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2019 | OriginalPaper | Buchkapitel

3. Fundamental Science of Gas Storage

verfasst von : Tomonori Ohba, Fernando Vallejos-Burgos, Katsumi Kaneko

Erschienen in: Nanoporous Materials for Gas Storage

Verlag: Springer Singapore

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Abstract

High-pressure adsorption measurement of supercritical gas needs accurate particle density which should be obtained by high-pressure He buoyancy measurement. As the surface excess mass adsorption is not greatly larger than the bulk gas contribution in the adsorbed layer, the absolute adsorption amount containing the bulk gas contribution in the adsorbed layer must be used for thermodynamic analysis and evaluation of the storage amount. The plot of the compression factor of adsorbed layer against the inverse of the average adsorbed layer density provides the Henry, virial, and cooperative types, giving information on the strength of the gas-solid interaction. The nanoporous material showing the cooperative type is promising for the storage of the target gas. Two factors of the strength of the gas-solid interaction and the surface area predict that nanopores consisting of narrow belt walls are promising for gas storage. Molecular simulation of methane in the graphitic pore over the wide temperature range from 120 to 300 K indicates an upward shift of the critical temperature of methane adsorbed in the graphitic pore. The heat of adsorption of methane in the graphitic pore without the heat-releasing mechanism elevates the temperature of the graphitic carbon by 70 K, decreasing the adsorption amount of methane by 30%; an efficient heat releasing mechanism must be installed in the storage device.

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Literatur
1.
Zurück zum Zitat Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KS (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem 87(9–10):1051–1069. https://doi.org/10.1515/pac-2014-1117 Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KS (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem 87(9–10):1051–1069. https://​doi.​org/​10.​1515/​pac-2014-1117
2.
Zurück zum Zitat Murata K, El-Merraoui M, Kaneko K (2001) A new determination method of absolute adsorption isotherm of supercritical gases under high pressure with a special relevance to density-functional theory study. J Chem Phys 114(9):4196–4205. https://doi.org/10.1063/1.1344926 CrossRef Murata K, El-Merraoui M, Kaneko K (2001) A new determination method of absolute adsorption isotherm of supercritical gases under high pressure with a special relevance to density-functional theory study. J Chem Phys 114(9):4196–4205. https://​doi.​org/​10.​1063/​1.​1344926 CrossRef
4.
Zurück zum Zitat Murata K, Kaneko K, Kanoh H, Kasuya D, Takahashi K, Kokai F, Yudasaka M, Iijima S (2002) Adsorption mechanism of supercritical hydrogen in internal and interstitial nanospaces of single-wall carbon nanohorn assembly. J Phys Chem B 106(43):11132–11138. https://doi.org/10.1021/jp020583u CrossRef Murata K, Kaneko K, Kanoh H, Kasuya D, Takahashi K, Kokai F, Yudasaka M, Iijima S (2002) Adsorption mechanism of supercritical hydrogen in internal and interstitial nanospaces of single-wall carbon nanohorn assembly. J Phys Chem B 106(43):11132–11138. https://​doi.​org/​10.​1021/​jp020583u CrossRef
20.
23.
Zurück zum Zitat Kondo A, Noguchi H, Ohnishi S, Kajiro H, Tohdoh A, Hattori Y, Xu WC, Tanaka H, Kanoh H, Kaneko K (2006) Novel expansion/shrinkage modulation of 2D layered MOF triggered by clathrate formation with CO2 molecules. Nano Lett 6(11):2581–2584. https://doi.org/10.1021/nl062032b CrossRef Kondo A, Noguchi H, Ohnishi S, Kajiro H, Tohdoh A, Hattori Y, Xu WC, Tanaka H, Kanoh H, Kaneko K (2006) Novel expansion/shrinkage modulation of 2D layered MOF triggered by clathrate formation with CO2 molecules. Nano Lett 6(11):2581–2584. https://​doi.​org/​10.​1021/​nl062032b CrossRef
24.
Zurück zum Zitat Nicholson D, Parsonage NG (1982) Computer simulation and the statistical mechanics of adsorption. Academic Press, google-Books-ID: 7HInFGsTVFwC Nicholson D, Parsonage NG (1982) Computer simulation and the statistical mechanics of adsorption. Academic Press, google-Books-ID: 7HInFGsTVFwC
26.
27.
Zurück zum Zitat Rigby M (1986) The forces between molecules. Clarendon Press, google-Books-ID: ckdCAQAAIAAJ Rigby M (1986) The forces between molecules. Clarendon Press, google-Books-ID: ckdCAQAAIAAJ
28.
Zurück zum Zitat Pace EL (1967) Adsorption thermodynamics and experimental measurement, vol 1, chap 4. Dekker, New York, pp 105–110 Pace EL (1967) Adsorption thermodynamics and experimental measurement, vol 1, chap 4. Dekker, New York, pp 105–110
29.
Zurück zum Zitat Ross S, Olivier JP (1964) On physical adsorption. Interscience Publishers, New York. google-Books-ID: DRBRAAAAMAAJ Ross S, Olivier JP (1964) On physical adsorption. Interscience Publishers, New York. google-Books-ID: DRBRAAAAMAAJ
30.
Zurück zum Zitat Fowler (1967) Statistical mechanics. CUP Archive, google-Books-ID: qLE8AAAAIAAJ Fowler (1967) Statistical mechanics. CUP Archive, google-Books-ID: qLE8AAAAIAAJ
31.
Zurück zum Zitat Hartl M, Gillis RC, Daemen L, Olds DP, Page K, Carlson S, Cheng Y, Hügle T, Iverson EB, Ramirez-Cuesta AJ et al (2016) Hydrogen adsorption on two catalysts for the ortho- to parahydrogen conversion: Cr-doped silica and ferric oxide gel. Phys Chem Chem Phys 18(26):17281–17293. https://doi.org/10.1039/C6CP01154C CrossRef Hartl M, Gillis RC, Daemen L, Olds DP, Page K, Carlson S, Cheng Y, Hügle T, Iverson EB, Ramirez-Cuesta AJ et al (2016) Hydrogen adsorption on two catalysts for the ortho- to parahydrogen conversion: Cr-doped silica and ferric oxide gel. Phys Chem Chem Phys 18(26):17281–17293. https://​doi.​org/​10.​1039/​C6CP01154C CrossRef
Metadaten
Titel
Fundamental Science of Gas Storage
verfasst von
Tomonori Ohba
Fernando Vallejos-Burgos
Katsumi Kaneko
Copyright-Jahr
2019
Verlag
Springer Singapore
DOI
https://doi.org/10.1007/978-981-13-3504-4_3