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2014 | OriginalPaper | Buchkapitel

Gold Nanoclusters: Size-Controlled Synthesis and Crystal Structures

verfasst von : Chenjie Zeng, Rongchao Jin

Erschienen in: Gold Clusters, Colloids and Nanoparticles I

Verlag: Springer International Publishing

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Abstract

One of the major goals in nanoparticle research is to investigate their unique properties not seen in bulk materials or small molecules. In this chapter, we focus on a new class of gold nanoparticles (often called nanoclusters) that possess atomic precision (as opposed to conventional nanoparticles with a size distribution). The synthetic methods for obtaining atomically precise thiolate-protected gold nanocluters are first discussed, followed by the anatomy of the X-ray crystal structures of gold nanoclusters.

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Literatur
1.
Zurück zum Zitat Jin R, Cao Y, Mirkin CA, Kelly KL, Schatz GC, Zheng JG (2001) Photoinduced conversion of silver nanospheres to nanoprisms. Science 294:1901–1903CrossRef Jin R, Cao Y, Mirkin CA, Kelly KL, Schatz GC, Zheng JG (2001) Photoinduced conversion of silver nanospheres to nanoprisms. Science 294:1901–1903CrossRef
2.
Zurück zum Zitat Jin R (2010) Quantum sized thiolate-protected gold nanoclusters. Nanoscale 2:343–362CrossRef Jin R (2010) Quantum sized thiolate-protected gold nanoclusters. Nanoscale 2:343–362CrossRef
3.
Zurück zum Zitat Qian H, Zhu M, Wu Z, Jin R (2012) Quantum sized gold nanoclusters with atomic precision. Acc Chem Res 45:1470CrossRef Qian H, Zhu M, Wu Z, Jin R (2012) Quantum sized gold nanoclusters with atomic precision. Acc Chem Res 45:1470CrossRef
4.
Zurück zum Zitat Negishi Y, Nobusada K, Tsukuda T (2005) Glutathione-protected gold clusters revisited: bridging the gap between gold(I)-thiolate complexes and thiolate-protected gold nanocrystals. J Am Chem Soc 127:5261–5270CrossRef Negishi Y, Nobusada K, Tsukuda T (2005) Glutathione-protected gold clusters revisited: bridging the gap between gold(I)-thiolate complexes and thiolate-protected gold nanocrystals. J Am Chem Soc 127:5261–5270CrossRef
5.
Zurück zum Zitat Tracy JB, Crowe MC, Parker JF, Hampe O, Fields-Zinna CA, Dass A, Murray RW (2007) Electrospray ionization mass spectrometry of uniform and mixed monolayer nanoparticles: Au25[S(CH2)2Ph]18 and Au25[S(CH2)2Ph]18-x(SR)x. J Am Chem Soc 129:16209–16215CrossRef Tracy JB, Crowe MC, Parker JF, Hampe O, Fields-Zinna CA, Dass A, Murray RW (2007) Electrospray ionization mass spectrometry of uniform and mixed monolayer nanoparticles: Au25[S(CH2)2Ph]18 and Au25[S(CH2)2Ph]18-x(SR)x. J Am Chem Soc 129:16209–16215CrossRef
6.
Zurück zum Zitat Qian H, Zhu M, Andersen UN, Jin R (2009) Facile, large-scale synthesis of dodecanethiol-stabilized Au38 clusters. J Phys Chem A 113:4281–4284CrossRef Qian H, Zhu M, Andersen UN, Jin R (2009) Facile, large-scale synthesis of dodecanethiol-stabilized Au38 clusters. J Phys Chem A 113:4281–4284CrossRef
7.
Zurück zum Zitat Jadzinsky PD, Calero G, Ackerson CJ, Bushnell DA, Kornberg RD (2007) Structure of a thiol monolayer-protected gold nanoparticle at 1.1Å resolution. Science 318:430–433CrossRef Jadzinsky PD, Calero G, Ackerson CJ, Bushnell DA, Kornberg RD (2007) Structure of a thiol monolayer-protected gold nanoparticle at 1.1Å resolution. Science 318:430–433CrossRef
8.
Zurück zum Zitat Heaven MW, Dass A, White PS, Holt KM, Murray RW (2008) Crystal structure of the gold nanoparticle [N(C8H17)4][Au25(SCH2CH2Ph)18]. J Am Chem Soc 130:3754–3755CrossRef Heaven MW, Dass A, White PS, Holt KM, Murray RW (2008) Crystal structure of the gold nanoparticle [N(C8H17)4][Au25(SCH2CH2Ph)18]. J Am Chem Soc 130:3754–3755CrossRef
9.
Zurück zum Zitat Zhu M, Aikens CM, Hollander FJ, Schatz GC, Jin R (2008) Correlating the crystal structure of a thiol-protected Au25 cluster and optical properties. J Am Chem Soc 130:5883–5885CrossRef Zhu M, Aikens CM, Hollander FJ, Schatz GC, Jin R (2008) Correlating the crystal structure of a thiol-protected Au25 cluster and optical properties. J Am Chem Soc 130:5883–5885CrossRef
10.
Zurück zum Zitat Qian H, Eckenhoff WT, Zhu Y, Pintauer T, Jin R (2010) Total structure determination of thiolate-protected Au38 nanoparticles. J Am Chem Soc 132:8280–8281CrossRef Qian H, Eckenhoff WT, Zhu Y, Pintauer T, Jin R (2010) Total structure determination of thiolate-protected Au38 nanoparticles. J Am Chem Soc 132:8280–8281CrossRef
11.
