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Erschienen in: Journal of Sol-Gel Science and Technology 2/2021

24.03.2021 | Original Paper: Sol-gel, hybrids and solution chemistries

Gelation of Konjac glucomannan crosslinked by organotitanium chelated with different ligands

verfasst von: Zhixin Zhao, Shanjun Gao, Yunzhe Li, Fucheng Wu, Chunhui Shen

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2021

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Abstract

Konjac Glucomannan (KGM) gels can be formed in the presence of organotitanium as crosslinkers which were chelated by different organic compounds. Organotitanium cross-linking agent is a chelate formed by coordination between tetrabutyl titanate and different organic compounds. The gel network was formed through the crosslinking reaction between titanium ions dissociated from organotitanium crosslinkers and the cis-diol hydroxyl groups on the mannose units of polysaccharide chains. Effect of concentration and species of ligands on rheological properties of the complex gels was studied by dynamic viscoelastic measurements. The gelation kinetics of the gels were investigated and the critical gelation points of the gels were accurately determined according to the Winter-Chambon criterion. The effects of kinds and concentrations of ligands on the shear storage modulus (G’), the loss modulus (G”), and the sol-gel transition points were studied. The sol-gel transition time varies with different ligands in the organotitanium crosslinkers. The sol-gel transition time and temperature were obviously observed and in good agreement with Winter–Chambon criterion.

