a distinction between organic and hydraulic load is a useful tool in describing this problem.

Maria Rosa di Cicco, Antonio Spagnuolo, Antonio Masiello, Carmela Vetromile, Carmine Lubritto, Mariano Nappa, Gaetano Corbo
Sulfate Radicals-Based Technology as a Promising Strategy for Wastewater Management

Successful persulfate activation by iron was achieved. Amberlite was demonstrated to be a suitable support for obtaining an efficient iron catalyst. Electro-activation of peroxymonosulfate in the presence of iron-based minerals as catalyst was developed. Reusability of heterogeneous catalysts was demonstrated. Lissamine Green B and 1-butyl-1-methylpyrrolidinium chloride removal through sulfate radicals was accomplished.

María Arellano, M. Ángeles Sanromán, Marta Pazos
Fluoxetine and Pirimicarb Abatement by Ecofriendly Electro-Fenton Process

Electro-Fenton generation of ·OH is more efficient and significant than the ·OH produced in the anode surface by anodic oxidation. Electro-Fenton process was optimised determining the relationship among key variables as electrodes surface and stirring rate. At optimal conditions, the combination of fluoxetine and pirimicarb was easily degraded with high mineralisation level.

Emílio Rosales, António Soares, G. Buftia, Marta Pazos, G. Lazar, Cristina Delerue-Matos, M. Ángeles Sanromán
Diversity and Performance of Sulphate-Reducing Bacteria in Acid Mine Drainage Remediation Systems

Microbial diversity in acid mine drainage from eMalahleni, Mpumalanga, South Africa. Enrichment of SRB improves its performance in sulphate reduction. Microbial community shows synergy between SRB Proteobacteria and facultative Bacilli. Sulphate reduction of 85% and cadmium reduction of 98% were observed within 7 days of continuous operational mode. The microbial community showed wider substrates utilisation.

Enoch A. Akinpelu, Elvis Fosso-Kankeu, Frans Waanders, Justine O. Angadam, Seteno K. O. Ntwampe
Sustainable Materials for Affordable Point-of-Use Water Purification

Nanoscale ferrihydrite incorporated biopolymeric composites prepared for arsenic removal from water. Composite shows excellent adsorption capacities for both arsenite and arsenate (overall >100 mg/g). Low dosage of the composite shows very fast kinetics over a wide pH range of water sample. The green synthesis yields a thermally stable composite with very high mechanical strength. This robust nanocomposite is industrially viable and offers an affordable and sustainable solution to arsenic contamination.

Sritama Mukherjee, Ligy Philip, Thalappil Pradeep
Self-Forming Dynamic Membrane: A Review

This paper presents self-forming dynamic membrane (SFDM) process as a promising alternative to membrane technology. A stable dynamic membrane (DM) is mainly composed of gel layer and cake layer which are responsible for filtration and biodegradation. An understanding of the formation mechanism and impact of operating conditions, support mesh, sludge properties and configuration on the formation, and characteristics of the dynamic membrane is essential to optimize the efficiency and reduce fouling propensity of this technology. The paper thus aims to promote its applicability on wastewater treatment. Review of the influence of mesh support properties, different operating conditions and sludge properties on SFDM performance, and cost comparison between MBR and SFDMBR technologies.

J. M. J. Millanar-Marfa, Laura Borea, Mark Daniel G. De Luna, Vincenzo Belgiorno, Vincenzo Naddeo
Influence of Membrane Flux, Ultrasonic Frequency and Recycle Ratio in the Hybrid Process USAMe

This paper focused on the combination of membrane ultrafiltration, adsorption and ultrasound processes in one hybrid process called USAMe for improving membrane wastewater treatment performance and membrane fouling control. Different tests were conducted at different ultrasound frequencies and recycle ratio. Improved permeate quality in the USAMe process. Membrane fouling reduction with the combined application of ultrasound and activated carbon. Influence of ultrasound frequency, membrane flux and recycle ratio on treatment performance.

Laura Borea, Vincenzo Naddeo, Vincenzo Belgiorno
Using Water–Energy Nexus as Greenhouse Gas Emissions Mitigation Tool in Wastewater Treatment Plants

Climate change mitigation in the integral water cycle. WWTPs as energy producers. Use of the plant intrinsic energy. Integration of renewable energies in WWTPs. Water–energy nexus as greenhouse gas emissions reduction tool.

B. Del Río-Gamero, A. Ramos-Martín, N. Melián-Martel, S. O. Pérez-Baez
Corrosion Behavior of Carbon Steel in the Presence of Escherichia coli and Pseudomonas fluorescens Biofilm in Reclaimed Water

The results show that compared with Escherichia coli promoting corrosion and Pseudomonas fluorescens inhibiting corrosion, in mixed bacteria, the average corrosion rate of carbon steel is reduced by 25.66%. Corrosion current density (Icorr) decreases and the diameter of Nyquist plots increases with time. Meanwhile, the dominant bacteria in mixed condition is verified with different phases. Extracellular polymeric substances (EPS) of E. coli promote the growth of P. fluorescens, and EPS of P. fluorescens can inhibit the growth of E. coli at 400 mg L−1. Scanning electron microscope (SEM) and X-ray diffraction (XRD) demonstrate that the transformation of corrosion products makes the biofilm-corrosion products film formed on the surface of carbon steel more compact in mixed bacteria.

Ping Xu, Yumin Ou, Zhigang Wei
Development of Pilot-Scale Photocatalytic Reactor Employing Novel TiO2 Epoxy Grains for Wastewater Treatment

High-density TiO2 epoxy grains for easy gravitational separation after treatment ends. Passive aeration for maintaining high DO levels. Degradation rate constant and reactor throughput as benchmarks for reactor performance. Water turbidity indicator for photocatalyst resistance to abrasion. Promising for scale-up: modular design, integrated storage, no UV transmitting parts.

Yasmine Abdel-Maksoud, Emad Imam, Adham Ramadan
Evaluation of Fungal White-Rot Strains for Assisting in Algal Harvest in Wastewater

Microalgae co-cultured with certain filamentous fungi form biopellets. Biopellets can be used in microalgae harvesting and in water treatment. White-rot fungi producing laccase are of interest for water treatment. In suitable environmental conditions, certain white-rot fungi can form biopellets with microalgae.

M Hultberg, H Bodin
Event Scale Modeling of Experimental Green Roofs Runoff in a Mediterranean Environment

Event scale analysis of green roofs hydrological performances in a Mediterranean environment. Different green roofs constructive technologies are investigated. Different hydrological models are applied to identify pros and cons of empirical and physically based models.

Mirka Mobilia, Antonia Longobardi
Advanced Technologies for Satellite Monitoring of Water Resources

Exploitation of synthetic aperture radar satellite data. Monitoring of surface water resources with high resolution in time and space. Low-cost technic for freshwater monitoring. Appropriate technology for developing countries. Retrieval of river features: active channels, sediment bars and wet channels.

Maria Nicolina Papa, Giuseppe Ruello, Francesco Mitidieri, Donato Amitrano
Tannery Wastewater Treatment After Biological Pretreatment by Using Electrochemical Oxidation

Tanning industry is receiving a lot of attention due to its pollution levels and discharge legislations toward the environment. Tanerry wastewater treatment by using electrochemical oxidation with SnO2/Ti and PbO2/Ti anodes. The tannery wastewater was pretreated using biological method with aerotank process. SnO2/Ti and PbO2/Ti anodes effectively treated COD and total nitrogen over 85% after 90 min of electrolysis. The treatment efficiency in tannery wastewater of SnO2/Ti anode is greater than PbO2/Ti anode.