Zurück zum Zitat Zeng C, Qian H, Li T, Li G, Rosi NL, Yoon B, Barnett RN, Whetten RL, Landman U, Jin R (2012) Total structure and electronic properties of the gold nanocrystal Au36(SR)24. Angew Chem Int Ed 51:13114–13118CrossRef Zeng C, Qian H, Li T, Li G, Rosi NL, Yoon B, Barnett RN, Whetten RL, Landman U, Jin R (2012) Total structure and electronic properties of the gold nanocrystal Au36(SR)24. Angew Chem Int Ed 51:13114–13118CrossRef
12.
Zurück zum Zitat Zeng C, Li T, Das A, Rosi NL, Jin R (2013) Chiral structure of thiolate-protected 28-Gold-atom nanocluster determined by X-ray crystallography. J Am Chem Soc 135:10011–10013CrossRef Zeng C, Li T, Das A, Rosi NL, Jin R (2013) Chiral structure of thiolate-protected 28-Gold-atom nanocluster determined by X-ray crystallography. J Am Chem Soc 135:10011–10013CrossRef
13.
Zurück zum Zitat Zhu M, Eckenhoff WT, Pintauer T, Jin R (2008) Conversion of anionic [Au25(SCH2CH2Ph)18]− cluster to charge neutral cluster via air oxidation. J Phys Chem C 112:14221–14224CrossRef Zhu M, Eckenhoff WT, Pintauer T, Jin R (2008) Conversion of anionic [Au25(SCH2CH2Ph)18] cluster to charge neutral cluster via air oxidation. J Phys Chem C 112:14221–14224CrossRef
14.
Zurück zum Zitat Wu Z, Gayathri C, Gil RR, Jin R (2009) Probing the structure and charge state of glutathione-capped Au25(SG)18 clusters by NMR and mass spectrometry. J Am Chem Soc 131:6535–6542CrossRef Wu Z, Gayathri C, Gil RR, Jin R (2009) Probing the structure and charge state of glutathione-capped Au25(SG)18 clusters by NMR and mass spectrometry. J Am Chem Soc 131:6535–6542CrossRef
15.
Zurück zum Zitat Qian H, Zhu M, Gayathri C, Gil RR, Jin R (2011) Chirality in gold nanoclusters probed by NMR spectroscopy. ACS Nano 5:8935–8942CrossRef Qian H, Zhu M, Gayathri C, Gil RR, Jin R (2011) Chirality in gold nanoclusters probed by NMR spectroscopy. ACS Nano 5:8935–8942CrossRef
16.
Zurück zum Zitat McPartlin M, Mason R, Malatesta L (1969) Novel cluster complexes of gold(0)-gold(I). J Chem Soc D 334–334 McPartlin M, Mason R, Malatesta L (1969) Novel cluster complexes of gold(0)-gold(I). J Chem Soc D 334–334
17.
Zurück zum Zitat Briant CE, Theobald BRC, White JW, Bell LK, Mingos DMP, Welch AJ (1981) Synthesis and X-ray structural characterization of the centred icosahedral gold cluster compound [Aul3(PMe2Ph)10Cl2](PF6)3; the realization of a theoretical prediction. J Chem Soc Chem Commun 201–202 Briant CE, Theobald BRC, White JW, Bell LK, Mingos DMP, Welch AJ (1981) Synthesis and X-ray structural characterization of the centred icosahedral gold cluster compound [Aul3(PMe2Ph)10Cl2](PF6)3; the realization of a theoretical prediction. J Chem Soc Chem Commun 201–202
18.
Zurück zum Zitat Schmid G, Pfeil R, Boese R, Bandermann F, Meyer S, Calis GHM, Vandervelden WA (1981) Au55[P(C6H5)3]12Cl6 − a gold cluster of an exceptional size. Chem Ber 114:3634–3642CrossRef Schmid G, Pfeil R, Boese R, Bandermann F, Meyer S, Calis GHM, Vandervelden WA (1981) Au55[P(C6H5)3]12Cl6 − a gold cluster of an exceptional size. Chem Ber 114:3634–3642CrossRef
19.
Zurück zum Zitat Teo BK, Shi XB, Zhang H (1992) Pure gold cluster of 1:9:9:1:9:9:1 layered structure: a novel 39-metal-atom cluster [(Ph3P)14Au39Cl6]Cl2 with an interstitial gold atom in a hexagonal antiprismatic cage. J Am Chem Soc 114:2743–2745CrossRef Teo BK, Shi XB, Zhang H (1992) Pure gold cluster of 1:9:9:1:9:9:1 layered structure: a novel 39-metal-atom cluster [(Ph3P)14Au39Cl6]Cl2 with an interstitial gold atom in a hexagonal antiprismatic cage. J Am Chem Soc 114:2743–2745CrossRef
20.
Zurück zum Zitat Teo BK, Shi X, Zhang H (1991) Cluster of clusters. structure of a novel gold-silver cluster [(Ph3P)10Au13Ag12Br8](SbF6) containing an exact staggered-eclipsed-staggered metal configuration. Evidence of icosahedral units as building blocks. J Am Chem Soc 113:4329–4331CrossRef Teo BK, Shi X, Zhang H (1991) Cluster of clusters. structure of a novel gold-silver cluster [(Ph3P)10Au13Ag12Br8](SbF6) containing an exact staggered-eclipsed-staggered metal configuration. Evidence of icosahedral units as building blocks. J Am Chem Soc 113:4329–4331CrossRef
21.
Zurück zum Zitat Boon KT, Hong MC, Hong Z, Huang DB (1987) Cluster of clusters: structure of the 37-atom cluster [(p-Tol3P)12Au18Ag19Br11]2+ and a novel series of supraclusters based on vertex-sharing icosahedra. Angew Chem Int Ed 26:897–900CrossRef Boon KT, Hong MC, Hong Z, Huang DB (1987) Cluster of clusters: structure of the 37-atom cluster [(p-Tol3P)12Au18Ag19Br11]2+ and a novel series of supraclusters based on vertex-sharing icosahedra. Angew Chem Int Ed 26:897–900CrossRef
22.
