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2013 | OriginalPaper | Buchkapitel

Functional Polyolefins Through Polymerizations by Using Bis(indenyl) Zirconium Catalysts

verfasst von : Jukka Seppälä, Esa Kokko, Petri Lehmus, Anneli Pakkanen née Malmberg, Kimmo Hakala, Sami Lipponen, Barbro Löfgren

Erschienen in: Polyolefins: 50 years after Ziegler and Natta II

Verlag: Springer Berlin Heidelberg

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Abstract

The discovery of metallocene catalysts has enabled synthesis of new polyolefin structures through the ability to incorporate comonomers that are not applicable using Ziegler–Natta or other conventional olefin polymerization catalysts. Extensive research has been carried out on the copolymerization behavior of different bis(indenyl) zirconium catalysts in order to understand their comonomer response, chain termination mechanisms, and chain-end isomerization. Metallocene-catalyzed copolymerization enables unforeseen material structures, leading to functional polyolefins with strongly or weakly interacting comonomers or long-chain branches. These copolymers show interesting technical properties like reactive functionality, compatibility, adhesion properties, and modified rheology.

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Titel: Functional Polyolefins Through Polymerizations by Using Bis(indenyl) Zirconium Catalysts
verfasst von: Jukka Seppälä
Esa Kokko
Petri Lehmus
Anneli Pakkanen née Malmberg
Kimmo Hakala
Sami Lipponen
Barbro Löfgren
Verlag: Springer Berlin Heidelberg
Buch: Polyolefins: 50 years after Ziegler and Natta II
Print ISBN: 978-3-642-40804-5

Electronic ISBN: 978-3-642-40805-2

Copyright-Jahr: 2013
DOI: https://doi.org/10.1007/12_2013_210

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