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24.04.2020 | Original Research

Fully bio-based fire-safety viscose/alginate blended nonwoven fabrics: thermal degradation behavior, flammability, and smoke suppression

verfasst von: Yun Liu, Ye Tao, Bin Wang, Ping Li, Ying-Jun Xu, Zhi-Ming Jiang, Chao-Hong Dong, Ping Zhu

Erschienen in: Cellulose | Ausgabe 10/2020

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Abstract

Ecofriendly bio-based alginate fibres are one of the inherently flame-retardant fibres. Can the incorporation of alginate fibres to viscose fibres enhance the flame retardancy and decrease the smoke release of prepared viscose/alginate blended nonwoven fabrics? Aiming to resolve this question, in the present work, viscose/alginate blended nonwoven fabrics were prepared in a green way without any pollution. Vertical flame test, cone calorimetry test and microscale combustion calorimetry results indicated that the incorporation of alginate fibres enhanced the flame retardancy and fire behaviors; what is more, the incorporation of alginate fibres seriously prolonged time to ignition. The results mentioned above indicate that alginate fibres can enhance the flame retardancy and inhibit the smoke release of viscose fibres. The incorporation of alginate fibres altered the thermal stability of viscose fibres and decreased the flammable gas emissions, thus improving the flame retardancy of viscose/alginate blended nonwoven fabrics. A conclusion can be made that inherently bio-based alginate fibres can be used as a kind of flame retardant to flame-retard viscose fibres.

Graphic abstract

The incorporation of alginate fibres improves the flame retardancy and suppresses the release of smoke for viscose/alginate blended nonwoven fabrics.

Vorheriger Artikel Guanidine-functionalized cotton fabrics for achieving permanent antibacterial activity without compromising their physicochemical properties and cytocompatibility

Nächster Artikel Novel, sustainable and water efficient nano bubble dyeing of cotton fabric

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Alongi J, Cuttica F, Carosio F (2016) DNA coatings from byproducts: a panacea for the flame retardancy of EVA, PP, ABS, PET, and PA6? ACS Sustain Chem Eng 4:3544–3551. https://doi.org/10.1021/acssuschemeng.6b00625 CrossRef

Bhoyate S, Ionescu M, Kahol PK, Gupta RK (2018) Sustainable flame-retardant polyurethanes using renewable resources. Ind Crops Prod 123:480–488. https://doi.org/10.1016/j.indcrop.2018.07.025 CrossRef

Bychkova EV, Panova LG (2016) Fire-resistant viscose rayon fiber materials. Fibre Chem 48:217–223. https://doi.org/10.1007/s10692-016-9771-9 CrossRef

Carosio F, Fontaine G, Alongi J, Bourbigot S (2015) Starch-based layer by layer assembly: efficient and sustainable approach to cotton fire protection. ACS Appl Mater Interfaces 7:12158–12167. https://doi.org/10.1021/acsami.5b02507 CrossRefPubMed

Chauhan P, Chen HY, Goswami SR, Yan N (2019) Improved mechanical properties of flexible bio-based polymeric materials derived from epoxy mono/di-abietic acid and soyabean oil. Ind Crops Prod 138:9. https://doi.org/10.1016/j.indcrop.2019.05.086 CrossRef

Cheng XW, Guan JP, Tang RC, Liu KQ (2016) Phytic acid as a bio-based phosphorus flame retardant for poly(lactic acid) nonwoven fabric. J Clean Prod 124:114–119. https://doi.org/10.1016/j.jclepro.2016.02.113 CrossRef

Choi K, Seo S, Kwon H, Kim D, Park YT (2018) Fire protection behavior of layer-by-layer assembled starch–clay multilayers on cotton fabric. J Mater Sci 53:11433–11443. https://doi.org/10.1007/s10853-018-2434-x CrossRef

Feng J, Zhang M, Hua T, Chan KH (2019) Study of a newly structuralized meta-aramid/cotton blended yarn for fabrics with enhanced flame-resistance. Text Res J. https://doi.org/10.1177/0040517519871262 CrossRef

Gaan S, Rupper P, Salimova V, Heuberger M, Rabe S, Vogel F (2009) Thermal decomposition and burning behavior of cellulose treated with ethyl ester phosphoramidates: effect of alkyl substituent on nitrogen atom. Polym Degrad Stab 94:1125–1134. https://doi.org/10.1016/j.polymdegradstab.2009.03.017 CrossRef

Garvey SJ, Anand SC, Rowe T, Horrocks AR, Walker DG (1996) The flammability of hybrid viscose blends. Polym Degrad Stab 54:413–416. https://doi.org/10.1016/S0141-3910(96)00072-9 CrossRef

He Y, Chen Y, Zheng Q, Zheng J, Chen S (2015) Preparation and properties of flame-retardant viscose fiber modified with poly[bis(methoxyethoxy)phosphazene]. Fiber Polym 16:1005–1011. https://doi.org/10.1007/s12221-015-1005-x CrossRef