Zurück zum Zitat Teo BK, Shi X, Zhang H (1993) Clusters of clusters. 25. Synthesis and structure of a new [gold-silver]-38-metal-atom cluster [(Ph3P)14Au18Ag20Cl12]Cl2 and its implications with regard to intracavity chemistry on metal cluster surfaces. Inorg Chem 32:3987–3988CrossRef Teo BK, Shi X, Zhang H (1993) Clusters of clusters. 25. Synthesis and structure of a new [gold-silver]-38-metal-atom cluster [(Ph3P)14Au18Ag20Cl12]Cl2 and its implications with regard to intracavity chemistry on metal cluster surfaces. Inorg Chem 32:3987–3988CrossRef
23.
Zurück zum Zitat Tran NT, Powell DR, Dahl LF (2000) Nanosized Pd145(CO)x(PEt3)30 containing a capped three-shell 145-atom metal-core geometry of pseudo icosahedral symmetry. Angew Chem Int Ed 39:4121–4125CrossRef Tran NT, Powell DR, Dahl LF (2000) Nanosized Pd145(CO)x(PEt3)30 containing a capped three-shell 145-atom metal-core geometry of pseudo icosahedral symmetry. Angew Chem Int Ed 39:4121–4125CrossRef
24.
Zurück zum Zitat Tran NT, Dahl LF (2003) Nanosized [Pd69(CO)36(PEt3)18]: metal-core geometry containing a linear assembly of three face-sharing centered Pd33 icosahedra inside of a hexagonal-shaped Pd30 tube. Angew Chem Int Ed 42:3533–3537CrossRef Tran NT, Dahl LF (2003) Nanosized [Pd69(CO)36(PEt3)18]: metal-core geometry containing a linear assembly of three face-sharing centered Pd33 icosahedra inside of a hexagonal-shaped Pd30 tube. Angew Chem Int Ed 42:3533–3537CrossRef
25.
Zurück zum Zitat Mednikov EG, Ivanov SA, Slovokhotova IV, Dahl LF (2005) Nanosized [Pd52(CO)36(PEt3)14] and [Pd66(CO)45(PEt3)16] clusters based on a hypothetical Pd38 vertex-truncated ν 3 octahedron. Angew Chem Int Ed 44:6848–6854CrossRef Mednikov EG, Ivanov SA, Slovokhotova IV, Dahl LF (2005) Nanosized [Pd52(CO)36(PEt3)14] and [Pd66(CO)45(PEt3)16] clusters based on a hypothetical Pd38 vertex-truncated ν 3 octahedron. Angew Chem Int Ed 44:6848–6854CrossRef
26.
Zurück zum Zitat Mednikov EG, Dahl LF (2008) Nanosized Pd37(CO)28{P(p-Tolyl)3}12 containing geometrically unprecedented central 23-atom interpenetrating tri-icosahedral palladium kernel of double icosahedral units: its postulated metal-core evolution and resulting stereochemical implications. J Am Chem Soc 130:14813–14821CrossRef Mednikov EG, Dahl LF (2008) Nanosized Pd37(CO)28{P(p-Tolyl)3}12 containing geometrically unprecedented central 23-atom interpenetrating tri-icosahedral palladium kernel of double icosahedral units: its postulated metal-core evolution and resulting stereochemical implications. J Am Chem Soc 130:14813–14821CrossRef
27.
Zurück zum Zitat Shichibu Y, Konishi K (2010) HCl-induced nuclearity convergence in diphosphine-protected ultrasmall gold clusters: a novel synthetic route to “Magic-Number” Au13 clusters. Small 6:1216–1220CrossRef Shichibu Y, Konishi K (2010) HCl-induced nuclearity convergence in diphosphine-protected ultrasmall gold clusters: a novel synthetic route to “Magic-Number” Au13 clusters. Small 6:1216–1220CrossRef
28.
Zurück zum Zitat Pettibone JM, Hudgens JW (2011) Gold cluster formation with phosphine ligands: etching as a size-selective synthetic pathway for small clusters? ACS Nano 5:2989–3002CrossRef Pettibone JM, Hudgens JW (2011) Gold cluster formation with phosphine ligands: etching as a size-selective synthetic pathway for small clusters? ACS Nano 5:2989–3002CrossRef
29.
Zurück zum Zitat Wan X-K, Lin Z-W, Wang Q-M (2012) Au20 nanocluster protected by hemilabile phosphines. J Am Chem Soc 134:14750–14752CrossRef Wan X-K, Lin Z-W, Wang Q-M (2012) Au20 nanocluster protected by hemilabile phosphines. J Am Chem Soc 134:14750–14752CrossRef
30.
Zurück zum Zitat Shichibu Y, Negishi Y, Watanabe T, Chaki NK, Kawaguchi H, Tsukuda T (2007) Biicosahedral gold clusters [Au25(PPh3)10(SCnH2n+1)5Cl2]2+ (n = 2-18): a stepping stone to cluster-assembled materials. J Phys Chem C 111:7845–7847CrossRef Shichibu Y, Negishi Y, Watanabe T, Chaki NK, Kawaguchi H, Tsukuda T (2007) Biicosahedral gold clusters [Au25(PPh3)10(SCnH2n+1)5Cl2]2+ (n = 2-18): a stepping stone to cluster-assembled materials. J Phys Chem C 111:7845–7847CrossRef
31.
Zurück zum Zitat Qian H, Eckenhoff WT, Bier ME, Pintauer T, Jin R (2011) Crystal structures of Au2 complex and Au25 nanocluster and mechanistic insight into the conversion of polydisperse nanoparticles into monodisperse Au25 nanoclusters. Inorg Chem 50:10735–10739CrossRef Qian H, Eckenhoff WT, Bier ME, Pintauer T, Jin R (2011) Crystal structures of Au2 complex and Au25 nanocluster and mechanistic insight into the conversion of polydisperse nanoparticles into monodisperse Au25 nanoclusters. Inorg Chem 50:10735–10739CrossRef
32.