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Literatur
1.
Zurück zum Zitat McGlade CE (2012) A review of the uncertainties in estimates of global oil resources. Energy 47:262–270CrossRef McGlade CE (2012) A review of the uncertainties in estimates of global oil resources. Energy 47:262–270CrossRef
2.
Zurück zum Zitat Legemah M, Guerin M, Sun H et al. (2014) Novel high-efficiency boron crosslinkers for low-polymer-loading fracturing fluids. SPE J 19:737–743CrossRef Legemah M, Guerin M, Sun H et al. (2014) Novel high-efficiency boron crosslinkers for low-polymer-loading fracturing fluids. SPE J 19:737–743CrossRef
3.
Zurück zum Zitat Liu J, Wang S, Wang C et al. (2020) Influence of nanomaterial morphology of guar-gum fracturing fluid, physical and mechanical properties. Carbohydr Polym 234:115915CrossRef Liu J, Wang S, Wang C et al. (2020) Influence of nanomaterial morphology of guar-gum fracturing fluid, physical and mechanical properties. Carbohydr Polym 234:115915CrossRef
4.
Zurück zum Zitat Kato K, Matsuda K (1969) Studies on the chemical structure of konjac mannan. Part I. Isolation and characterization of oligosaccharides from the partial acid hydrolyzate of the mannan. Agriculture Biol Chem 33:1446–1453 Kato K, Matsuda K (1969) Studies on the chemical structure of konjac mannan. Part I. Isolation and characterization of oligosaccharides from the partial acid hydrolyzate of the mannan. Agriculture Biol Chem 33:1446–1453
5.
Zurück zum Zitat Kishida N, Okimasu S, Kamata T (1978) Molecular weight and intrinsic viscosity of konjac glucomannan. Agric Biol Chem 42:1645–1650 Kishida N, Okimasu S, Kamata T (1978) Molecular weight and intrinsic viscosity of konjac glucomannan. Agric Biol Chem 42:1645–1650
6.
Zurück zum Zitat Annable P, Williams PA, Nishinari K (2002) Interaction in xanthan-glucomannan mixtures and the influence of electrolyte. Macromolecules 27:4204–4211CrossRef Annable P, Williams PA, Nishinari K (2002) Interaction in xanthan-glucomannan mixtures and the influence of electrolyte. Macromolecules 27:4204–4211CrossRef
7.
Zurück zum Zitat Williams PA, Clegg SM, Langdon MJ et al. (1993) Investigation of the gelation mechanism in k-carrageenan/konjac mannan mixtures using differential scanning calorimetry and electron spin resonance spectroscopy. Macromolecules 26:0024–9297CrossRef Williams PA, Clegg SM, Langdon MJ et al. (1993) Investigation of the gelation mechanism in k-carrageenan/konjac mannan mixtures using differential scanning calorimetry and electron spin resonance spectroscopy. Macromolecules 26:0024–9297CrossRef
8.
Zurück zum Zitat Ridout MJ, Gunning AP, Morris VJ et al. (1998) Characterisation of the polysaccharide produced by Acetobacter xylinum strain CR1/4 by light scattering and atomic force microscopy. Int J Biol Macromolecules 23:287–293CrossRef Ridout MJ, Gunning AP, Morris VJ et al. (1998) Characterisation of the polysaccharide produced by Acetobacter xylinum strain CR1/4 by light scattering and atomic force microscopy. Int J Biol Macromolecules 23:287–293CrossRef
9.
Zurück zum Zitat Gao S, Wu C, Nishinari K (2008) In situ pH-decrease-induced gelation of sodium alginate/carboxymethylated konjac glucomannan. J Appl Polym Sci 108:2825–2832CrossRef Gao S, Wu C, Nishinari K (2008) In situ pH-decrease-induced gelation of sodium alginate/carboxymethylated konjac glucomannan. J Appl Polym Sci 108:2825–2832CrossRef
10.
Zurück zum Zitat Gao S, Guo J, Wu L et al. (2008) Gelation of konjac glucomannan crosslinked by organic borate. Carbohydr Polym 73:498–505CrossRef Gao S, Guo J, Wu L et al. (2008) Gelation of konjac glucomannan crosslinked by organic borate. Carbohydr Polym 73:498–505CrossRef
11.
Zurück zum Zitat Goel N, Shah SN, Yuan W et al. (2001) Suspension characteristics of borate-crosslinked gels: Rheology and atomic force microscopy measurements. J Appl Polym Sci 8229:78–2990 Goel N, Shah SN, Yuan W et al. (2001) Suspension characteristics of borate-crosslinked gels: Rheology and atomic force microscopy measurements. J Appl Polym Sci 8229:78–2990
12.
Zurück zum Zitat Li R, Zeng H, Zhou X (2013) Inorganic chemistry (21th ed.). Beijing: Chemical Industry Press Li R, Zeng H, Zhou X (2013) Inorganic chemistry (21th ed.). Beijing: Chemical Industry Press
13.
