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Erschienen in: Journal of Materials Science 18/2014

01.09.2014

Graphene sheets decorated with ZnO nanoparticles as anode materials for lithium ion batteries

verfasst von: Ling-Li Xu, Shao-Wei Bian, Kang-Lin Song

Erschienen in: Journal of Materials Science | Ausgabe 18/2014

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Abstract

ZnO/graphene composites were synthesized using a facile solution-based method. Scanning electron microscopy, transmission electron microscopy, X-ray diffraction, thermogravimetric analysis, and Raman spectra revealed that ZnO nanoparticles with a particle size of around 4 nm were densely and homogeneously deposited on graphene sheets. As the anode material for the lithium ion batteries, the ZnO/graphene composites delivered a stable capacity of 404 mAh/g after 100 cycles at a current rate of 0.5 C, which is much superior to bare ZnO nanoparticles. The battery performance result indicates the presence of graphene sheets in the composites effectively enhance the conductivity and accommodate the volume change.

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Literatur
1.
Zurück zum Zitat Liu R, Duay J, Lee SB (2011) Heterogeneous nanostructured electrode materials for electrochemical energy storage. Chem Commun 47:1384–1404CrossRef Liu R, Duay J, Lee SB (2011) Heterogeneous nanostructured electrode materials for electrochemical energy storage. Chem Commun 47:1384–1404CrossRef
2.
Zurück zum Zitat Bian S-W, Zhu L (2013) Template-free synthesis of mesoporous Co3O4 with controlled morphologies for lithium ion batteries. RSC Adv 3:4212–4215CrossRef Bian S-W, Zhu L (2013) Template-free synthesis of mesoporous Co3O4 with controlled morphologies for lithium ion batteries. RSC Adv 3:4212–4215CrossRef
3.
Zurück zum Zitat Bian S-W, Zhao Y-P, Xian C-Y (2013) Porous MnO2 hollow spheres constructed by nanosheets and their application in electrochemical capacitors. Mater Lett 111:75–77CrossRef Bian S-W, Zhao Y-P, Xian C-Y (2013) Porous MnO2 hollow spheres constructed by nanosheets and their application in electrochemical capacitors. Mater Lett 111:75–77CrossRef
4.
Zurück zum Zitat Kamat PV (2011) Graphene-based nanoassemblies for energy conversion. J Phys Chem Lett 2:242–251CrossRef Kamat PV (2011) Graphene-based nanoassemblies for energy conversion. J Phys Chem Lett 2:242–251CrossRef
5.
Zurück zum Zitat Wang J, Gao Z, Li Z, Wang B, Yan Y, Liu Q, Mann T, Zhang M, Jiang Z (2011) Green synthesis of graphene nanosheets/ZnO composites and electrochemical properties. J Solid State Chem 184:1421–1427CrossRef Wang J, Gao Z, Li Z, Wang B, Yan Y, Liu Q, Mann T, Zhang M, Jiang Z (2011) Green synthesis of graphene nanosheets/ZnO composites and electrochemical properties. J Solid State Chem 184:1421–1427CrossRef
6.
Zurück zum Zitat Liu J, Zhou Y, Liu F, Liu C, Wang J, Pan Y, Xue D (2012) One-pot synthesis of mesoporous interconnected carbon-encapsulated Fe3O4 nanospheres as superior anodes for Li-ion batteries. RSC Adv 2:2262–2265CrossRef Liu J, Zhou Y, Liu F, Liu C, Wang J, Pan Y, Xue D (2012) One-pot synthesis of mesoporous interconnected carbon-encapsulated Fe3O4 nanospheres as superior anodes for Li-ion batteries. RSC Adv 2:2262–2265CrossRef
7.
Zurück zum Zitat Zhang W-M, Wu X-L, Hu J-S, Guo Y-G, Wan L-J (2008) Carbon coated Fe3O4 nanospindles as a superior anode material for lithium-ion batteries. Adv Funct Mater 18:3941–3946CrossRef Zhang W-M, Wu X-L, Hu J-S, Guo Y-G, Wan L-J (2008) Carbon coated Fe3O4 nanospindles as a superior anode material for lithium-ion batteries. Adv Funct Mater 18:3941–3946CrossRef
8.
