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Polymer Bulletin
Erschienen in: Polymer Bulletin 7/2016

29.12.2015 | Original Paper

Functional modification of poly(vinyl alcohol) with maleimide compounds

verfasst von: Constantin Gaina, Viorica Gaina, Daniela Ionita

Erschienen in: Polymer Bulletin | Ausgabe 7/2016

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Abstract

A new synthetic way for obtaining poly(vinyl alcohol) functionalized with maleimide by the acetalization of poly(vinyl alcohol) with 4-formylphenyl-4-maleimidobenzoate and its cycloadducts with furan or anthracene to give the corresponding acetal was studied in detail. The deprotection of modified poly(vinyl alcohol) leaves the double bond of maleimide available for subsequent photocross-linking, “thiol click” or Diels–Alder reactions. The synthesized structures were confirmed by the Fourier transform infrared and the nuclear magnetic resonance (NMR) spectroscopy. The thermal deprotection of modified poly(vinyl alcohol) was investigated by the means of differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), NMR spectroscopy and TG-DSC/FTIR/mass spectrometer system.
Vorheriger Artikel Dynamic mechanical, mechanical and thermal analysis of CPI/NBR blends: effect of blend composition and crosslink density
Nächster Artikel Mechanical properties and biodegradability of porous polyurethanes reinforced with green nanofibers for applications in tissue engineering

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Metadaten
Titel
Functional modification of poly(vinyl alcohol) with maleimide compounds
verfasst von
Constantin Gaina
Viorica Gaina
Daniela Ionita
Publikationsdatum
29.12.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2016
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-015-1591-1

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