Zurück zum Zitat Dai C, Zhao G, You Q et al. (2014) A study on environment‐friendly polymer gel for water shut-off treatments in low-temperature reservoirs. J Appl Polym Sci 131:1–7 Dai C, Zhao G, You Q et al. (2014) A study on environment‐friendly polymer gel for water shut-off treatments in low-temperature reservoirs. J Appl Polym Sci 131:1–7
14.
Zurück zum Zitat Allain C, Salome L (1987) Sol-gel transition of hydrolyzed polyacrylamide –chromium (III): Rheological behavior versus cross-link concentration. Macromolecules 20:2957–2958CrossRef Allain C, Salome L (1987) Sol-gel transition of hydrolyzed polyacrylamide –chromium (III): Rheological behavior versus cross-link concentration. Macromolecules 20:2957–2958CrossRef
15.
Zurück zum Zitat Ahad E (1974) Differential scanning calorimetry of aqueous polymer solutions and gels. J Appl Polym Sci 18:1587–1602CrossRef Ahad E (1974) Differential scanning calorimetry of aqueous polymer solutions and gels. J Appl Polym Sci 18:1587–1602CrossRef
16.
Zurück zum Zitat Li C (2011) Preparation of Organic Zirconium Composite Crosslinking Agent and Research on Crosslinking. Xi’an Shiyou University Li C (2011) Preparation of Organic Zirconium Composite Crosslinking Agent and Research on Crosslinking. Xi’an Shiyou University
17.
Zurück zum Zitat Gao S, Nishinari K, Guo J (2007) Thermoreversible konjac glucomannan gel crosslinked by borax. Carbohydr Polym 72:315–325CrossRef Gao S, Nishinari K, Guo J (2007) Thermoreversible konjac glucomannan gel crosslinked by borax. Carbohydr Polym 72:315–325CrossRef
18.
Zurück zum Zitat Brannon H, Ault M (1991) New delayed borate-crosslinked fluid provides improved fracture conductivity in high-temperature applications. SPE 22838 Brannon H, Ault M (1991) New delayed borate-crosslinked fluid provides improved fracture conductivity in high-temperature applications. SPE 22838
19.
Zurück zum Zitat Li X, Liu H, Jiang A et al. (2012) Research and application of ultra-high temperature organic boron crosslinking agent. Oilfield Chemistry 29:80–82 Li X, Liu H, Jiang A et al. (2012) Research and application of ultra-high temperature organic boron crosslinking agent. Oilfield Chemistry 29:80–82
20.
Zurück zum Zitat Ma G, Shen Y, Wei Z (2013) An organic titanium crosslinking agent and its preparation method and use method. China Patent CN103113874A May 22 Ma G, Shen Y, Wei Z (2013) An organic titanium crosslinking agent and its preparation method and use method. China Patent CN103113874A May 22
21.
Zurück zum Zitat Xu Y, Shen C, Gao S (2015) Preparation and characterization of chitosan gel beads crosslinked by organic titanium. J Polym Res 22:53CrossRef Xu Y, Shen C, Gao S (2015) Preparation and characterization of chitosan gel beads crosslinked by organic titanium. J Polym Res 22:53CrossRef
22.
Zurück zum Zitat Gao S, Nishinari K (2004) Effect of deacetylation rate on gelation kinetics of konjac glucomannan. Colloids Surf B: Biointerfaces 38:241–249CrossRef Gao S, Nishinari K (2004) Effect of deacetylation rate on gelation kinetics of konjac glucomannan. Colloids Surf B: Biointerfaces 38:241–249CrossRef
23.
Zurück zum Zitat Gao S, Nishinari K (2004) Effect of degree of acetylation on gelation behavior of konjac glucomannan. Biomacromolecules 5:175–185CrossRef Gao S, Nishinari K (2004) Effect of degree of acetylation on gelation behavior of konjac glucomannan. Biomacromolecules 5:175–185CrossRef
24.
Zurück zum Zitat Xie W, Song Z, Liu Z (2016) Surface modification of PCC with guar gum using organic titanium ionic crosslinking agent and its application as papermaking filler. Carbohydr Polym 150:114–120CrossRef Xie W, Song Z, Liu Z (2016) Surface modification of PCC with guar gum using organic titanium ionic crosslinking agent and its application as papermaking filler. Carbohydr Polym 150:114–120CrossRef
25.
Zurück zum Zitat Driscoll P, Bowen J, Mark A(1980) Oil Base Foam Fracturing Applied to The Niobrara Shale Formation. SPE 9335 Driscoll P, Bowen J, Mark A(1980) Oil Base Foam Fracturing Applied to The Niobrara Shale Formation. SPE 9335
26.
Zurück zum Zitat DuPont Inc, Versatile Tyzor Organic Titanates, Product brochure, Wilmington, Delaware DuPont Inc, Versatile Tyzor Organic Titanates, Product brochure, Wilmington, Delaware
27.