Zurück zum Zitat Li B, Cao H, Shao J, Li G, Qu M, Yin G (2011) Co3O4@graphene composites as anode materials for high-performance lithium ion batteries. Inorg Chem 50:1628–1632CrossRef Li B, Cao H, Shao J, Li G, Qu M, Yin G (2011) Co3O4@graphene composites as anode materials for high-performance lithium ion batteries. Inorg Chem 50:1628–1632CrossRef
9.
Zurück zum Zitat Yang M, Gao Q (2011) Copper oxide and ordered mesoporous carbon composite with high performance using as anode material for lithium-ion battery. Microporous Mesoporous Mater 143:230–235CrossRef Yang M, Gao Q (2011) Copper oxide and ordered mesoporous carbon composite with high performance using as anode material for lithium-ion battery. Microporous Mesoporous Mater 143:230–235CrossRef
10.
Zurück zum Zitat Ning J, Dai Q, Jiang T, Men K, Liu D, Xiao N, Li C, Li D, Liu B, Zou B, Zou G, Yu WW (2008) Facile synthesis of tin oxide nanoflowers: a potential high-capacity lithium-ion-storage material. Langmuir 25:1818–1821CrossRef Ning J, Dai Q, Jiang T, Men K, Liu D, Xiao N, Li C, Li D, Liu B, Zou B, Zou G, Yu WW (2008) Facile synthesis of tin oxide nanoflowers: a potential high-capacity lithium-ion-storage material. Langmuir 25:1818–1821CrossRef
11.
Zurück zum Zitat Wang CD, Zhang QM, Wu QH, Ng TW, Wong TL, Ren JG, Shi ZC, Lee CS, Lee ST, Zhang WJ (2012) Facile synthesis of laminate-structured graphene sheet-Fe3O4 nanocomposites with superior high reversible specific capacity and cyclic stability for lithium-ion batteries. RSC Adv 2:10680–10688CrossRef Wang CD, Zhang QM, Wu QH, Ng TW, Wong TL, Ren JG, Shi ZC, Lee CS, Lee ST, Zhang WJ (2012) Facile synthesis of laminate-structured graphene sheet-Fe3O4 nanocomposites with superior high reversible specific capacity and cyclic stability for lithium-ion batteries. RSC Adv 2:10680–10688CrossRef
12.
Zurück zum Zitat Su J, Cao M, Ren L, Hu C (2011) Fe3O4–graphene nanocomposites with improved lithium storage and magnetism properties. J Phys Chem C 115:14469–14477CrossRef Su J, Cao M, Ren L, Hu C (2011) Fe3O4–graphene nanocomposites with improved lithium storage and magnetism properties. J Phys Chem C 115:14469–14477CrossRef
13.
Zurück zum Zitat Zhu X, Zhu Y, Murali S, Stoller MD, Ruoff RS (2011) Nanostructured reduced graphene oxide/Fe2O3 composite as a high-performance anode material for lithium ion batteries. ACS Nano 5:3333–3338CrossRef Zhu X, Zhu Y, Murali S, Stoller MD, Ruoff RS (2011) Nanostructured reduced graphene oxide/Fe2O3 composite as a high-performance anode material for lithium ion batteries. ACS Nano 5:3333–3338CrossRef
14.
Zurück zum Zitat Barreca D, Cruz-Yusta M, Gasparotto A, Maccato C, Morales J, Pozza A, Sada C, Sánchez L, Tondello E (2010) Cobalt oxide nanomaterials by vapor-phase synthesis for fast and reversible lithium storage. J Phys Chem C 114:10054–10060CrossRef Barreca D, Cruz-Yusta M, Gasparotto A, Maccato C, Morales J, Pozza A, Sada C, Sánchez L, Tondello E (2010) Cobalt oxide nanomaterials by vapor-phase synthesis for fast and reversible lithium storage. J Phys Chem C 114:10054–10060CrossRef
15.
Zurück zum Zitat Yu A, Park HW, Davies A, Higgins DC, Chen Z, Xiao X (2011) Free-standing layer-by-layer hybrid thin film of graphene-MnO2 nanotube as anode for lithium ion batteries. J Phys Chem Lett 2:1855–1860CrossRef Yu A, Park HW, Davies A, Higgins DC, Chen Z, Xiao X (2011) Free-standing layer-by-layer hybrid thin film of graphene-MnO2 nanotube as anode for lithium ion batteries. J Phys Chem Lett 2:1855–1860CrossRef
16.