Hribernik S, Smole MS, Kleinschek KS, Bele M, Jamnik J, Gaberscek M (2007) Flame retardant activity of SiO₂-coated regenerated cellulose fibres. Polym Degrad Stab 92:1957–1965. https://doi.org/10.1016/j.polymdegradstab.2007.08.010 CrossRef

Huang J, Liu J, Chen J, Xie W, Kuo J, Lu X, Chang K, Wen S, Sun G, Cai H, Buyukada M, Evrendilek F (2018) Combustion behaviors of spent mushroom substrate using TG-MS and TG-FTIR: thermal conversion, kinetic, thermodynamic and emission analyses. Bioresour Technol 266:389–397. https://doi.org/10.1016/j.biortech.2018.06.106 CrossRefPubMed

Jian RK, Ai YF, Xia L, Zhao LJ, Zhao HB (2019) Single component phosphamide-based intumescent flame retardant with potential reactivity towards low flammability and smoke epoxy resins. J Hazard Mater 371:529–539. https://doi.org/10.1016/j.jhazmat.2019.03.045 CrossRefPubMed

Jiang Z, Wang C, Fang S, Ji P, Wang H, Ji C (2018) Durable flame-retardant and antidroplet finishing of polyester fabrics with flexible polysiloxane and phytic acid through layer-by-layer assembly and sol–gel process. J Appl Polym Sci. https://doi.org/10.1002/app.46414 CrossRefPubMedPubMedCentral

Jiang Z, Li H, He Y, Liu Y, Dong C, Zhu P (2019a) Flame retardancy and thermal behavior of cotton fabrics based on a novel phosphorus-containing siloxane. Appl Surf Sci 479:765–775. https://doi.org/10.1016/j.apsusc.2019.02.159 CrossRef

Jiang ZM, Xu DH, Ma XB, Liu J, Zhu P (2019b) Facile synthesis of novel reactive phosphoramidate siloxane and application to flame retardant cellulose fabrics. Cellulose 26:5783–5796. https://doi.org/10.1007/s10570-019-02465-2 CrossRef

Kandola BK, Horrocks AR, Price D, Coleman GV (1996) Flame-retardant treatments of cellulose and their influence on the mechanism of cellulose pyrolysis. J Macromol Sci C 36:721–794. https://doi.org/10.1080/15321799608014859 CrossRef

Laufer G, Kirkland C, Morgan AB, Grunlan JC (2012) Intumescent multilayer nanocoating, made with renewable polyelectrolytes, for flame-retardant cotton. Biomacromol 13:2843–2848. https://doi.org/10.1021/bm300873b CrossRef

Li X, Zhang K, Shi R, Ma X, Tan L, Ji Q, Xia Y (2017) Enhanced flame-retardant properties of cellulose fibers by incorporation of acid-resistant magnesium-oxide microcapsules. Carbohydr Polym 176:246–256. https://doi.org/10.1016/j.carbpol.2017.08.096 CrossRefPubMed

Li P, Wang B, Xu YJ, Jiang ZM, Dong CH, Liu Y, Zhu P (2019) Ecofriendly flame-retardant cotton fabrics: preparation, flame retardancy, thermal degradation properties, and mechanism. ACS Sustain Chem Eng 7:19246–19256. https://doi.org/10.1021/acssuschemeng.9b05523 CrossRef

Li P, Wang B, Liu YY, Xu YJ, Jiang ZM, Dong CH, Zhang L, Liu Y, Zhu P (2020) Fully bio-based coating from chitosan and phytate for fire-safety and antibacterial cotton fabrics. Carbohydr Polym 237:116173. https://doi.org/10.1016/j.carbpol.2020.116173 CrossRefPubMed

Liu Y, Zhao J, Deng CL, Chen L, Wang DY, Wang YZ (2011) Flame-retardant effect of sepiolite on an intumescent flame-retardant polypropylene system. Ind Eng Chem Res 50:2047–2054. https://doi.org/10.1021/ie101737n CrossRef

Liu XJ, Ren XY, Guan S, Li HQ, Song ZK, Gao GH (2015a) Highly stretchable and tough double network hydrogels via molecular stent. Eur Polym J 73:149–161. https://doi.org/10.1016/j.eurpolymj.2015.10.011 CrossRef

Liu Y, Li Z, Wang J, Zhu P, Zhao J, Zhang C, Guo Y, Jin X (2015b) Thermal degradation and pyrolysis behavior of aluminum alginate investigated by TG-FTIR-MS and Py-GC-MS. Polym Degrad Stab 118:59–68. https://doi.org/10.1016/j.polymdegradstab.2015.04.010 CrossRef

