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2016 | OriginalPaper | Buchkapitel

1. Glycosides, Synthesis and Characterization

verfasst von : Marco Brito-Arias

Erschienen in: Synthesis and Characterization of Glycosides

Verlag: Springer International Publishing

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Abstract

Monosaccharides are generally defined as aldoses and ketoses connected to a polyhydroxylated skeleton [1]. In an aqueous solution, monosaccharides are subject to internal nucleophilic addition to form cyclic hemiacetal structures. When addition occurs between -OH at C(4) or -OH at C(5), and the carbonyl group, a five- or a six-member ring is formed called a furanose or a pyranose respectively. It is also known that an equilibrium exists between the open and the cyclic form, being displaced to the latter by more than 90 %. Therefore, in aqueous solution, it is more accurate to consider that most sugars are present as cyclic molecules and behave chemically as hemiacetals.

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Titel: Glycosides, Synthesis and Characterization
verfasst von: Marco Brito-Arias
Verlag: Springer International Publishing
Buch: Synthesis and Characterization of Glycosides
Print ISBN: 978-3-319-32308-4

Electronic ISBN: 978-3-319-32310-7

Copyright-Jahr: 2016
DOI: https://doi.org/10.1007/978-3-319-32310-7_1

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