Zurück zum Zitat Zhang D, Wen M, Zhang P, Zhu J, Li G, Li H (2012) Microwave-induced synthesis of porous single-crystal-like TiO2 with excellent lithium storage properties. Langmuir 28:4543–4547CrossRef Zhang D, Wen M, Zhang P, Zhu J, Li G, Li H (2012) Microwave-induced synthesis of porous single-crystal-like TiO2 with excellent lithium storage properties. Langmuir 28:4543–4547CrossRef
17.
Zurück zum Zitat Bian SW, Mudunkotuwa IA, Rupasinghe T, Grassian VH (2011) Aggregation and dissolution of 4 nm ZnO nanoparticles in a queous environments: influence of pH, ionic strength, size, and adsorption of humic acid. Langmuir 27:6059–6068CrossRef Bian SW, Mudunkotuwa IA, Rupasinghe T, Grassian VH (2011) Aggregation and dissolution of 4 nm ZnO nanoparticles in a queous environments: influence of pH, ionic strength, size, and adsorption of humic acid. Langmuir 27:6059–6068CrossRef
18.
Zurück zum Zitat Chen W, Li S, Chen C, Yan L (2011) Self-assembly and embedding of nanoparticles by in situ reduced graphene for preparation of a 3D graphene/nanoparticle aerogel. Adv Mater 23:5679–5683CrossRef Chen W, Li S, Chen C, Yan L (2011) Self-assembly and embedding of nanoparticles by in situ reduced graphene for preparation of a 3D graphene/nanoparticle aerogel. Adv Mater 23:5679–5683CrossRef
19.
Zurück zum Zitat Liu J, Li Y, Ding R, Jiang J, Hu Y, Ji X, Chi Q, Zhu Z, Huang X (2009) Carbon/ZnO nanorod array electrode with significantly improved lithium storage capability. J Phys Chem C 113:5336–5339CrossRef Liu J, Li Y, Ding R, Jiang J, Hu Y, Ji X, Chi Q, Zhu Z, Huang X (2009) Carbon/ZnO nanorod array electrode with significantly improved lithium storage capability. J Phys Chem C 113:5336–5339CrossRef
20.
Zurück zum Zitat Su D, Kim H-S, Kim W-S, Wang G (2012) Synthesis of tuneable porous hematites (α-Fe2O3) for gas sensing and lithium storage in lithium ion batteries. Microporous Mesoporous Mater 149:36–45CrossRef Su D, Kim H-S, Kim W-S, Wang G (2012) Synthesis of tuneable porous hematites (α-Fe2O3) for gas sensing and lithium storage in lithium ion batteries. Microporous Mesoporous Mater 149:36–45CrossRef
21.
Zurück zum Zitat Chen JS, Zhu T, Hu QH, Gao J, Su F, Qiao SZ, Lou XW (2010) Shape-controlled synthesis of cobalt-based nanocubes, nanodiscs, and nanoflowers and their comparative lithium-storage properties. ACS Appl Mater Interfaces 2:3628–3635CrossRef Chen JS, Zhu T, Hu QH, Gao J, Su F, Qiao SZ, Lou XW (2010) Shape-controlled synthesis of cobalt-based nanocubes, nanodiscs, and nanoflowers and their comparative lithium-storage properties. ACS Appl Mater Interfaces 2:3628–3635CrossRef
22.
Zurück zum Zitat Huang XH, Xia XH, Yuan YF, Zhou F (2011) Porous ZnO nanosheets grown on copper substrates as anodes for lithium ion batteries. Electrochim Acta 56:4960–4965CrossRef Huang XH, Xia XH, Yuan YF, Zhou F (2011) Porous ZnO nanosheets grown on copper substrates as anodes for lithium ion batteries. Electrochim Acta 56:4960–4965CrossRef
23.
Zurück zum Zitat Lee J-H, Hon M-H, Chung Y-W, Leu I-C (2011) The effect of TiO2 coating on the electrochemical performance of ZnO nanorod as the anode material for lithium-ion battery. Appl Phys A 102:545–550CrossRef Lee J-H, Hon M-H, Chung Y-W, Leu I-C (2011) The effect of TiO2 coating on the electrochemical performance of ZnO nanorod as the anode material for lithium-ion battery. Appl Phys A 102:545–550CrossRef
24.