Zurück zum Zitat Das A, Li T, Nobusada K, Zeng Q, Rosi NL, Jin R (2012) Total structure and optical properties of a phosphine/thiolate-protected Au24 nanocluster. J Am Chem Soc 134:20286–20289CrossRef Das A, Li T, Nobusada K, Zeng Q, Rosi NL, Jin R (2012) Total structure and optical properties of a phosphine/thiolate-protected Au24 nanocluster. J Am Chem Soc 134:20286–20289CrossRef
33.
Zurück zum Zitat Yang H, Wang Y, Lei J, Shi L, Wu X, Mäkinen V, Lin S, Tang Z, He J, Häkkinen H, Zheng L, Zheng N (2013) Ligand-stabilized Au13Cux (x = 2, 4, 8) bimetallic nanoclusters: ligand engineering to control the exposure of metal sites. J Am Chem Soc 135:9568–9571CrossRef Yang H, Wang Y, Lei J, Shi L, Wu X, Mäkinen V, Lin S, Tang Z, He J, Häkkinen H, Zheng L, Zheng N (2013) Ligand-stabilized Au13Cux (x = 2, 4, 8) bimetallic nanoclusters: ligand engineering to control the exposure of metal sites. J Am Chem Soc 135:9568–9571CrossRef
34.
Zurück zum Zitat Brust M, Walker M, Bethell D, Schiffrin DJ, Whyman R (1994) Synthesis of thiol-derivatized gold nanoparticles in a two-phase liquid-liquid system. J Chem Soc Chem Commun 7:801–802CrossRef Brust M, Walker M, Bethell D, Schiffrin DJ, Whyman R (1994) Synthesis of thiol-derivatized gold nanoparticles in a two-phase liquid-liquid system. J Chem Soc Chem Commun 7:801–802CrossRef
35.
Zurück zum Zitat Whetten RL, Khoury JT, Alvarez MM, Murthy S, Vezmar I, Wang ZL, Stephens PW, Cleveland CL, Luedtke WD, Landman U (1996) Nanocrystal Gold Molecules. Adv Mater 8:428–433CrossRef Whetten RL, Khoury JT, Alvarez MM, Murthy S, Vezmar I, Wang ZL, Stephens PW, Cleveland CL, Luedtke WD, Landman U (1996) Nanocrystal Gold Molecules. Adv Mater 8:428–433CrossRef
36.
Zurück zum Zitat Alvarez MM, Khoury JT, Schaaff TG, Shafigullin MN, Vezmar I, Whetten RL (1997) Optical absorption spectra of nanocrystal gold molecules. J Phys Chem B 101:3706–3712CrossRef Alvarez MM, Khoury JT, Schaaff TG, Shafigullin MN, Vezmar I, Whetten RL (1997) Optical absorption spectra of nanocrystal gold molecules. J Phys Chem B 101:3706–3712CrossRef
37.
Zurück zum Zitat Jin R, Qian H, Wu Z, Zhu Y, Zhu M, Mohanty A, Garg N (2010) Size focusing: a methodology for synthesizing atomically precise gold nanoclusters. J Phys Chem Lett 1:2903–2910CrossRef Jin R, Qian H, Wu Z, Zhu Y, Zhu M, Mohanty A, Garg N (2010) Size focusing: a methodology for synthesizing atomically precise gold nanoclusters. J Phys Chem Lett 1:2903–2910CrossRef
38.
Zurück zum Zitat Zhu M, Lanni E, Garg N, Bier ME, Jin R (2008) Kinetically controlled, high-yield synthesis of Au25 clusters. J Am Chem Soc 130:1138–1139CrossRef Zhu M, Lanni E, Garg N, Bier ME, Jin R (2008) Kinetically controlled, high-yield synthesis of Au25 clusters. J Am Chem Soc 130:1138–1139CrossRef
39.
Zurück zum Zitat Qian H, Zhu Y, Jin R (2009) Size-focusing synthesis, optical and electrochemical properties of monodisperse Au38(SC2H4Ph)24 nanoclusters. ACS Nano 3:3795–3803CrossRef Qian H, Zhu Y, Jin R (2009) Size-focusing synthesis, optical and electrochemical properties of monodisperse Au38(SC2H4Ph)24 nanoclusters. ACS Nano 3:3795–3803CrossRef
40.
Zurück zum Zitat Qian H, Jin R (2009) Controlling nanoparticles with atomic precision: the case of Au144(SCH2CH2Ph)60. Nano Lett 9:4083–4087CrossRef Qian H, Jin R (2009) Controlling nanoparticles with atomic precision: the case of Au144(SCH2CH2Ph)60. Nano Lett 9:4083–4087CrossRef
41.
Zurück zum Zitat Qian H, Zhu Y, Jin R (2012) Atomically precise gold nanocrystal molecules with surface plasmon resonance. Proc Natl Acad Sci U S A 109:696–700CrossRef Qian H, Zhu Y, Jin R (2012) Atomically precise gold nanocrystal molecules with surface plasmon resonance. Proc Natl Acad Sci U S A 109:696–700CrossRef
42.
Zurück zum Zitat Shichibu Y, Negishi Y, Tsukuda T, Teranishi T (2005) Large-scale synthesis of thiolated Au25 clusters via ligand exchange reactions of phosphine-stabilized Au11 clusters. J Am Chem Soc 127:13464–13465CrossRef Shichibu Y, Negishi Y, Tsukuda T, Teranishi T (2005) Large-scale synthesis of thiolated Au25 clusters via ligand exchange reactions of phosphine-stabilized Au11 clusters. J Am Chem Soc 127:13464–13465CrossRef
43.