Tran Le Luu, Tran Tan Tien, Nguyen Ba Duong, Nguyen Thi Thanh Phuong
Numerical Modelling of Integrated OMBR-NF Hybrid System for Simultaneous Wastewater Reclamation and Brine Management

OMBR is a recently developed technology for wastewater treatment. OMBR-NF hybrid system was numerically modelled. Influence of process variables on system performance indicators was investigated.

Shadi Wajih Hasan, Vincenzo Naddeo
Climate, Soil Moisture and Drainage Layer Properties Impact on Green Roofs in a Mediterranean Environment

Analysis of event scale hydrological performances of green roofs in a Mediterranean environment. Different green roofs constructive technologies are investigated. Observed soil water contents help describe the impact of cumulative rainfall depth and duration on green roofs hydrological performances.

Mirka Mobilia, Roberta D’Ambrosio, Antonia Longobardi
Orthophosphate Versus Bicarbonate for Buffering the Acidification in a Bromide Enhanced Ozonation of Ammonia Nitrogen

The acidification in the process of ammonia nitrogen oxidation must be prevented. The superiority of orthophosphate versus bicarbonate was demonstrated. Ammonia nitrogen removal rate in the presence of $${{\text{HPO}}_{4}}^{ = } /{\text{H}}_{2} {{{\text{PO}}_{4}}^{ - }}$$ increased by 15%. Nitrate generation in the presence of $${{\text{HPO}}_{4}}^{ = } /{\text{H}}_{2} {{{\text{PO}}_{4}}^{ - }}$$ decreased by 50%. Presence of $${{\text{HPO}}_{4}}^{ = } /{\text{H}}_{2} {{{\text{PO}}_{4}}^{ - }}$$ limited the generation of bromate to 0.04% of the bromate yield.

Barbara Ruffino, Maria Chiara Zanetti
New Approach with Fluidized Bed Reactor Using Low-Cost Pyrophyllite/Alumina Composite Membrane for Real-Metal Plating Wastewater Treatment

Hybrid fluidized bed ceramic membrane reactor was developed using low-cost pyrophyllite/alumina composite membrane with GAC particles as fluidized media to treat real metal-plating wastewater. With GAC fluidization, both uncoated and coated ceramic membranes achieved more than 90% of COD removal efficiency. There was no occurrence in membrane fouling under GAC fluidization during one-day of system operation for both membranes.

Soomin Chang, Deaeun Kwon, Jeonghwan Kim
Impact of Seasonality on Quorum Quenching Efficacy and Stability for Biofouling Control in Membrane Bioreactors

Low temperatures produce more biopolymers, leading to severe biofouling. Moving QQ sheets mitigate biofouling under cold weather conditions. QQ activities drop sharply with decreasing water temperatures. QQ sheets remain active during long-term field tests using real wastewater. QQ sheets have no impact on activated sludge treatment performance.

Kibaek Lee, Jun-Seong Park, Tahir Iqbal, Chang Hyun Nahm, Pyung-Kyu Park, Kwang-Ho Choo
Surface Modification of RO Desalination Membrane Using ZnO Nanoparticles of Different Morphologies to Mitigate Fouling

Chemical modification of different morphologies of ZnO nanoparticles (spherical, flowers). Modification of thin-film composite (TFC) using ZnO nanoparticles by surface coating. Measured flux, NaCl rejection and hydrophilicity. Fouling resistance studies on unmodified and modified membrane. Best membrane performance was observed with 0.02 wt% ZnO-S-modified membrane.

Revathy Rajakumaran, Boddu Vinisha, Mathava Kumar, Raghuram Chetty
Nutrient Removal and Biomass Production by Immobilized Chlorella Vulgaris

Immobilized cells of Chlorella vulgaris in alginate–chitosan matrix achieved faster growth rates and produced more biomass than their free cell counterpart in synthetic aquaculture wastewater. Higher (89.8%) nitrate-N removal was achieved by immobilized cells than by the free cells (45.9%). Phosphate-P removal was both high at 98.9 and 99.5% by immobilized and free cells, respectively. The alginate–chitosan matrix was found suitable for growth, nutrient removal, and biomass production in synthetic aquaculture wastewater.

Marion Lux Y. Castro, Florencio C. Ballesteros Jr.
Treatment of Printed Circuit Board Wastewater Containing Copper and Nickel Ions by Fluidized-Bed Homogeneous Granulation Process

In this study, treatment of synthetic printed circuit board wastewater containing copper and nickel ions was done through fluidized-bed homogeneous granulation process (FBHGP). The treatment occurred in a single reactor, removing and granulating both copper and nickel ions at the same period of time. The effect of total carbonate loading (10, 12, 15, 17, 20 mM) on the treatment of Cu2+ (6.3 mM) and Ni2+ (3.4 mM) was evaluated in this study with initial precipitant flow rate of 15 mL/min and initial operating pH of 6.5 and shifted to 8.5 pH on the given period of time. The synthetic wastewater containing copper and nickel ions had better result in terms of size of recovered granules, removal and granulation efficiencies when 17 mM of CO3 was employed in the system, resulting to copper removal of 97.5%, copper granulation of 93.1% and nickel removal and granulation efficiencies of 81.2 and 73.6%, respectively. The granules recovered were >0.42 mm in size with rough surface and EDX analysis identified the presence of oxygen, copper and nickel.

Nathaniel E. Quimada, Mark Daniel G. De Luna, Ming-Chun Lu
Investigation of the Synthesis and Adsorption Kinetics of Biochar-Supported Fe3-XMnxO4 for Imidacloprid Pesticide Removal

Simple synthesis procedure for biochar-supported Fe3-xMnxO4 was conducted. Synthesis conditions were examined for optimal metal impregnation yield. Kinetics of adsorption was investigated for imidacloprid removal.

Mark Daniel G. De Luna, Michael M. Sablas, Chiu-Wen Chen, Cheng-Di Dong
A Kinetic Study of Calcium Carbonate Granulation Through Fluidized-Bed Homogeneous Process for Removal of Calcium-Hardness from Raw and Tap Waters

Fluidized-bed technology had been greatly employed to treat wastewater by removal of heavy metals, nutrients, and dissolved minerals through granulation or crystallization. This work focuses to imply the technology of fluidized-bed homogeneous granulation process to remove hardness from raw and tap waters. The paper investigated the granulation kinetics of CaCO3 through fluidized-bed homogeneous granulation (FBHG) process during the homogenous nucleation stage. The mechanism followed the pseudo-second-order (PSO) kinetics, that calcium cation attracts to carbonate anion to form particle of CaCO3 through double displacement chemical reaction. The calcium-to-carbonate molar ratio ([Ca2+]/[ $${{\text{CO}}_{3}}^{2 - }$$ ]) was varied into 1.25, 1.50, 1.75, 2.00, 2.25, and 2.50, with constant values of operating pH = 10 ± 0.2, influent carbonate concentration ([ $${{\text{CO}}_{3}}^{2 - }$$ ]) = 10 mM and total influx flow rate (QT) = 60 mL min−1.

