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Polymer Bulletin
Erschienen in: Polymer Bulletin 1/2019

30.05.2018 | Original Paper

Gamma radiation-induced preparation of poly(1-vinyl-2-pyrrolidone-co-sodium acrylate) for effective removal of Co(II), Ni(II), and Cu(II)

verfasst von: Ahmed Galal Ibrahim, Alaaeldine Shaker Saleh, Emad Mohamed Elsharma, Essam Metwally, Tharwat Siyam

Erschienen in: Polymer Bulletin | Ausgabe 1/2019

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Abstract

Clearing the water and wastewater from toxic heavy metals has received attentions from many researchers and scientists. In this study, poly(1-vinyl-2-pyrrolidone-co-sodium acrylate), P(VP-SA), was prepared by gamma radiation-induced copolymerization of VP and SA and utilized for the effective removal of cobalt(II), nickel(II), and copper(II) from their aqueous solutions. Effect of comonomer composition and concentration besides the adsorbed dose on the conversion percentage and the reduced viscosity was studied. The formed copolymer was characterized using Fourier transform infrared and gel permeation chromatography analysis, and the thermal stability was examined using thermogravimetric analysis. The influence of the adsorption conditions such as contact time, pH, copolymer concentration, and initial metal ion concentration on the metal ion binding capacity was tested. Pseudo-first-order, pseudo-second-order, and intraparticle diffusion adsorption models were used to explain the adsorption kinetics. Finally, the equilibrium adsorption data fitted well with Langmuir isotherm model, and the maximum adsorption amounts on P(VP-SA) copolymer calculated by Langmuir equation were 425.60, 93.01 and 450.81 mg g−1 for Cu+2, Ni+2, and Co+2, respectively.
Vorheriger Artikel PBAT/organoclay composite films—part 2: effect of UV aging on permeability, mechanical properties and biodegradation
Nächster Artikel New crystalline poly(aniline-co-benzidine)/bentonite microcomposites: synthesis and characterization

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Metadaten
Titel
Gamma radiation-induced preparation of poly(1-vinyl-2-pyrrolidone-co-sodium acrylate) for effective removal of Co(II), Ni(II), and Cu(II)
verfasst von
Ahmed Galal Ibrahim
Alaaeldine Shaker Saleh
Emad Mohamed Elsharma
Essam Metwally
Tharwat Siyam
Publikationsdatum
30.05.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 1/2019
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2379-x

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