Zurück zum Zitat Shen X, Mu D, Chen S, Wu B, Wu F (2013) Enhanced electrochemical performance of ZnO-loaded/porous carbon composite as anode materials for lithium ion batteries. ACS Appl Mater Interfaces 5:3118–3125CrossRef Shen X, Mu D, Chen S, Wu B, Wu F (2013) Enhanced electrochemical performance of ZnO-loaded/porous carbon composite as anode materials for lithium ion batteries. ACS Appl Mater Interfaces 5:3118–3125CrossRef
25.
Zurück zum Zitat Chen Y-L, Hu Z-A, Chang Y-Q, Wang H-W, Zhang Z-Y, Yang Y–Y, Wu H-Y (2011) Zinc oxide/reduced graphene oxide composites and electrochemical capacitance enhanced by homogeneous incorporation of reduced graphene oxide sheets in zinc oxide matrix. J Phys Chem C 115:2563–2571CrossRef Chen Y-L, Hu Z-A, Chang Y-Q, Wang H-W, Zhang Z-Y, Yang Y–Y, Wu H-Y (2011) Zinc oxide/reduced graphene oxide composites and electrochemical capacitance enhanced by homogeneous incorporation of reduced graphene oxide sheets in zinc oxide matrix. J Phys Chem C 115:2563–2571CrossRef
26.
Zurück zum Zitat Tang X, Pan Q, Liu J (2010) Enhancing lithium storage capacity of ZnO anodes through Ni3ZnC0.7 incorporation. J Electrochem Soc 157:A55–A59CrossRef Tang X, Pan Q, Liu J (2010) Enhancing lithium storage capacity of ZnO anodes through Ni3ZnC0.7 incorporation. J Electrochem Soc 157:A55–A59CrossRef
27.
Zurück zum Zitat Fu LJ, Yang LC, Shi Y, Wang B, Wu YP (2009) Synthesis of carbon coated nanoporous microcomposite and its rate capability for lithium ion battery. Microporous Mesoporous Mater 117:515–518CrossRef Fu LJ, Yang LC, Shi Y, Wang B, Wu YP (2009) Synthesis of carbon coated nanoporous microcomposite and its rate capability for lithium ion battery. Microporous Mesoporous Mater 117:515–518CrossRef
28.
Zurück zum Zitat Lee KT, Jung YS, Kim T, Kim CH, Kim JH, Kwon JY, Oh SM (2008) Liquid gallium electrode confined in porous carbon matrix as anode for lithium secondary batteries. Electrochem Solid-State Lett 11:A21–A24CrossRef Lee KT, Jung YS, Kim T, Kim CH, Kim JH, Kwon JY, Oh SM (2008) Liquid gallium electrode confined in porous carbon matrix as anode for lithium secondary batteries. Electrochem Solid-State Lett 11:A21–A24CrossRef
29.
Zurück zum Zitat Yang SJ, Nam S, Kim T, Im JH, Jung H, Kang JH, Wi S, Park B, Park CR (2013) Preparation and exceptional lithium anodic performance of porous carbon-coated ZnO quantum dots derived from a metal–organic framework. J Am Chem Soc 135:7394–7397CrossRef Yang SJ, Nam S, Kim T, Im JH, Jung H, Kang JH, Wi S, Park B, Park CR (2013) Preparation and exceptional lithium anodic performance of porous carbon-coated ZnO quantum dots derived from a metal–organic framework. J Am Chem Soc 135:7394–7397CrossRef
30.
Zurück zum Zitat Xu YX, Bai H, Lu GW, Li C, Shi GQ (2008) Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets. J Am Chem Soc 130:5856–5857CrossRef Xu YX, Bai H, Lu GW, Li C, Shi GQ (2008) Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets. J Am Chem Soc 130:5856–5857CrossRef
31.
Zurück zum Zitat Shin HJ, Kim KK, Benayad A, Yoon SM, Park HK, Jung IS, Jin MH, Jeong HK, Kim JM, Choi JY, Lee YH (2009) Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance. Adv Funct Mater 19:1987–1992CrossRef Shin HJ, Kim KK, Benayad A, Yoon SM, Park HK, Jung IS, Jin MH, Jeong HK, Kim JM, Choi JY, Lee YH (2009) Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance. Adv Funct Mater 19:1987–1992CrossRef
32.
Zurück zum Zitat Li B, Cao H (2011) ZnO@graphene composite with enhanced performance for the removal of dye from water. J Mater Chem 21:3346–3349CrossRef Li B, Cao H (2011) ZnO@graphene composite with enhanced performance for the removal of dye from water. J Mater Chem 21:3346–3349CrossRef
33.