Arianne S. Sioson, Mark Daniel G. De Luna, Ming-Chun Lu
Destruction of Selected Pharmaceuticals with Peroxydisulfate (PDS): An Influence of PDS Activation Methods

The presence of pharmaceuticals’ residual in water is considered as a serious environmental problem. Two of them, i.e., paracetamol and diclofenac were treated with peroxydisulfate activated with ferrous ions and copper oxide. The degradation rates of both compounds versus type activators applied were evaluated by the means of changes of pharmaceutical concentration as well as observed changes of nitrite and nitrate concentrations in the reaction mixtures during the oxidation processes. The results clearly show that paracetamol was relatively easily decomposed independently from the type of PDS activator applied, contrary to the diclofenac, which was more resistant to the oxidation, especially, when CuO activation was used.

Robert Wolski, Monika Półtorak, Iwona Rykowska, Sławomir Kaczmarek, Przemysław Andrzejewski
Non-destructive In Situ Fouling Monitoring in Membrane Processes

Fouling is considered the bottleneck of membrane systems. In this study, the fouling occuring in different membrane processes and configurations was studied by using Optical Coherence Tomography (OCT). Fouling formation in membrane system was assessed and quantified non-invasively during operation. The use of the OCT enabled monitoring fouling evolution and correlating it to the membrane performance decline.

L. Fortunato, S. Jeong, T. Leiknes
Preparation of TiO2/SiO2 Ceramic Membranes Via Solgel Dip Coating for the Treatment of Produced Wastewater

TiO2-based commercial membranes were coated with SiO2 nanoparticles using solgel dip coating. Membranes were characterized using FTIR, SEM, contact angle and were also tested for the COD removal efficiency. Membrane coating was confirmed from FTIR spectra. SiO2 coating enhanced membranes hydrophilicity.

Sarah S. Marzouk, Fawzi Banat, Shadi Wajih Hasan
Multicriteria Evaluation of Novel Technologies for Organic Micropollutants Removal in Advanced Water Reclamation Schemes for Indirect Potable Reuse

Multicriteria evaluation based on technical, economic and environmental assessment shows the benefits and limitations of novel PAC-NF systems versus conventional UF-RO (50%) systems.

C. Echevarría, I. Martin, M. Arnaldos, X. Bernat, C. Valderrama, J. L. Cortina
Environmental or Economic Considerations in Photo-Fenton Processes: What Choice Has the Most Notable Benefits for Large-Scale Applications?

A marginal increase in operational costs led to a 45% reduction in carbon footprint. Life cycle assessment and multivariable analysis allow identifying an economic and environmentally friendly operational condition. Photo-Fenton in raceway reactors increases biodegradability of recalcitrant effluents at a low cost (0.33 US$/m3).

D. Prato Garcia, A. Robayo Avendaño
Optimization of Energy Consumption in Activated Sludge Process Using Deep Learning Selective Modeling

Optimization of Energy consumption in activated sludge plants. Selection approach of the best observation that will be used in a supervised deep learning model. The model was applied to learning and validation period in order to show its performance.

Rafik Oulebsir, Abdelouahab Lefkir, Abdelmalek Bermad, Abdelhamid Safri
Electrochemical Sensors for Emerging Contaminants: Diclofenac Preconcentration and Detection on Paper-Based Electrodes

A paper-based electrochemical sensor has been developed as a green tool for analysis of diclofenac. The electrochemical behaviour of diclofenac has been studied on carbon-paper-based electrodes. A miniaturized device combining paper electrodes and reusable connections allows to perform decentralized analysis. The employment of a paper-based electrode allows simple on-site preconcentration of the analyte improving the sensitivity of the methodology.

E. Costa-Rama, Henri P. A. Nouws, Cristina Delerue-Matos, M. C. Blanco-López, M. T. Fernández-Abedul
Optimization of the Wastewater Treatment Plant: From Energy Saving to Environmental Impact Mitigation

This paper outlines a multi-objective, integrated approach to analyse various possibilities for increasing energy efficiency of the largest Italian wastewater treatment plant (WWTP) at Castiglione Torinese. In this approach, wastewater and sludge treatment units are thoroughly investigated to find the potential ways for improving the energy efficiency of the system. Firstly, a multi-step simulation-based methodology is proposed to make a full link between treatment processes and the energy demand and production. Further, a scenario-based optimization approach is proposed to find the non-dominated and optimized performance of the WWTP. The results prove a potential to save up to 5000 MWh of the annual energy consumption of the plant, in addition to improve the effluent quality through operational changes only. Even for what concerns the sludge line a model was proposed for the optimization of the energy recovery from the processes that in a WWTP are devoted to the management of sewage sludge. The obtained results show that the introduction of an advanced thickening stage and sludge pre-treatment, together with the optimized production and use of biomethane, would have a positive impact on the energy and greenhouse gas balance of the plant. The preliminary tests were conducted with microalgae, under different light intensities (3 and 5 fluorescent lamps equal to 44 and 76 μmol/m2/s), that had shown a total CO2 reduction of 80 and 70%, respectively.

D. Panepinto, V. Riggio, Barbara Ruffino, G. Campo, A. Cerutti, S. Borzooei, M. Ravina, I. Bianco, Maria Chiara Zanetti
Influence of Microalgae–Bacteria Consortium on Pathogens Removal (Pseudomonas aeruginosa and Escherichia coli) from Domestic Wastewater

The potential of microalgae, bacteria, and a microalgae–bacteria consortium for the removal of Pseudomonas aeruginosa and Escherichia coli during domestic wastewater treatment was investigated; P. aeruginosa was removed mainly by microalgae action when in the microalgae–bacteria consortium; E. coli was removed by both microalgae and bacterial action; The effect of the LEDs was higher on E. coli than P. aeruginosa removal; The symbiotic system is more advantageous than just microalgae system, because the biomass productivity is higher and pathogens removal is almost similar for both systems.

Graziele Ruas, Mayara Leite Serejo, Priscila Guenka Scarcelli, Marc Árpád Boncz
Fuzzy-Assisted Ultrafiltration of Wastewater from Milk Industries

The whey is a by-product rich in organic substances; the system, as conceived, is self-learning.

Francesco Villecco, Rita Patrizia Aquino, Vincenza Calabrò, Maria Ida Corrente, Antonio Grasso, Vincenzo Naddeo
Performance of Electro-Fenton Water Treatment Technology in Decreasing Zebrafish Embryotoxicity Elicited by a Mixture of Organic Contaminants

Electro-Fenton technology was able to decrease zebrafish embryotoxicity of fluoxetine and pirimicarb, when single or in mixture.

João Amorim, Carlos Pinheiro, Isabel Abreu, Pedro Rodrigues, M. Ángeles Sanromán, Emílio Rosales, Marta Pazos, António Soares, Cristina Delerue-Matos, Aurélia Saraiva, Luís Oliva-Teles, António Paulo Carvalho, Laura Guimarães
An Overview of Photocatalytic Drinking Water Treatment

Photocatalytic disinfection of Escherichia coli was assessed. Removal of natural organic matter by advanced oxidation processes more specifically photocatalysis was considered. Application of first-, second- as well as third-generation photocatalysts was evaluated. Photocatalytic degradation process was evaluated for drinking water quality aspects.

Miray Bekbolet
Solar Light-Initiated Photoinactivation of E. coli: Influence of Natural Organic Matter

Increasing need for clean potable water around the world, have led researchers to focus on water disinfection using natural and/or artificial sunlight for the inactivation of a wide range of microorganisms. In this study solar light-initiated photoinactivation of pathogenic bacteria i.e. Escherichia coli (E. coli). The effect of natural organic matter (NOM) type and water matrix was evaluated. Both NOM and bacteria removal by solar irradiation was followed by UV-vis and fluorescence spectroscopic analysis to characterize NOM and reveal inactivation data of E. coli to kinetics.