Zurück zum Zitat Nimmala PR, Dass A (2011) Au36(SPh)23 nanomolecules. J Am Chem Soc 133:9175–9177CrossRef Nimmala PR, Dass A (2011) Au36(SPh)23 nanomolecules. J Am Chem Soc 133:9175–9177CrossRef
44.
Zurück zum Zitat Cleveland CL, Landman U, Schaaff TG, Shafigullin MN, Stephens PW, Whetten RL (1997) Structural evolution of smaller gold nanocrystals: the truncated decahedral motif. Phys Rev Lett 79:1873–1876CrossRef Cleveland CL, Landman U, Schaaff TG, Shafigullin MN, Stephens PW, Whetten RL (1997) Structural evolution of smaller gold nanocrystals: the truncated decahedral motif. Phys Rev Lett 79:1873–1876CrossRef
45.
Zurück zum Zitat Schaaff TG, Shafigullin MN, Khoury JT, Vezmar I, Whetten RL, Cullen WG, First PN, Gutierrez-Wing C, Ascensio J, Jose-Yacaman MJ (1997) Isolation of smaller nanocrystal au molecules: robust quantum effects in optical spectra. J Phys Chem B 101:7885–7891CrossRef Schaaff TG, Shafigullin MN, Khoury JT, Vezmar I, Whetten RL, Cullen WG, First PN, Gutierrez-Wing C, Ascensio J, Jose-Yacaman MJ (1997) Isolation of smaller nanocrystal au molecules: robust quantum effects in optical spectra. J Phys Chem B 101:7885–7891CrossRef
46.
Zurück zum Zitat Schaaff TG, Knight G, Shafigullin MN, Borkman RF, Whetten RL (1998) Isolation and selected properties of a 10.4 kDa gold: glutathione cluster compound. J Phys Chem B 102:10643–10646CrossRef Schaaff TG, Knight G, Shafigullin MN, Borkman RF, Whetten RL (1998) Isolation and selected properties of a 10.4 kDa gold: glutathione cluster compound. J Phys Chem B 102:10643–10646CrossRef
47.
Zurück zum Zitat Schaaff TG, Shafigullin MN, Khoury JT, Vezmar I, Whetten RL (2001) Properties of a ubiquitous 29 kDa Au: SR cluster compound. J Phys Chem B 105:8785–8796CrossRef Schaaff TG, Shafigullin MN, Khoury JT, Vezmar I, Whetten RL (2001) Properties of a ubiquitous 29 kDa Au: SR cluster compound. J Phys Chem B 105:8785–8796CrossRef
48.
Zurück zum Zitat Chaki NK, Negishi Y, Tsunoyama H, Shichibu Y, Tsukuda T (2008) Ubiquitous 8 and 29 kDa Gold:Alkanethiolate cluster compounds: mass-spectrometric determination of molecular formulas and structural implications. J Am Chem Soc 130:8608–8610CrossRef Chaki NK, Negishi Y, Tsunoyama H, Shichibu Y, Tsukuda T (2008) Ubiquitous 8 and 29 kDa Gold:Alkanethiolate cluster compounds: mass-spectrometric determination of molecular formulas and structural implications. J Am Chem Soc 130:8608–8610CrossRef
49.
Zurück zum Zitat Tsunoyama H, Negishi Y, Tsukuda T (2006) Chromatographic isolation of “Missing” Au55 clusters protected by alkanethiolates. J Am Chem Soc 128:6036–6037CrossRef Tsunoyama H, Negishi Y, Tsukuda T (2006) Chromatographic isolation of “Missing” Au55 clusters protected by alkanethiolates. J Am Chem Soc 128:6036–6037CrossRef
50.
Zurück zum Zitat Qian H, Zhu Y, Jin R (2010) Isolation of ubiquitous Au40(SR)24 clusters from the 8 kDa gold clusters. J Am Chem Soc 132:4583–4585CrossRef Qian H, Zhu Y, Jin R (2010) Isolation of ubiquitous Au40(SR)24 clusters from the 8 kDa gold clusters. J Am Chem Soc 132:4583–4585CrossRef
51.
Zurück zum Zitat Knoppe S, Boudon J, Dolamic I, Dass A, Burgi T (2011) Size exclusion chromatography for semipreparative scale separation of Au38(SR)24 and Au40(SR)24 and larger clusters. Anal Chem 83:5056–5061CrossRef Knoppe S, Boudon J, Dolamic I, Dass A, Burgi T (2011) Size exclusion chromatography for semipreparative scale separation of Au38(SR)24 and Au40(SR)24 and larger clusters. Anal Chem 83:5056–5061CrossRef
52.
Zurück zum Zitat Qian H, Jin R (2011) Synthesis and electrospray mass spectrometry determination of thiolate-protected Au55(SR)31 nanoclusters. Chem Comm 47:11462–11464CrossRef Qian H, Jin R (2011) Synthesis and electrospray mass spectrometry determination of thiolate-protected Au55(SR)31 nanoclusters. Chem Comm 47:11462–11464CrossRef
53.
Zurück zum Zitat Negishi Y, Sakamoto C, Ohyama T, Tsukuda T (2012) Synthesis and the origin of the stability of thiolate-protected Au130 and Au187 clusters. J Phys Chem Lett 3:1624–1628CrossRef Negishi Y, Sakamoto C, Ohyama T, Tsukuda T (2012) Synthesis and the origin of the stability of thiolate-protected Au130 and Au187 clusters. J Phys Chem Lett 3:1624–1628CrossRef
54.
Zurück zum Zitat Nimmala PR, Yoon B, Whetten RL, Landman U, Dass A (2013) Au67(SR)35 nanomolecules: characteristic size-specific optical, electrochemical, structural properties and first-principles theoretical analysis. J Phys Chem A 117:504–517CrossRef Nimmala PR, Yoon B, Whetten RL, Landman U, Dass A (2013) Au67(SR)35 nanomolecules: characteristic size-specific optical, electrochemical, structural properties and first-principles theoretical analysis. J Phys Chem A 117:504–517CrossRef
55.
