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Erschienen in:
Introduction to Ionic Liquids Kapitel lesen Erstes Kapitel lesen

2016 | OriginalPaper | Buchkapitel

5. Glassy Dynamics and Charge Transport in Polymeric Ionic Liquids

verfasst von : Falk Frenzel, Wolfgang H. Binder, Joshua Rume Sangoro, Friedrich Kremer

Erschienen in: Dielectric Properties of Ionic Liquids

Verlag: Springer International Publishing

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Abstract

While glassy dynamics and (ionic) charge transport coincide in low-molecular weight ionic liquids (ILs), they are widely decoupled in corresponding polymeric systems. This is studied by means of broadband dielectric spectroscopy (BDS) for monovalent and bivalent telechelic polyisobutylene (PIB) carrying the Ionic Liquid (IL)-like cationic headgroup (N,N,N-triethylammonium or 1-methylpyrrolidinium) with Br, NTf2, OTf or pTOS as anions, as well as for neat and polymerized 1-vinyl-3-pentylimidazolium bis-(trifluoromethylsulfonyl) imide (PVIM NTf2). The former shows a wealth of dielectrically active fluctuations in contrast to the latter, where only the dynamic glass transition is observed. Additionally a conductivity relaxation originating from charge transport in the IL-like moieties and a weak electrode polarization caused by the accumulation of mobile charge carriers at the metal interfaces is found. In both systems molecular fluctuations and charge transport are well separated from each other thereby enabling accurate description of the net conductivity within the framework of the effective medium approximation for the PIB-based systems.

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Vorheriges Kapitel High-Pressure Dielectric Spectroscopy for Studying the Charge Transfer in Ionic Liquids and Solids
Nächstes Kapitel Ionic Transport and Dielectric Relaxation in Polymer Electrolytes
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Metadaten
Titel
Glassy Dynamics and Charge Transport in Polymeric Ionic Liquids
verfasst von
Falk Frenzel
Wolfgang H. Binder
Joshua Rume Sangoro
Friedrich Kremer
Copyright-Jahr
2016
Buch
Dielectric Properties of Ionic Liquids

Print ISBN: 978-3-319-32487-6

Electronic ISBN: 978-3-319-32489-0

Copyright-Jahr: 2016

DOI
https://doi.org/10.1007/978-3-319-32489-0_5

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