Ceyda S. Uyguner-Demirel, Ezgi Lale, Nazmiye Cemre Birben, Miray Bekbolet
Molecular Size Distribution Profiles of Organic Matrix in Reverse Osmosis Concentrate Under Oxidative and Non-oxidative Conditions

Photolytic/photocatalytic degradation of synthetic ROC samples was evaluated. Role of various photocatalysts on ROC degradation was evaluated. Molecular size fractionation was performed following photodegradation/photocatalytic degradation. Advanced fluorescence techniques used for detecting changes in fluorophores.

Nazmiye Cemre Birben, Miray Bekbolet
Solar Photocatalytic Degradation of Humic Acids Using Copper-Doped TiO2

Preparation of undoped and Cu-doped TiO2 photocatalysts using sol–gel method. Characterization of photocatalysts using XRD, SEM, XPS, UV-DRS, BET and FTIR techniques. Visible light photocatalytic degradation of humic acid in drinking water. Investigation of degradation pathway using humic acid fluorescence excitation emission matrix contour plots. Evaluation of adsorption characteristics of TiO2 photocatalysts on humic acid solution.

Miray Bekbolet, Nazli Turkten
Hyperspectral Monitoring of a Constructed Wetland as a Tertiary Treatment in a Wastewater Treatment Plant for Domestic Sewage

Constructed wetlands are an efficient technology for wastewater treatment; environmental monitoring via the analysis of hyperspectral data has a huge potentiality; vegetation indices make it possible to synthesize reflectance characteristics related to health state.

Agostina Chiavola, Cecilia Bagolan, Monica Moroni, Simona Bongirolami
Applicability of WQI and Scientific Communication for Conservation of River Ganga System in India

Water one of the most important vital source for the survival of living forms on earth. In the last two decades, a rapid increase in population has given a tremendous increase in uncontrolled development activities leading to the destruction of all major water bodies on earth. River Ganga System, covering 2525 km from the Himalayas to the Bay of Bengal nourishing millions of peoples of India and one of the major source of water and other use in India. With its tremendous use and importance, it is very much important to monitor it on regular basis and categorize its water quality on the basis of water quality indexing. This categorization will help to aware mass depended on the water body for various uses and to policy makers to improve the decision-making system for the betterment of the River Ganga System for its conservation and rejuvenation.

Gagan Matta
Techno-Economic Feasibility of Membrane Bioreactor (MBR)

MBR CAPEX is higher than CAS+coagulation CAPEX; MBR OPEX is lower than CAS CAPEX; MBR may be economically competitive with CAS+coagulation systems.

Paolo Roccaro, Federico G. A. Vagliasindi
Electrochemical Wastewater Treatment with SnO2-Based Electrodes: A Review

This review paper focuses on discussing SnO2-based electrodes with regard to the stability, their application to water treatment. The approaches have been based on developing new doping routes, new fabrication routes, or combining TiO2 nanotubes with SnO2 catalyst. Operation parameters also need considering thoroughly when SnO2 electrodes are applied to treat wastewater. More effort should be put on optimizing the catalysts and the preparation routes. SnO2-based electrode is a very promise electrode material for electrochemical wastewater treatment.

Duong Hieu Linh, Tran Le Luu

Control of Hazardous Substances in Water and Recovery of Renewable/Valuable Resources from Wastewater

Frontmatter
Statistical Analysis of the Quality Indicators of the Danube River Water (in Romania)

Analysis of the distribution of the water quality indicators of the Danube River during the period 2010–2012 for the surface water in Chiciu area (km 375). Analysis of the correlation of the quality indicators at the observation points. Similarity and dissimilarity studies of the parameters’ series at the observation points. Mathematical modeling of the indicators series.

Alina Bărbulescu, Lucica Barbeş, Anita Dani
Statistical Analysis of the Water Quality of the Major Rivers in India

This study presents a longitudinal analysis of pollution profiles of rivers in India. Pollution profiles of 40 in India are created based on the levels of the biochemical oxygen demand (BOD). The cluster analysis has been used to represent groups of rivers with similar levels of pollutants. The longitudinal analysis has been used to reveal how the profiles change over six years from 2007 to 2012. The analysis is used for detecting rivers which remained polluted throughout.

Anita Dani, Alina Bărbulescu
Methane and Hydrogen Production from Cotton Wastes in Dark Fermentation Process Under Anaerobic and Microaerobic Conditions

Dark fermentation of textile wastes is discussed in the paper. The fermentation was carried out under the following conditions: load 5 g/L, pH was varied in the range 6.23–7.8, and oxygen in small quantities was added. The oxygen flow rates (OFR) were between 1 and 4.6 mL/h. The highest volumes of methane were obtained under anaerobic conditions (pH 6.23 and 7.8), while production of hydrogen was larger under oxygen flow rate 4.6 mL/h and pH value 6.23.

Gaweł Sołowski, Izabela Konkol, Adam Cenian
Microalgae Production Coupled with Simulated Blackwater Treatment

Efficiency of simulated blackwater treatment by UASB was analyzed. Removal of N, P, and DOC by Chlorella sorokiniana was evaluated. Total ammonia removal was obtained.

Luan de Souza Leite, Maria Teresa Hoffmann, Luiz Antonio Daniel
Waterborne Diseases in Sebou Watershed

Starting from an extremely important territory from an ecological and socioeconomic point of view but subject to a strong constraint linked to anthropic pressures. We show in this work how global change has the potential to affect human health through the deterioration of water quality.

Rachida El Morabet, Mohamed Aneflouss, Said El Mouak
Chances and Barriers of Wastewater Heat Recovery from a Multidisciplinary Perspective

The heating sector is a key energy sector in the European Union. Wastewater contains significant amounts of thermal energy. Heat recovery from wastewater can support the energy transition. Wastewater heat recovery concerns a multitude of different disciplines.

Florian Kretschmer, Thomas Ertl
Mine Water in the Closure of a Coal Basin: From Waste to Potential Resources

The closure of the coal mines originates underground water reservoirs. The stored water can be used to produce energy. The water is at a temperature between 20 and 25 °C. A potential use consists in the production of thermal energy with heat pump.

Javier Menéndez, Jorge Loredo
Water Pollution by Polychlorinated Biphenyls from the Energy Sector of Armenia

Polychlorinated biphenyls (PCBs) were wildly used in electrical equipment of various types in the industry, power engineering and other branches of National Economy. Being absorbed from water and accumulated in media and tissue to concentrations greater than those found in surrounding water, PCBs bioaccumulate and increase up the food chain. The greatest danger to environment and people originates from lack of information about the related hazards among owners of PCB and PCB-filled equipment. Monitoring study was performed on surface waters, bottom sediment, foodstuffs, and soil samples. PCBs accumulation occurred from the lower to the higher trophic level.

A. Aleksandryan, A. Khachatryan, Yu. Bunyatyan
Semi-continuous Anaerobic Digestion of Orange Peel Waste: Preliminary Results

Orange peel waste (OPW) is a promising substrate for anaerobic digestion. The problems related to the presence of d-Limonene in OPW need to be overcome. Alkaline pretreatment of OPW and addition of granular activated carbon are promising remedies.

Paolo S. Calabrò, Filippo Fazzino, Adele Folino, Dimitrios Komilis
Nonwoven Wet Wipes Can Be Hazardous Substances in Wastewater Systems—Evidences from a Field Measurement Campaign in Berlin, Germany

Nonwoven wet wipes can be hazardous substances for wastewater systems. The study investigates the composition of physical constituents in the wastewater. The solid fractions per m3 wastewater are determined. The amount of nonwoven wet wipes in the sewer samples ranges from 0 to 116 g/m3. The accumulation of wet wipes along the path of wastewater transport is shown.