Zurück zum Zitat Schaaff TG, Whetten RL (1999) Controlled etching of Au:SR cluster compounds. J Phys Chem B 103:9394–9396CrossRef Schaaff TG, Whetten RL (1999) Controlled etching of Au:SR cluster compounds. J Phys Chem B 103:9394–9396CrossRef
56.
Zurück zum Zitat Sakai N, Tatsuma T (2010) Photovoltaic properties of glutathione-protected gold clusters adsorbed on TiO2 electrodes. Adv Mater 22:3185–3188CrossRef Sakai N, Tatsuma T (2010) Photovoltaic properties of glutathione-protected gold clusters adsorbed on TiO2 electrodes. Adv Mater 22:3185–3188CrossRef
57.
Zurück zum Zitat Sexton JZ, Ackerson CJ (2010) Determination of rigidity of protein bound Au144 clusters by electron cryomicroscopy. J Phys Chem C 114:16037–16042CrossRef Sexton JZ, Ackerson CJ (2010) Determination of rigidity of protein bound Au144 clusters by electron cryomicroscopy. J Phys Chem C 114:16037–16042CrossRef
58.
Zurück zum Zitat Wu Z, Wang M, Yang J, Zheng X, Cai W, Meng G, Qian H, Wang H, Jin R (2012) Well-defined nanoclusters as fluorescent nanosensors: a case study on Au25(SG)18. Small 8:2028–2035CrossRef Wu Z, Wang M, Yang J, Zheng X, Cai W, Meng G, Qian H, Wang H, Jin R (2012) Well-defined nanoclusters as fluorescent nanosensors: a case study on Au25(SG)18. Small 8:2028–2035CrossRef
59.
Zurück zum Zitat Li G, Jin R (2013) Atomically precise gold nanoclusters as new model catalysts. Acc Chem Res 46:1749–1758CrossRef Li G, Jin R (2013) Atomically precise gold nanoclusters as new model catalysts. Acc Chem Res 46:1749–1758CrossRef
60.
Zurück zum Zitat Wu Z, MacDonald M, Chen J, Zhang P, Jin R (2011) Kinetic control and thermodynamic selection in the synthesis of atomically precise gold nanoclusters. J Am Chem Soc 133:9670–9673CrossRef Wu Z, MacDonald M, Chen J, Zhang P, Jin R (2011) Kinetic control and thermodynamic selection in the synthesis of atomically precise gold nanoclusters. J Am Chem Soc 133:9670–9673CrossRef
61.
Zurück zum Zitat Akola J, Walter M, Whetten RL, Häkkinen H, Grönbeck H (2008) On the structure of thiolate-protected Au25. J Am Chem Soc 130:3756–3757CrossRef Akola J, Walter M, Whetten RL, Häkkinen H, Grönbeck H (2008) On the structure of thiolate-protected Au25. J Am Chem Soc 130:3756–3757CrossRef
62.
Zurück zum Zitat Wu Z, Suhan J, Jin R (2009) One-pot synthesis of atomically monodisperse, thiol-functionalized Au25 nanoclusters. J Mater Chem 19:622–626CrossRef Wu Z, Suhan J, Jin R (2009) One-pot synthesis of atomically monodisperse, thiol-functionalized Au25 nanoclusters. J Mater Chem 19:622–626CrossRef
63.
Zurück zum Zitat Liu C, Li G, Pang G, Jin R (2013) Toward understanding the growth mechanism of Au n (SR) m nanoclusters: effect of solvent on cluster size. RSC Adv 3:9778–9784CrossRef Liu C, Li G, Pang G, Jin R (2013) Toward understanding the growth mechanism of Au n (SR) m nanoclusters: effect of solvent on cluster size. RSC Adv 3:9778–9784CrossRef
64.
Zurück zum Zitat Dharmaratne AC, Krick T, Dass A (2009) Nanocluster size evolution studied by mass spectrometry in room temperature Au25(SR)18 synthesis. J Am Chem Soc 131:13604–13605CrossRef Dharmaratne AC, Krick T, Dass A (2009) Nanocluster size evolution studied by mass spectrometry in room temperature Au25(SR)18 synthesis. J Am Chem Soc 131:13604–13605CrossRef
65.
Zurück zum Zitat Qian H, Liu C, Jin R (2012) Controlled growth of molecularly pure Au25(SR)18 and Au38(SR)24 nanoclusters from the same polydispersed crude product. Sci China Chem 55:2359–2365CrossRef Qian H, Liu C, Jin R (2012) Controlled growth of molecularly pure Au25(SR)18 and Au38(SR)24 nanoclusters from the same polydispersed crude product. Sci China Chem 55:2359–2365CrossRef
66.
Zurück zum Zitat Stellwagen D, Weber A, Bovenkamp GL, Jin R, Bitter JH, Kumar CSSR (2012) Ligand control in thiol stabilized Au38 clusters. RSC Adv 2:2276–2283CrossRef Stellwagen D, Weber A, Bovenkamp GL, Jin R, Bitter JH, Kumar CSSR (2012) Ligand control in thiol stabilized Au38 clusters. RSC Adv 2:2276–2283CrossRef
67.
Zurück zum Zitat Qian H, Jin R (2011) Ambient synthesis of Au144(SR)60 nanoclusters in methanol. Chem Mater 23:2209–2217CrossRef Qian H, Jin R (2011) Ambient synthesis of Au144(SR)60 nanoclusters in methanol. Chem Mater 23:2209–2217CrossRef
68.
