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Journal of Electronic Materials
Erschienen in: Journal of Electronic Materials 6/2021

14.04.2021 | Original Research Article

Functionalization of Silver Nanoparticles with Carbohydrate Derivative for Colorimetric Assay of Thiram

verfasst von: Vishal Dhavle, Mehul R. Kateshiya, Tae-Jung Park, Suresh Kumar Kailasa

Erschienen in: Journal of Electronic Materials | Ausgabe 6/2021

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Abstract

The surface of silver nanoparticles (Ag NPs) was functionalized with a carbohydrate derivative (glutathione-lactose, GSH-Lac) to form GSH-Lac-Ag NPs for sensing of thiram in real samples with a rapid and sensitive visual readout. This colorimetric assay of thiram relies on the change in the surface plasmon resonance (SPR) band of the GSH-Lac-Ag NPs, resulting in their aggregation by thiram, which leads to a visual change of the GSH-Lac-Ag NPs from yellow to reddish brown. As a result, the SPR band of GSH-Lac-Ag NPs red-shifts from 406 nm to 458 nm, showing good linearity in the range of 0.01 µM to 3.00 µM (R2 = 0.9841) with a limit of detection (LOD) of 3.00 nM. Addition of other pesticides did not show a remarkable red-shift of the SPR band of the GSH-Lac-Ag NPs, indicating their high selectivity as a colorimetric sensor. This method enables a facile and portable analytical platform for on-site detection of thiram in real samples with minimum volume.

Graphic Abstract

Vorheriger Artikel Linear and Nonlinear Optical Properties of CuO NPs for Photonics
Nächster Artikel Temperature-Dependent Analytical Modeling of Graded-Channel Gate-All-Around (GC-GAA) Junctionless Field-Effect Transistors (JLFETs)

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Metadaten
Titel
Functionalization of Silver Nanoparticles with Carbohydrate Derivative for Colorimetric Assay of Thiram
verfasst von
Vishal Dhavle
Mehul R. Kateshiya
Tae-Jung Park
Suresh Kumar Kailasa
Publikationsdatum
14.04.2021
Verlag
Springer US
Erschienen in
Journal of Electronic Materials / Ausgabe 6/2021
Print ISSN: 0361-5235
Elektronische ISSN: 1543-186X
DOI
https://doi.org/10.1007/s11664-021-08875-y

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