Raja-Louisa Mitchell, Michel Gunkel, Jan Waschnewski, Paul Uwe Thamsen
Wastewater to Energy: Relating Granule Size and Biogas Production of UASB Reactors Treating Municipal Wastewater

The effect of granular size distribution and temperature on the performance of UASB reactors treating municipal wastewater was studied. Larger granular size distribution favours stable methane production. Increase in temperature increases UASB performance. SMA of sludge decreases with increasing height along the reactor.

Isaac Owusu-Agyeman, Elzbieta Plaza, Zeynep Cetecioglu
CO2 Biofixation by Chlamydomonas reinhardtii Using Different CO2 Dosing Strategies

The CO2 sequestration potential of the green microalga Chlamydomonas reinhardtii was investigated with different CO2 dosing strategies. A gas mixture containing 30% CO2 and 70% N2 was used in these experiments in order to simulate the treatment of flue gases from various industries containing high concentrations of CO2. Alongside the CO2 sequestration, the results suggest that the microalgal biomass was rich in carbohydrates and lipids, and thus suitable to be used for biofuel production.

Nilesh R. Badgujar, Franscesco Di Capua, Stefano Papirio, Francesco Pirozzi, Piet N. L. Lens, Giovanni Esposito
A Suggestion on Nutrient Removal/Recovery from Source Separated Human Urine Using Clinoptilolite Combined with Anaerobic Processing

Source separated human urine is a renewable alternative source of fertilizers. Plant nutrients therein may be concentrated upon clinoptilolite to be made available to plants in due course. The remaining liquid phase is a saline solution containing appreciable amounts of organics which may be converted into biogas to be used as energy while it is treated anaerobically. The preliminary results reveal that in addition to high levels of nutrient recovery and considerable organics removal, the remaining liquid waste may possibly be treated using anaerobic processes and that the outcomes can be improved especially after determining the best choices for process variables.

B. Beler-Baykal, M. N. Taher, M. Altinbas
Niches for Bioelectrochemical Systems in Wastewater Treatment Plants

Climate change and future depletion of resources are two of the most important environmental challenges that humankind have ever faced. This chapter aims to give a second chance to contaminated water and recalcitrant carbon dioxide (CO2) streams by putting forward a resilience and sustainable technology-based electron-driven microbial reactions.

Miguel Osset-Álvarez, Laura Alsina, Narcis Pous, Ramiro Blasco-Gómez, Jesús Colprim, M. Dolors Balaguer, Sebastià Puig
Degradation of Gaseous VOCs by Ultrasonication: Effect of Water Recirculation and Ozone Addition

Ultrasonication with water recirculation slightly enhanced the removal of toluene compared to water recirculation alone due to conjunction of pyrolysis and hydroxyl radical oxidation with absorption. On the other hand, the addition of ozone with ultrasonication decreased the removal efficiency due to scavenging of hydroxyl radicals. The reaction rate for ozone and OH radicals produced during the US process was faster compared to the rate for ozone and toluene.

Jose Comia Jr., Giuseppina Oliva, Tiziano Zarra, Vincenzo Naddeo, Florencio C. Ballesteros Jr., Vincenzo Belgiorno
Optimal Chlorination Station Scheduling in an Operating Water Distribution Network Using GANetXL

Chlorination is the process of adding chlorine to drinking water to disinfect it prior to transmission and distribution to the receiving community. In order to maintain the drinking water quality, the chlorine level must remain within certain minimum and maximum values. This paper aims at applying GANetXL optimization tool to a real-world water network to best determine where and how much disinfectant should be injected. GANetXL is a software module that relies on the use of a genetic algorithm (GA) interfaced with EPANET 2.0. The results clearly demonstrate the positive performance of GANetXL to optimize both the disinfectant dosage value as well as the dosing location (i.e., the proper nodes to which the chlorine should be injected).

Roya Peirovi, Alireza Moghaddam, Carol Miller, Asiyeh Moteallemi, Mahdi Rouholamini, Mohammadamin Moghbeli
Utilization of Microalgae Cultivated in Municipal Wastewater for CO2 Fixation from Power Plant Flue Gas and Lipid Production

This study established a combined culture system for microalgae, wastewater, and flue gas. The microalgae growth rate could be greatly enhanced by feeding with CO2 of flue gas. The maximum carbon sequestration and average carbon sequestration rate were 1.203 g/L and 0.225 g/(L·d).

R. J. Tu, S. F. Han, W. B. Jin, X. Zhou, Q. Wang, H. Y. Chen, F. Z. Zeng, Z. Q. He, J. Q. Wang
Techno-Economic Assessment of Combined Heat and Power Units Fuelled by Waste Vegetable Oil for Wastewater Treatment Plants: A Real Case Study

An integrated system for sewage sludge drying and electricity production is proposed. The system is powered by waste vegetable oil from separate collection. The system significantly reduces the sludge to be disposed of and the electricity to be supplied by the grid.

Simona Di Fraia, Nicola Massarotti, Laura Vanoli, Riccardo Bentivoglio, Gianfranco Milani
Eco-LCA of Biological Wastewater Treatments Focused on Energy Recovery

This work presents a novel methodology for sustainability assessment of biological wastewater treatment systems (Bio-WWTs) promoting the energy valorization of their by-products (e.g. biogas). The methodology combines analytical identification of principles-criteria of sustainability (PCS), life cycle assessment (LCA) and energy analysis (EmA) to obtain a set of sustainable development indicators (SDIs). Synergy among single SDIs is required to confirm an overall sustainable condition.

Alexander Meneses-Jácome, Adriana Ruiz-Colorado
Optimization of Nutrient Recovery from Synthetic Swine Wastewater Using Response Surface Methodology

Phosphorus and nitrogen were recovered as struvite in an FBC reactor. Nutrients recovery performance was optimized by using synthetic swine wastewater. Upflow velocity of 20 cm min−1 and influent PO43− of 162.32 mg L−1 yield the best nutrient recovery conditions. Model validation proved that RSM-generated models are robust.

Ralf Ruffel M. Abarca, Remegio S. Pusta Jr., Rea B. Labad, Jenz Lawrence A. Andit, Claudine M. Rejas, Mark Daniel G. De Luna
Enzymatic Pretreatment of Chicken Manure for Improved Biogas Yield

Chicken manure is an important substrate for biogas production. Enzymatic pretreatment of chicken manure was investigated. A higher biodegradability of chicken manure was the primary aim. Batch anaerobic digestion tests were conducted after pretreatment. Enzymatic pretreatment provided higher biogas yields.

Seyedmehdi Emadian, Murat Kuzulcan, Mehmet Ali Küçüker, Burak Demirel, Turgut Tüzün Onay
Integration of Liquid–Liquid Membrane Contactors and Electrodialysis for Ammonia Recovery from Urban Wastewaters

The liquid-liquid membrane contactor (LLMC) is an innovative and eco-friendly technology for ammonium salts production; Electrodialysis (ED) can concentrate efficiently ammonium salts; Concentrated ammonium salts can be obtained by means of integration processes (LLMC and ED); Ammonium salts produced can be used as liquid fertilizers.