Liu Y, Zhao JC, Zhang CJ, Guo Y, Zhu P, Wang DY (2015c) Effect of manganese and cobalt ions on flame retardancy and thermal degradation of bio-based alginate films. J Mater Sci 51:1052–1065. https://doi.org/10.1007/s10853-015-9435-9 CrossRef

Liu Y, Zhang CJ, Zhao JC, Guo Y, Zhu P, Wang DY (2016a) Bio-based barium alginate film: preparation, flame retardancy and thermal degradation behavior. Carbohydr Polym 139:106–114. https://doi.org/10.1016/j.carbpol.2015.12.044 CrossRefPubMed

Liu Y, Zhao JC, Zhang CJ, Cui L, Guo Y, Zhu P, Zhang H, Zheng Z-W, Wang D-Y (2016b) Flame retardancy and thermal degradation properties of cotton/alginate fabric. J Therm Anal Calorim 127:1543–1551. https://doi.org/10.1007/s10973-016-5418-6 CrossRef

Liu Y, Zhao XR, Peng YL, Wang D, Yang L, Peng H, Zhu P, Wang D-Y (2016c) Effect of reactive time on flame retardancy and thermal degradation behavior of bio-based zinc alginate film. Polym Degrad Stab 127:20–31. https://doi.org/10.1016/j.polymdegradstab.2015.12.024 CrossRef

Liu XH, Zhang QY, Cheng BW, Ren YL, Zhang YG, Ding C (2017) Durable flame retardant cellulosic fibers modified with novel, facile and efficient phytic acid-based finishing agent. Cellulose 25:799–811. https://doi.org/10.1007/s10570-017-1550-0 CrossRef

Liu L, Huang Z, Pan Y, Wang X, Song L, Hu Y (2018a) Finishing of cotton fabrics by multi-layered coatings to improve their flame retardancy and water repellency. Cellulose 25:4791–4803. https://doi.org/10.1007/s10570-018-1866-4 CrossRef

Liu XH, Zhang YG, Cheng BW, Ren YL, Zhang QY, Ding C, Peng B (2018b) Preparation of durable and flame retardant lyocell fibers by a one-pot chemical treatment. Cellulose 25:6745–6758. https://doi.org/10.1007/s10570-018-2005-y CrossRef

Liu Y, Wang QQ, Jiang ZM, Zhang CJ, Li ZF, Chen HQ, Zhu P (2018c) Effect of chitosan on the fire retardancy and thermal degradation properties of coated cotton fabrics with sodium phytate and APTES by LBL assembly. J Anal Appl Pyrol 135:289–298. https://doi.org/10.1016/j.jaap.2018.08.024 CrossRef

Liu X, Zhang Q, Peng B, Ren Y, Cheng B, Ding C, Su X, He J, Lin S (2020) Flame retardant cellulosic fabrics via layer-by-layer self-assembly double coating with egg white protein and phytic acid. J Clean Prod. https://doi.org/10.1016/j.jclepro.2019.118641 CrossRef

Ortelli S, Malucelli G, Blosi M, Zanoni I, Costa AL (2019) NanoTiO₂@DNA complex: a novel eco, durable, fire retardant design strategy for cotton textiles. J Colloid Interface Sci 546:174–183. https://doi.org/10.1016/j.jcis.2019.03.055 CrossRefPubMed

Pan Y, Zhao H (2018) A novel blowing agent polyelectrolyte for fabricating intumescent multilayer coating that retards fire on cotton fabric. J Appl Polym Sci. https://doi.org/10.1002/app.46583 CrossRef

Pan Y, Zhan J, Pan HF, Wang W, Tang G, Song L, Hu Y (2016) Effect of fully biobased coatings constructed via layer-by-layer assembly of chitosan and lignosulfonate on the thermal, flame retardant, and mechanical properties of flexible polyurethane foam. ACS Sustain Chem Eng 4:1431–1438. https://doi.org/10.1021/acssuschemeng.5b01423 CrossRef

Sharma A, Sen D, Thakre S, Kumaraswamy G (2019) Characterizing microvoids in regenerated cellulose fibers obtained from viscose and lyocell processes. Macromolecules 52:3987–3994. https://doi.org/10.1021/acs.macromol.9b00487 CrossRef

Tausif M, Ahmad F, Hussain U, Basit A, Hussain T (2015) A comparative study of mechanical and comfort properties of bamboo viscose as an eco-friendly alternative to conventional cotton fibre in polyester blended knitted fabrics. J Clean Prod 89:110–115. https://doi.org/10.1016/j.jclepro.2014.11.011 CrossRef

Thakur S, Sharma B, Verma A, Chaudhary J, Tamulevicius S, Thakur VK (2018) Recent progress in sodium alginate based sustainable hydrogels for environmental applications. J Clean Prod 198:143–159. https://doi.org/10.1016/j.jclepro.2018.06.259 CrossRef