Zurück zum Zitat Guo Y, Cao X, Lan X, Zhao C, Xue X, Song Y (2008) Solution-based doping of manganese into colloidal ZnO nanorods. J Phys Chem C 112:8832–8838CrossRef Guo Y, Cao X, Lan X, Zhao C, Xue X, Song Y (2008) Solution-based doping of manganese into colloidal ZnO nanorods. J Phys Chem C 112:8832–8838CrossRef
34.
Zurück zum Zitat Zou W, Zhu J, Sun Y, Wang X (2010) Depositing ZnO nanoparticles onto graphene in a polyol system. Mater Chem Phys 125:617–620CrossRef Zou W, Zhu J, Sun Y, Wang X (2010) Depositing ZnO nanoparticles onto graphene in a polyol system. Mater Chem Phys 125:617–620CrossRef
35.
Zurück zum Zitat Zhou K, Zhu Y, Yang X, Jiang X, Li C (2010) Preparation of graphene-TiO2 composites with enhanced photocatalytic activity. New J Chem 35:353–359CrossRef Zhou K, Zhu Y, Yang X, Jiang X, Li C (2010) Preparation of graphene-TiO2 composites with enhanced photocatalytic activity. New J Chem 35:353–359CrossRef
36.
Zurück zum Zitat Ji L, Tan Z, Kuykendall TR, Aloni S, Xun S, Lin E, Battaglia V, Zhang Y (2011) Fe3O4 nanoparticle-integrated graphene sheets for high-performance half and full lithium ion cells. Phys Chem Chem Phys 13:7170–7177CrossRef Ji L, Tan Z, Kuykendall TR, Aloni S, Xun S, Lin E, Battaglia V, Zhang Y (2011) Fe3O4 nanoparticle-integrated graphene sheets for high-performance half and full lithium ion cells. Phys Chem Chem Phys 13:7170–7177CrossRef
37.
Zurück zum Zitat Yu M, Shao D, Lu F, Sun X, Sun H, Hu T, Wang G, Sawyer S, Qiu H, Lian J (2013) ZnO/graphene nanocomposite fabricated by high energy ball milling with greatly enhanced lithium storage capability. Electrochem Commun 34:312–315CrossRef Yu M, Shao D, Lu F, Sun X, Sun H, Hu T, Wang G, Sawyer S, Qiu H, Lian J (2013) ZnO/graphene nanocomposite fabricated by high energy ball milling with greatly enhanced lithium storage capability. Electrochem Commun 34:312–315CrossRef
38.
Zurück zum Zitat Song WT, Xie J, Liu SY, Zheng YX, Cao GS, Zhu TJ, Zhao XB (2012) Graphene decorated with ZnO nanocrystals with improved electrochemical properties prepared by a facile in situ hydrothermal route. Int J Electrochem Sci 7:2164–2174 Song WT, Xie J, Liu SY, Zheng YX, Cao GS, Zhu TJ, Zhao XB (2012) Graphene decorated with ZnO nanocrystals with improved electrochemical properties prepared by a facile in situ hydrothermal route. Int J Electrochem Sci 7:2164–2174
39.
Zurück zum Zitat Hsieh C-T, Lin C-Y, Chen Y-F, Lin J-S (2013) Synthesis of ZnO@graphene composites as anode materials for lithium ion batteries. Electrochim Acta 111:359–365CrossRef Hsieh C-T, Lin C-Y, Chen Y-F, Lin J-S (2013) Synthesis of ZnO@graphene composites as anode materials for lithium ion batteries. Electrochim Acta 111:359–365CrossRef
40.
Zurück zum Zitat Wang H, Cui L-F, Yang Y, Sanchez Casalongue H, Robinson JT, Liang Y, Cui Y, Dai H (2010) Mn3O4–graphene hybrid as a high-capacity anode material for lithium ion batteries. J Am Chem Soc 132:13978–13980CrossRef Wang H, Cui L-F, Yang Y, Sanchez Casalongue H, Robinson JT, Liang Y, Cui Y, Dai H (2010) Mn3O4–graphene hybrid as a high-capacity anode material for lithium ion batteries. J Am Chem Soc 132:13978–13980CrossRef
Metadaten
Titel
Graphene sheets decorated with ZnO nanoparticles as anode materials for lithium ion batteries
verfasst von
Ling-Li Xu
Shao-Wei Bian
Kang-Lin Song
Publikationsdatum
01.09.2014
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 18/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8346-5

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