X. Vecino, M. Reig, B. Bhushan, J. López, O. Gibert, C. Valderrama, J. L. Cortina
Remediation of Water Contaminated by Pb(II) Using Virgin Coniferous Wood Biochar as Adsorbent

Charcoal from vegetable wastes showed good adsorbent properties for lead-contaminated water. Adsorption capacity at equilibrium was about 10 and 20 mg/g at 50 and 100 mg/L Pb, respectively. Breakthrough curves highlighted longer operation times of column plant filled with charcoal mixed sand than with sand only.

Agostina Chiavola, Simone Marzeddu, Maria Rosaria Boni
A Simplified Model to Simulate a Bioaugmented Anaerobic Digestion of Lignocellulosic Biomass

Normalized root mean square error (NRMSE) results from calibration and validation phases confirmed the model robustness and stability; kd calibrated values were consistent with the initial faster process kinetic observed in the anaerobic digestion (AD) configuration; α values from model calibration step further confirmed the beneficial effects of F210 and ARF on the hydrolysis step enhancement of wheat straw (WS).

Alberto Ferraro, Giulia Massini, Valentina Mazzurco Miritana, Antonella Signorini, Marco Race, Massimiliano Fabbricino
Dissolved Oxygen Perturbations: A New Strategy to Enhance the Removal of Organic Micropollutants in Activated Sludge Process

Cycles of dissolved oxygen perturbation can affect emerging contaminants removal. The nitrification process can also be enhanced by oxygen perturbations. Perturbation frequency is a sensitive parameter.

Camilla Di Marcantonio, Amrita Bains, Agostina Chiavola, Naresh Singhal, Maria Rosaria Boni
PFOA and PFOS Removal Processes in Activated Sludge Reactor at Laboratory Scale

Adsorption was the main removal process of PFOS and PFOA in activated sludge reactors at laboratory scale. Some biodegradation of the two tested contaminants was also detected, after adsorption. Respirometric tests showed inhibition of the nitrifying bacteria up to 30% due to the presence of PFOS and PFOA. COD removal was not affected by the presence of PFOS and PFOA.

Agostina Chiavola, Camilla Di Marcantonio, Maria Rosaria Boni, Stefano Biagioli, Alessandro Frugis, Giancarlo Cecchini
Selectrodialysis and Ion-Exchange Resins as Integration Processes for Copper and Zinc Recovery from Metallurgical Streams Containing Arsenic

SED is an innovative technology for metallurgical effluents treatment; IEX resin is an efficient methodology for metal separation and concentration steps; Cu and Zn were recovered by means of integration processes (SED and IEX resins).

M. Reig, X. Vecino, M. Hermassi, J. López, C. Valderrama, O. Gibert, J. L. Cortina
Microalgae Cultivation for Pretreatment of Pharmaceutical Wastewater Associated with Microbial Fuel Cell and Biomass Feed Stock Production

This study evaluated the potential of microalgae Scenedesmus abundance for pretreatment of pharmaceutical wastewater in photobioreactor (PBR) associated with photosynthetic microbial fuel cell (PMFC). At the end of pretreatment process, the removal efficiency of COD of 75 % along with nitrate and phosphate of 78 and 83 % was obtained, respectively. In continuation of treatment process, the pretreated wastewater was used as a substrate for further treatment in PMFC and was succeeded to achieve maximum COD removal of 87.8 % calculating the total (combined of PBR and PMFC) removal efficiency of 95 %. A maximum voltage of 740.13 mV and power density of 838.68 mW/m2 was achieved. A maximum biomass of 0.71 g/L from PBR after pretreatment and 0.78 g/L from PMFC process was obtained.

Jagdeep Kumar Nayak, Uttam Kumar Ghosh
Embryotoxicity and Molecular Alterations of Fluoxetine and Norfluoxetine in Early Zebrafish Larvae

Embryos and larvae exposed to FLX showed higher mortality rates at 32 hpf than those exposed to NFLX. At 80 hpf gross malformations, mainly in pigmentation, were higher in NFLX exposed larvae than in FLX exposed larvae. In general, strong positive correlations were found between the expression of 34 target genes. Negative correlations were associated with opposite patterns of gene expression in NFLX and FLX larvae. Adrenergic receptors, and some correlated genes, can be responsible for anomalies in pigmentation.

Pedro Rodrigues, V. Cunha, M. Ferreira, Laura Guimarães
Biological Treatment of Municipal Wastewater Using Green Microalgae and Activated Sludge as Combined Culture

This paper highlights the use of the combined culture system in municipal wastewater treatment. Removal of nutrients was significantly increased in properly inoculated combined culture system. Release of organic matter from Chlorella biomass decreased the COD removal performance.

Ghulam Mujtaba, Muhammad Rizwan, Kisay Lee
Fouling Morphologies on Ion-Exchange Membranes in Reverse Electrodialysis with Effluent from Sewage Treatment Plant

Fouling occurred on the ion-exchange membranes under practical condition, Reversible fouling occurred on the CEM, Irreversible fouling occurred on the AEM.

Hanki Kim, Won-Sik Kim, Joo-Youn Nam, Ji-Yeon Choi, Kyo-sik Hwang, Yong Seog, Nam-Jo Jeong
Co-composting Biosolids and Organic Fraction of Municipal Solid Waste or Carbonized Rice Hull and Trichoderma harzianum Augmented Inoculum

Through composting, biosolids can be converted to a soil conditioner provided pathogen control is ensured. Carbonized rice hull is a promising bulking agent for composting, while OFMSW can provide more organic matter needed for achieving higher peak temperatures. Augmenting with T. harzianum improves quality of compost product, thereby providing resistance to plant diseases and promotes growth.

Analiza Palenzuela Rollon, Enrico Luis Coquico, Fredie More Pablo, Angelene Paradero
Production of Bioenergy and Biochemicals from Organic Solid Waste: Influence of the Pretreatment Operating Parameters

The organic solvent pretreatment promotes the bioconversion of the organic solid waste. A low acid concentration increases the hydrogen production. Lactate production is favoured by high acid concentration and temperature of the pretreatment.

A. Conte, A. Cesaro, H. Carrère, E. Trably, F. Paillet, Vincenzo Belgiorno
Sulfate Ion Removal from Reverse Osmosis Concentrate Using Electrodialysis and Nano-Filtration in Combination with Ettringite Precipitation

NF membranes reject divalent ions ( $$ {{\text{SO}}_{4}}^{2 - } $$ ) at much higher rate than monovalent ions (Cl−); Electrodialysis showed higher removal efficiency of $$ {{\text{SO}}_{4}}^{2 - } $$ and Cl−; Sulfate coexists with calcium- and aluminum-enhanced ettringite precipitation.

Yongxun Jin, Kangwoo Cho, Chong Min Chung, Seokwon Hong
Increasing Sustainability on the Metallurgical Industry by Integration of Membrane NF Processes: Acid Recovery

Treatment of hydrometallurgical effluents by nanofiltration membranes for acid recovery. Application of Solution-Electro-Diffusion Model to determine membrane permeances.

J. López, M. Reig, X. Vecino, C. Valderrama, O. Gibert, J. L. Cortina

Energy Saving Technologies and Future Clean Energy Solutions Under Water Constraints

Frontmatter
Overview of the Water Requirements for Energy Production in Africa

86% of the total water consumed for fuel production in Africa corresponds to oil. 74% of the water consumption for power plant operations is for coal power plants and 60% of the water withdrawals is for natural gas power plants. Renewable energies represent 2% of water consumption and 0.06% of water withdrawals in electricity production in Africa.