Zurück zum Zitat Zhu M, Qian H, Jin R (2009) Thiolate-protected Au20 clusters with a large energy gap of 2.1 eV. J Am Chem Soc 131:7220–7221CrossRef Zhu M, Qian H, Jin R (2009) Thiolate-protected Au20 clusters with a large energy gap of 2.1 eV. J Am Chem Soc 131:7220–7221CrossRef
69.
Zurück zum Zitat Zhu M, Qian H, Jin R (2010) Thiolate-protected Au24(SC2H4Ph)20 nanoclusters: superatoms or not? J Phys Chem Lett 1:1003–1007CrossRef Zhu M, Qian H, Jin R (2010) Thiolate-protected Au24(SC2H4Ph)20 nanoclusters: superatoms or not? J Phys Chem Lett 1:1003–1007CrossRef
70.
Zurück zum Zitat Levi-Kalisman Y, Jadzinsky PD, Kalisman N, Tsunoyama H, Tsukuda T, Bushnell DA, Kornberg RD (2011) Synthesis and characterization of Au102(p-MBA)44 nanoparticles. J Am Chem Soc 133:2976–2983CrossRef Levi-Kalisman Y, Jadzinsky PD, Kalisman N, Tsunoyama H, Tsukuda T, Bushnell DA, Kornberg RD (2011) Synthesis and characterization of Au102(p-MBA)44 nanoparticles. J Am Chem Soc 133:2976–2983CrossRef
71.
Zurück zum Zitat Xu Q, Wang S, Liu Z, Xu G, Meng X, Zhu M (2013) Synthesis of selenolate-protected Au18(SeC6H5)14 nanoclusters. Nanoscale 5:1176–1182CrossRef Xu Q, Wang S, Liu Z, Xu G, Meng X, Zhu M (2013) Synthesis of selenolate-protected Au18(SeC6H5)14 nanoclusters. Nanoscale 5:1176–1182CrossRef
72.
Zurück zum Zitat Yu Y, Chen X, Yao Q, Yu Y, Yan N, Xie J (2013) Scalable and precise synthesis of thiolated Au10–12, Au15, Au18, and Au25 nanoclusters via pH controlled CO reduction. Chem Mater 25:946–952CrossRef Yu Y, Chen X, Yao Q, Yu Y, Yan N, Xie J (2013) Scalable and precise synthesis of thiolated Au10–12, Au15, Au18, and Au25 nanoclusters via pH controlled CO reduction. Chem Mater 25:946–952CrossRef
73.
Zurück zum Zitat Ghosh A, Udayabhaskararao T, Pradeep T (1997–2002) One-step route to luminescent Au18SG14 in the condensed phase and its closed shell molecular ions in the gas phase. J Phys Chem Lett 2012:3 Ghosh A, Udayabhaskararao T, Pradeep T (1997–2002) One-step route to luminescent Au18SG14 in the condensed phase and its closed shell molecular ions in the gas phase. J Phys Chem Lett 2012:3
74.
Zurück zum Zitat Zeng C, Liu C, Pei Y, Jin R (2013) Thiol ligand-induced transformation of Au38(SC2H4Ph)24 to Au36(SPh-t-Bu)24. ACS Nano 7:6138–6145CrossRef Zeng C, Liu C, Pei Y, Jin R (2013) Thiol ligand-induced transformation of Au38(SC2H4Ph)24 to Au36(SPh-t-Bu)24. ACS Nano 7:6138–6145CrossRef
75.
76.
Zurück zum Zitat Jiang D, Tiago ML, Luo W, Dai S (2008) The “Staple” Motif: a key to stability of thiolate-protected gold nanoclusters. J Am Chem Soc 130:2777–2779CrossRef Jiang D, Tiago ML, Luo W, Dai S (2008) The “Staple” Motif: a key to stability of thiolate-protected gold nanoclusters. J Am Chem Soc 130:2777–2779CrossRef
77.
Zurück zum Zitat Pei Y, Gao Y, Zeng XC (2008) Structural prediction of thiolate-protected Au38: a face-fused bi-icosahedral Au core. J Am Chem Soc 130:7830–7832CrossRef Pei Y, Gao Y, Zeng XC (2008) Structural prediction of thiolate-protected Au38: a face-fused bi-icosahedral Au core. J Am Chem Soc 130:7830–7832CrossRef
78.
Zurück zum Zitat Lopez-Acevedo O, Tsunoyama H, Tsukuda T, Häkkinen H, Aikens CM (2010) Chirality and electronic structure of the thiolate-protected Au38 nanocluster. J Am Chem Soc 132:8210–8218CrossRef Lopez-Acevedo O, Tsunoyama H, Tsukuda T, Häkkinen H, Aikens CM (2010) Chirality and electronic structure of the thiolate-protected Au38 nanocluster. J Am Chem Soc 132:8210–8218CrossRef
79.
Zurück zum Zitat Jiang D-E, Overbury SH, Dai S (2013) Structure of Au15(SR)13 and its implication for the origin of the nucleus in thiolated gold nanoclusters. J Am Chem Soc 135:8786–8789CrossRef Jiang D-E, Overbury SH, Dai S (2013) Structure of Au15(SR)13 and its implication for the origin of the nucleus in thiolated gold nanoclusters. J Am Chem Soc 135:8786–8789CrossRef
80.
Zurück zum Zitat Pei Y, Gao Y, Shao N, Zeng XC (2009) Thiolate-protected Au20(SR)16 cluster: prolate Au8 core with new [Au3(SR)4] staple Motif. J Am Chem Soc 131:13619–13621CrossRef Pei Y, Gao Y, Shao N, Zeng XC (2009) Thiolate-protected Au20(SR)16 cluster: prolate Au8 core with new [Au3(SR)4] staple Motif. J Am Chem Soc 131:13619–13621CrossRef
81.