Vecchiato S, Skopek L, Jankova S, Pellis A, Ipsmiller W, Aldrian A, Mueller B, Acero EH, Guebitz GM (2018) Enzymatic recycling of high-value phosphor flame-retardant pigment and glucose from rayon fibers. ACS Sustain Chem Eng 6:2386–2394. https://doi.org/10.1021/acssuschemeng.7b03840 CrossRef

Wang DY, Liu Y, Ge XG, Wang YZ, Stec A, Biswas B, Hull TR, Price D (2008) Effect of metal chelates on the ignition and early flaming behaviour of intumescent fire-retarded polyethylene systems. Polym Degrad Stab 93:1024–1030. https://doi.org/10.1016/j.polymdegradstab.2007.12.011 CrossRef

Wang X, Li Q, Di Y, Xing G (2012a) Preparation and properties of flame-retardant viscose fiber containing phosphazene derivative. Fibers Polym 13:718–723. https://doi.org/10.1007/s12221-012-0718-3 CrossRef

Wang X, Song L, Yang H, Xing W, Kandola B, Hu Y (2012b) Simultaneous reduction and surface functionalization of graphene oxide with POSS for reducing fire hazards in epoxy composites. J Mater Chem 22:22037–22043CrossRef

Wang T, Xu X, Ren Y, Qin S, Sui X, Wang L (2014a) Kinetics of thermal degradation of viscose fiber and fire retardant viscose fiber. J Eng Fibers Fabrics 9:155892501400900205

Wang X, Lu C, Chen C (2014b) Effect of chicken-feather protein-based flame retardant on flame retarding performance of cotton fabric. J Appl Polym Sci 131:40584. https://doi.org/10.1002/app.40584 CrossRef

Wang LH, Ren YL, Wang XL, Zhao JY, Zhang Y, Zeng Q, Gu YT (2016) Fire retardant viscose fiber fabric produced by graft polymerization of phosphorus and nitrogen-containing monomer. Cellulose 23:2689–2700. https://doi.org/10.1007/s10570-016-0970-6 CrossRef

Wang B, Xu YJ, Li P, Zhang FQ, Liu Y, Zhu P (2020) Flame-retardant polyester/cotton blend with phosphorus/nitrogen/silicon-containing nano-coating by layer-by-layer assembly. Appl Surf Sci 509:145323. https://doi.org/10.1016/j.apsusc.2020.145323 CrossRef

Zhang X, Shi M (2019) Flame retardant vinylon/poly(m-phenylene isophthalamide) blended fibers with synergistic flame retardancy for advanced fireproof textiles. J Hazard Mater 365:9–15. https://doi.org/10.1016/j.jhazmat.2018.10.091 CrossRefPubMed

Zhang J, Ji Q, Shen X, Xia Y, Tan L, Kong Q (2011) Pyrolysis products and thermal degradation mechanism of intrinsically flame-retardant calcium alginate fibre. Polym Degrad Stab 96:936–942. https://doi.org/10.1016/j.polymdegradstab.2011.01.029 CrossRef

Zhang CJ, Liu Y, Cui L, Yan C, Zhu P (2016) Bio-based calcium alginate nonwoven fabrics: flame retardant and thermal degradation properties. J Anal Appl Pyrol 122:13–23. https://doi.org/10.1016/j.jaap.2016.10.030 CrossRef

Zhang XS, Xia YZ, Shi MW, Yan X (2018a) The flame retardancy of alginate/flame retardant viscose fibers investigated by vertical burning test and cone calorimeter. Chin Chem Lett 29:489–492. https://doi.org/10.1016/j.cclet.2017.07.023 CrossRef

Zhang X, Xia Y, Yan X, Shi M (2018b) Efficient suppression of flammability in flame retardant viscose fiber through incorporating with alginate fiber. Mater Lett 215:106–109. https://doi.org/10.1016/j.matlet.2017.12.077 CrossRef

Zhao B, Kolibaba TJ, Lazar S, Grunlan JC (2020) Facile two-step phosphazine-based network coating for flame retardant cotton. Cellulose. https://doi.org/10.1007/s10570-020-03047-3 CrossRef

Zhou Z, Youbo D, Hong W, Wei W, Libin G, Xing W (2019) Preparation and characterization of collagencoclotriphosphazene and its action in flame-retardant viscose fiber. Integr Ferroelectr 198:20–29. https://doi.org/10.1080/10584587.2019.1592573 CrossRef

Titel: Fully bio-based fire-safety viscose/alginate blended nonwoven fabrics: thermal degradation behavior, flammability, and smoke suppression
verfasst von: Yun Liu
Ye Tao
Bin Wang
Ping Li
Ying-Jun Xu
Zhi-Ming Jiang
Chao-Hong Dong
Ping Zhu
Publikationsdatum: 24.04.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 10/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03162-1

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