Rocio Gonzalez, Nicolae Scarlat
Evaluation of Water–Energy Nexus in Sakarya River Basin, Turkey

Achieving sustainable water–energy relationship is especially important for semi-arid regions. Water consumption due to electricity generation can reach up to 8.4% of the total water potential in the study area. Between 659 and 2851 m3 of water is found to be consumed per GWh of electricity generated at cooling systems.

Zeynep Özcan, Merih Aydınalp Köksal, Emre Alp
Water-Energy Nexus in Shallow Geothermal Systems

Ground-source heat pumps (GSHPs) reduce CO2 emissions compared to conventional heating and cooling systems. The thermally altered zone (thermal plume) is a key aspect for land management of GSHPs.

Alessandro Casasso, Rajandrea Sethi
Singular Applications of Capacitive Deionization: Reduction of the Brine Volume from Brackish Water Reverse Osmosis Plants

Current desalination technologies present certain limitations associated with brine management. CDI operational conditions similar to EDL capacitors might become a solution for brine volume reduction. Innovative operating procedure utilizes a concentrated brine stream as a washing solution during the salt desorption phase. A high energy efficiency in the adsorption–desorption cycle was obtained using the electrolyte replacement procedure. A coupled RO-CDI system integration was proposed as a method to reduce the volumetric flow of brine.

Julio J. Lado, Cleis Santos, Enrique García Quismondo, Marc A. Anderson, Belén Gutiérrez, Fernando Huertas, Antonio Ordóñez, Ángel de Miguel
An Unprecedented Thousandfold Enhancement of Antimicrobial Activity of Metal Ions by Selective Anion Treatment

The synergy between anions and cations is understood for their enhanced antimicrobial activity. Up to thousandfold enhancement of antibacterial and antiviral activity in drinking water by this technique. Enhancement makes disinfection of water affordable, compact and adaptable to multiple purification systems. A decrease in consumption of inorganic ions reduces health risks caused by disinfection by-products (DBPs). Thus DBPs and bioaccumulation related issues can be handled efficiently. This understanding of synergy helps to speed up the disinfection process.

Jakka Ravindran Swathy, Ligy Philip, Thalappil Pradeep
Harnessing Water Chemistry to Address Complex Water Challenges for a Thirsty World

Harnessing the photochemistry of chloramines can provide a promising approach for water reuse and treatment.

Haizhou Liu
Photo(cata)lytic Membrane Bioreactors for Bacterial Disinfection and Antifouling Enhancement in Advanced Wastewater Treatment

Photo(cata)lytic membrane bioreactors (pMBR) were investigated for bacterial disinfection and fouling control. The pMBR achieved >2.5 log removal in total bacterial count under optimum condition. The signal molecules were significantly inactivated by the photo(cata)lytic treatment. Biofouling was well inhibited during continuous pMBR operation.

Xiaolei Zhang, Kwang-Ho Choo
Water Networks as Flexible Loads to Power Systems

Water facilities consume a large amount of electrical power. The components of water networks (mostly pumps and tanks) represent an incomparable opportunity for joint operation of water networks and power systems. These components are well suited for being responsive loads to power systems because water is storable

Mahdi Rouholamini, Carol Miller, Caisheng Wang, Mohsen Mohammadian, Mohammadamin Moghbeli
Preparation of PES/GO/APTES-SiO2 Mixed Matrix Membrane for the Treatment of Oily Wastewater

PES/GO mixed matrix membranes were fabricated and characterized. Water permeability tests, hydrophilicity, and surface morphology characterizations were conducted. A max of 2870 L/m2 h water flux and contact angle of 64.5° were achieved.

Maryam B. Alkindy, Munirasu Selvaraj, Fawzi Banat, Shadi Wajih Hasan
Ayun Mousa Springs: Integrated Hydrological, Environmental and Geophysical Studies

Ayun Mousa springs area is the most important religious and historical sites in Sinai. The water quality of the exposed springs (seven springs) indicates brackish water suitable for medical purposes. Air quality indicates some pollution next to the highway.

Ahmed M. H. Shaban, Bassem S. Nabawy, Ali Abbas, Mohamed M. Kassab
Modelling Demand and Response in WWTPs: Extension of BSM1 with Aeration Tank Settling

Demand shedding through aeration control can exploit the wastewater treatment plant (WWTP) flexibility to help maintain the power system grid balance and reduce operational costs. The reactions and settling process combination is not considered in traditional WWTP models, but it could play an important role in the modelling of demand response (DR) strategies and their effects on the plants.

Matteo Giberti, Recep Kaan Dereli, Damian Flynn, Eoin Casey
Miscanthus as Energy Crop and Means of Mitigating Flood

Miscanthus is a suitable alternative for energy biomass. Particularly, in cultivation area that is prone to flooding. Current commercial Miscanthus can survive in the winter-flooded environment. There is no significant difference in yield and other physiological development. Observed height and tiller number have no differences between winter flooded and non-flooded ground.

Jason Kam, Daniel Traynor, John C. Clifton-Brown, Sarah J. Purdy, Jon P. McCalmont
Technical-Economic Comparison of Chemical Precipitation and Ion Exchange Processes for the Removal of Phosphorus from Wastewater

Superior performance of phosphorous removal was achieved by ion exchange process with respect to chemical precipitation. The ion exchange resins required a lower dosage to ensure compliance with the effluent limit. The ion exchange process was less costly due to the lower energy consumption and sludge production.

Chiavola Agostina, Bongirolami Simona, Di Francesco Giorgia

Implementation and Best Practices

Frontmatter
Advancements of Electrically Enhanced Membrane Bioreactor (eMBR) for Wastewater Treatment via Coupling with Novel Inorganic and Polymeric Mixed Matrix Membranes

eMBR is recently developed technology for wastewater treatment. Nanoporous hollow fiber PES membranes were fabricated and tested for eMBR post-treatment. α-MnO2/TiO2 inorganic membranes were fabricated, characterized, and tested for eMBR post-treatment. PES-fβCD mixed matrix membranes were fabricated, characterized, and tested for eMBR post-treatment.

Shadi Wajih Hasan
Cost-Effective Removal of COD in the Pre-treatment of Wastewater from Paper Industry

Different pre-treatment processes were applied to investigate the removal of chemical oxygen demand (COD) from paper mill effluent. The objective of this paper is to find the optimal operating conditions for coagulation process. The effect of key operational parameters, including the type of coagulant, initial pH, temperature, and coagulant dose, on the percent removal of COD was investigated. Under the optimal operational conditions, the treatment of wastewater from paper industries by coagulation has led to a reduction of fee paid for wastewater discharged.

Boguniewicz-Zablocka Joanna, Klosok-Bazan Iwona, Vincenzo Naddeo, Mozejko Clara
Sensors for Water Purification Using the Example of Wastewater Treatment Plant Gabrovo, Bulgaria

The article analyzes water purification and methods for the purpose. Types of sensors and appliances used for wastewater treatment are considered. The scheme and the principle of operation of a sewage treatment plant in Gabrovo, Bulgaria are presented.

S. Kartunov, B. Kosev
Design an Integration Platform Between Water Energy Nexus and Business Model Applied for Sustainable Development

Sustainable Development Calculator Application—Innovating tool for Sustainable Development WEN—A Platform for applying WEN Concepts—Integration Between Business Model and WEN—Mobile Application for Water Energy Nexus.

Heba Ahmed Mosalam, Mohamed El-Barad
New Tools and Approaches for Soil and Water Bioengineering in the Mediterranean to Enhance Water Quality

Soil and water bioengineering works can improve water quality. Soil and water bioengineering works are nature-based methods. Stakeholder inputs can improve soil and water bioengineering works. Case studies in soil and water bioengineering from the Mediterranean. New protocols and a template for soil and water bioengineering work for the Mediterranean.