Zurück zum Zitat Iwasa T, Nobusada K (2007) Theoretical investigation of optimized structures of thiolated gold cluster [Au25(SCH3)18]+. J Phys Chem C 111:45–49CrossRef Iwasa T, Nobusada K (2007) Theoretical investigation of optimized structures of thiolated gold cluster [Au25(SCH3)18]+. J Phys Chem C 111:45–49CrossRef
82.
Zurück zum Zitat Jin R, Zhu Y, Qian H (2011) Quantum-sized gold nanoclusters: bridging the gap between organometallics and nanocrystals. Chem Eur J 17:6584–6593CrossRef Jin R, Zhu Y, Qian H (2011) Quantum-sized gold nanoclusters: bridging the gap between organometallics and nanocrystals. Chem Eur J 17:6584–6593CrossRef
83.
Zurück zum Zitat Venzo A, Antonello S, Gascón JA, Guryanov I, Leapman RD, Perera NV, Sousa A, Zamuner M, Zanella A, Maran F (2011) Effect of the charge state (z = −1, 0, +1) on the nuclear magnetic resonance of monodisperse Au25[S(CH2)2Ph]18 z clusters. Anal Chem 83:6355–6362CrossRef Venzo A, Antonello S, Gascón JA, Guryanov I, Leapman RD, Perera NV, Sousa A, Zamuner M, Zanella A, Maran F (2011) Effect of the charge state (z = −1, 0, +1) on the nuclear magnetic resonance of monodisperse Au25[S(CH2)2Ph]18 z clusters. Anal Chem 83:6355–6362CrossRef
84.
Zurück zum Zitat Liu Z, Zhu M, Meng X, Xu G, Jin R (2011) Electron transfer between [Au25(SC2H4Ph)18]−TOA+ and oxoammonium cations. J Phys Chem Lett 2:2104–2109CrossRef Liu Z, Zhu M, Meng X, Xu G, Jin R (2011) Electron transfer between [Au25(SC2H4Ph)18]TOA+ and oxoammonium cations. J Phys Chem Lett 2:2104–2109CrossRef
85.
Zurück zum Zitat Negishi Y, Chaki NK, Shichibu Y, Whetten RL, Tsukuda T (2007) Origin of magic stability of thiolated gold clusters: a case study on Au25(SC6H13)18. J Am Chem Soc 129:11322–11323CrossRef Negishi Y, Chaki NK, Shichibu Y, Whetten RL, Tsukuda T (2007) Origin of magic stability of thiolated gold clusters: a case study on Au25(SC6H13)18. J Am Chem Soc 129:11322–11323CrossRef
86.
Zurück zum Zitat Parker JF, Choi J-P, Wang W, Murray RW (2008) Electron self-exchange dynamics of the nanoparticle couple [Au25(SC2Ph)18]0/1− by nuclear magnetic resonance line-broadening. J Phys Chem C 112:13976–13981CrossRef Parker JF, Choi J-P, Wang W, Murray RW (2008) Electron self-exchange dynamics of the nanoparticle couple [Au25(SC2Ph)18]0/1− by nuclear magnetic resonance line-broadening. J Phys Chem C 112:13976–13981CrossRef
87.
Zurück zum Zitat Kwak K, Lee D (2012) Electrochemical characterization of water-soluble Au25 nanoclusters enabled by phase-transfer reaction. J Phys Chem Lett 3:2476–2481CrossRef Kwak K, Lee D (2012) Electrochemical characterization of water-soluble Au25 nanoclusters enabled by phase-transfer reaction. J Phys Chem Lett 3:2476–2481CrossRef
88.
Zurück zum Zitat Swanick KN, Hesari M, Workentin MS, Ding Z (2012) Interrogating near-infrared electrogenerated chemiluminescence of Au25(SC2H4Ph)18 + clusters. J Am Chem Soc 134:15205–15208CrossRef Swanick KN, Hesari M, Workentin MS, Ding Z (2012) Interrogating near-infrared electrogenerated chemiluminescence of Au25(SC2H4Ph)18 + clusters. J Am Chem Soc 134:15205–15208CrossRef
89.
Zurück zum Zitat Zhu M, Aikens CM, Hendrich MP, Gupta R, Qian H, Schatz GC, Jin R (2009) Reversible switching of magnetism in thiolate-protected Au25 superatoms. J Am Chem Soc 131:2490–2492CrossRef Zhu M, Aikens CM, Hendrich MP, Gupta R, Qian H, Schatz GC, Jin R (2009) Reversible switching of magnetism in thiolate-protected Au25 superatoms. J Am Chem Soc 131:2490–2492CrossRef
90.
Zurück zum Zitat Marks L (1983) Modified Wulff constructions for twinned particles. J Cryst Growth 61:556–566CrossRef Marks L (1983) Modified Wulff constructions for twinned particles. J Cryst Growth 61:556–566CrossRef
91.
Zurück zum Zitat Marks L (1984) Surface structure and energetics of multiply twinned particles. Philos Mag A 49:81–93CrossRef Marks L (1984) Surface structure and energetics of multiply twinned particles. Philos Mag A 49:81–93CrossRef
92.
Zurück zum Zitat Mednikov EG, Dahl LF (2008) Crystallographically proven nanometer-sized gold thiolate cluster Au102(SR)44: its unexpected molecular anatomy and resulting stereochemical and bonding consequences. Small 4:534–537CrossRef Mednikov EG, Dahl LF (2008) Crystallographically proven nanometer-sized gold thiolate cluster Au102(SR)44: its unexpected molecular anatomy and resulting stereochemical and bonding consequences. Small 4:534–537CrossRef
Metadaten
Titel
Gold Nanoclusters: Size-Controlled Synthesis and Crystal Structures
verfasst von
Chenjie Zeng
Rongchao Jin
Copyright-Jahr
2014
DOI
https://doi.org/10.1007/430_2014_146

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