Zurück zum Zitat Rondesvadt C (1976) Titanium Compounds (Organic), Kirk-Othmer Encyclopedia of Chemical Technology, Vo123, 3rd ed Rondesvadt C (1976) Titanium Compounds (Organic), Kirk-Othmer Encyclopedia of Chemical Technology, Vo123, 3rd ed
28.
Zurück zum Zitat Kramer J, Prud’Homme R, Wiltzius P et al. (1988) Comparison of galactomannan crosslinking with organotitanates and borates[J]. Colloid Polym Sci 266:145–155CrossRef Kramer J, Prud’Homme R, Wiltzius P et al. (1988) Comparison of galactomannan crosslinking with organotitanates and borates[J]. Colloid Polym Sci 266:145–155CrossRef
29.
Zurück zum Zitat Nishinari K, Zhang H, Ikeda S (2000) Hydrocolloid gels of polysaccharides and proteins. Curr Opin Colloid Interface Sci 5:195–201CrossRef Nishinari K, Zhang H, Ikeda S (2000) Hydrocolloid gels of polysaccharides and proteins. Curr Opin Colloid Interface Sci 5:195–201CrossRef
30.
Zurück zum Zitat Nishinari K, Takahashi R (2003) Interaction in polysaccharide solutions and gels. Curr Opin Colloid Interface Sci 8:396–400CrossRef Nishinari K, Takahashi R (2003) Interaction in polysaccharide solutions and gels. Curr Opin Colloid Interface Sci 8:396–400CrossRef
31.
Zurück zum Zitat M Doi (1980) Molecular rheology of concentrated polymer systems. I. J Polym Sci Polym Phys Ed 18:1005–1020CrossRef M Doi (1980) Molecular rheology of concentrated polymer systems. I. J Polym Sci Polym Phys Ed 18:1005–1020CrossRef
32.
Zurück zum Zitat Chambon F, Winter HH (1985) Stopping of crosslinking reaction in a PDMS polymer at the gel point. Polym Bull 13:499–50CrossRef Chambon F, Winter HH (1985) Stopping of crosslinking reaction in a PDMS polymer at the gel point. Polym Bull 13:499–50CrossRef
33.
Zurück zum Zitat Koike A, Takada A, Nemoto N (1998) Structure and dynamics of ovalbumin gels: II. Gels induced by heat treatment at 80 °C. Polym Gels Netw 6:257–271CrossRef Koike A, Takada A, Nemoto N (1998) Structure and dynamics of ovalbumin gels: II. Gels induced by heat treatment at 80 °C. Polym Gels Netw 6:257–271CrossRef
34.
Zurück zum Zitat Chambon F, Winter HH (1985) Stopping of crosslinking reaction in a PDMS polymer at the gel point. Polym Bull 13:499–50CrossRef Chambon F, Winter HH (1985) Stopping of crosslinking reaction in a PDMS polymer at the gel point. Polym Bull 13:499–50CrossRef
35.
Zurück zum Zitat Hellio-Serughetti D, Djabourov M (2006) Gelatin hydrogels cross- linked with bis(vinylsulfonyl)methane (BVSM): 1. The chemical networks. Langmuir 22:8509–8515CrossRef Hellio-Serughetti D, Djabourov M (2006) Gelatin hydrogels cross- linked with bis(vinylsulfonyl)methane (BVSM): 1. The chemical networks. Langmuir 22:8509–8515CrossRef
36.
Zurück zum Zitat Te Nijenhuis K, Winter HH (1989) Mechanical properties at the gel point of crystallizing poly vinyl chloride solutions. Macromolecules 22:411–414CrossRef Te Nijenhuis K, Winter HH (1989) Mechanical properties at the gel point of crystallizing poly vinyl chloride solutions. Macromolecules 22:411–414CrossRef
37.
Zurück zum Zitat Rodd AB, Dunstan DE, Ross-Murphy SB et al. (2001) Dependence of linear viscoelastic critical strain and stress values on extent of gelation for a thermally activated gelling system. Rheologica Acta 40:23–29CrossRef Rodd AB, Dunstan DE, Ross-Murphy SB et al. (2001) Dependence of linear viscoelastic critical strain and stress values on extent of gelation for a thermally activated gelling system. Rheologica Acta 40:23–29CrossRef
38.
Zurück zum Zitat Huang L, Takahashi R, Kobayashi S et al. (2002) Gelation behavior of native acetylated konjac glucomannan. Biomacromolecules 3:1296–130CrossRef Huang L, Takahashi R, Kobayashi S et al. (2002) Gelation behavior of native acetylated konjac glucomannan. Biomacromolecules 3:1296–130CrossRef
39.
Zurück zum Zitat Shinzo Y, Toshisuke K (1990) Cross-linking agent manual (8 th ed.). Beijing: Chemical Industry Press Shinzo Y, Toshisuke K (1990) Cross-linking agent manual (8 th ed.). Beijing: Chemical Industry Press
Metadaten
Titel
Gelation of Konjac glucomannan crosslinked by organotitanium chelated with different ligands
verfasst von
Zhixin Zhao
Shanjun Gao
Yunzhe Li
Fucheng Wu
Chunhui Shen
Publikationsdatum
24.03.2021
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 2/2021
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-021-05517-x

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