George N. Zaimes, Guillermo Tardio, Valasia Iakovoglou, Martin Gimenez, Jose Luis Garcia-Rodriguez, Paola Sangalli
Multi-Criteria Decision Making for the Selection of Best Practice Seawater Desalination Technologies

Choice of optimum desalination technology is posited as a multi-criteria decision-making (MCDM) problem. Formulation considers technical, economic, environmental and social criteria. MCDM is an effective tool for selecting the best practice technology. Seawater reverse osmosis was found to consistently outperform thermal desalination technologies.

Dunia AbdulBaki, Fatima Mansour, Ali Yassine, Mahmoud Al-Hindi, Majdi Abou Najm
Modeling Co-treatment of Leachate in Municipal Wastewater Treatment Plants in the Context of Dynamic Loads and Energy Prices

Different leachate feeding strategies were tested and compared based on BSM1 framework. Leachate co-treatment adversely effected nitrogen removal efficiency and increased aeration energy costs. Shock loading at noon resulted in the worst treatment performance by overloading the plant. Drip feeding based on ammonia control ensures a higher degree of flexibility by adjusting the leachate flow.

Recep Kaan Dereli, Matteo Giberti, Qipeng Liu, Eoin Casey
Microfiltered Digestate to Fertigation: A Best Practice to Improve Water and Energy Efficiency in the Context of Biogasdoneright™

Biogasdoneright™ is an innovative agricultural model aimed at achieving a sustainable agricultural intensification. The microfiltration of the by-product from biogas production, the digestate, is among technology innovations supporting the implementation of best practices in the Biogasdoneright™ system. Digestate microfiltration tests were carried out under different operating conditions, to fine tune the best working conditions of the equipment. Then it was possible to distribute the microfiltered digestate in fertigation on growing maize through drip lines without causing blockage. Microfiltered digestate to fertigation has proven to be a best practice to improve nutrients, water and energy efficiency in the context of Biogasdoneright™.

Paolo Mantovi, Giuseppe Moscatelli, Sergio Piccinini, Stefano Bozzetto, Lorella Rossi
Optimal Design of Water Distribution Networks Incorporating Reliability Criteria

To achieve a robust and optimal design of water distribution networks, both hydraulic constraints and reliability concerns must be met. This paper aims at employing multi-objective particle swarm optimization (MOPSO) algorithm for reliability-oriented design of a water distribution network. We use Pareto-front analysis to make a compromise between cost and reliability satisfaction. Two criteria, referred to as Todini’s resilience index ( $$I_{r}$$ ) and network resilience index ( $$I_{n}$$ ), are used to evaluate the resilience of the network under study. The simulation results clearly show that MOPSO is capable of being used in optimal design of water distribution networks and $$I_{n}$$ is an effective criterion for water networks’ reliability evaluation.

Alireza Moghaddam, Ali Naghi Ziaei, Carol Miller, Zahra Fahim, Hossein Ansari, Fatemeh Attarzadeh, Mahdi Rouholamini, Mohammadamin Moghbeli
Creating Abundance: Nexus Stress as a Driver for Innovation in Solving Energy and Water Stress

Energy and water nexus stress drives innovation in technology, financing models, business models, and partnerships. There are new platforms to accelerate nexus innovation that leverage the skills and experience of successful entrepreneurs from outside the energy and water sectors. New business and financial models are needed to solve energy and water nexus stress challenges. New partnership models are emerging to foster cross-industry and entrepreneurial platform collaboration.

William Sarni, Joshua Sperling
Using Fast Messy Genetic Algorithm to Optimally Schedule Pump Operation

Darwin Scheduler model based on fast messy genetic algorithm is utilized to best schedule the operation of the pump stations. Van Zyl, which is a well-known water network, is used to simulate the aforesaid model. FMGA reduces energy costs and the number of start/stop of the pumps. FMGA leads to the reduction of the maintenance costs.

Javad Karami, Alireza Moghaddam, Alireza Faridhosseini, Ali Naghi Ziaei, Mahdi Rouholamini, Mohammadamin Moghbeli
Membrane Aerated Biofilm Reactor (MABR)—Distributed Treatment of Wastewater at Low Energy Consumption

Membrane-aerated biofilm reactor (MABR) is an energy efficient biological wastewater treatment process, based on passive aeration: by diffusion of oxygen through membranes, which also support an aerobic biofilm. The theoretical energy savings of MABR over that of conventional activated sludge (CAS) process were calculated to 86.8%. The paper analyzes two case studies of MABR implementation: one treating 25,000 GPD (95 m3/day) of municipal wastewater at US Virgin Islands and the second treating 125 m3/day of concentrated wastewater at Ha-Yogev WWTP in Israel. Energy consumption was measured and averaged over 2 months of operation. The results show the energy consumption for operation of the secondary treatment with MABR amounts to 0.212 kWh/m3 at the first case, while removing 98.9% BOD, 94.8% of NH4, and 96.8% of TSS. In the second case, the energy consumption for operation of the secondary treatment was below 0.4 kWh/m3 for the biological treatment achieving the required removal rates. By consuming very low energy at small treatment capacities, MABR supports the most important principles in water and energy efficiency: reduced energy for treatment and local water reuse.

Udi Tirosh, Ronen Shechter
Method to Assess Wastewater Pumps in the Nexus of Functionality and Energy Efficiency

To date, there is no standardised test available, which assesses the actual performance of a pump for wastewater (especially its clog resistance) as well as providing references about its efficiency. The developed testing procedure presented in this paper can display the different levels of performance for different pumps. The functionality of the pump, together with its efficiency is aggregated to the Function Efficiency Index (FEI). The FEI is thus a holistic parameter to describe a wastewater pump and enables a revaluation of the technologies available on the market.

Michael Pöhler, Paul Uwe Thamsen
Role of Pretreatment in Adsorption of Cobalt, Mercury and Nickel by Native Algae

Native macroalgae were used as an inexpensive and efficient biosorbent. Mercury (Hg), nickel (Ni) and cobalt (Co) were removed from synthetic wastewater. The algal biomass was pretreated with 0.1 HCl, 0.2 HCl, CaCl2 NaOH Na2CO3 and hot water. NaOH pretreatment was most suitable for the removal of Hg. Na2CO3 pretreatment was the best technique for the removal of Ni and Co.

Muhammad Rizwan, Alia Naz, Abdullah Khan, Wisal Shah, Ghulam Mujtaba, Mona Syed, Qadeer Ahmed, Noor Fatima
A Model-Based Approach for Energy Optimization of Real Wastewater Pumping Station

Wastewater pumping plants represent important energy consumers. A real case study in Italy is analyzed. A model-based approach is proposed. Optimization of pumps start/stop number is performed. The approach can be easily extended to different case studies.

Manuel De Chiara, Roberto De Rosa, Anna Giuliani, Salvatore Guadagnuolo, Angelo Leopardi, Luca Pucci, Dario Torregrossa
Metadaten
Titel
Frontiers in Water-Energy-Nexus—Nature-Based Solutions, Advanced Technologies and Best Practices for Environmental Sustainability
herausgegeben von
Prof. Dr. Vincenzo Naddeo
Dr. Malini Balakrishnan
Prof. Dr. Kwang-Ho Choo
Copyright-Jahr
2020
Electronic ISBN
978-3-030-13068-8
Print ISBN
978-3-030-13067-1
DOI
https://doi.org/10.1007/978-3-030-13068-8