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Adsorption

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05.09.2018

Green cylindrical mesoporous adsorbent based on alkali-activated phosphorous slag: synthesis, dye removal, and RSM modeling

verfasst von: Ali Salehi, Ebrahim Najafi Kani

Erschienen in: Adsorption | Ausgabe 7/2018

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Abstract

In this work, activated phosphorous slag based cylindrical adsorbent was synthesized for removal of basic violet (BV) and malachite green oxalate (MGO) dyes from aqueous solution. For this purpose, the adsorbent was prepared using a mixture of silica-fume and phosphorous slag as raw precursor and different concentration of NaOH as alkaline solution under a specified curing condition. Response surface methodology has been applied to determine the optimal adsorbent composition and experimental conditions (pH, initial concentration, adsorbent dosage, and contact time). The obtained results showed that the phosphorous slag combined with 30 wt% of silica-fume and 15 mol/L of NaOH was the optimal synthesized adsorbent with an acceptable strength of 6.25 MPa. The maximum adsorption capacity was measured as 46.58 mg/g for BV and 46.36 mg/g for MGO in the optimum condition. Specific surface area for the produced shaped adsorbent is 56.59 m²/g with average pore diameter of 20 nm which was classified as a mesoporous material. It was found from adsorption/desorption test that the overall adsorption capacity decreased about 11% after seven-cycle that result in a reliable reuse of the shaped adsorbent. The resulted high removal efficiency after several desorption cycles not only could be due to the porosity of the mesoporous adsorbent but also could be due to the presence of Si–O–Si bonds in its molecular-structure that result in higher adsorption efficiency. It was also found that silica-fume could play as a structure modifying agent that affect the molecular-structure of the adsorbent by formation of more Si–O–Si bonds due to increase in Si/Al molar ratio in the adsorbent composition.

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Ackley, M.W., Rege, S.U., Saxena, H.: Application of natural zeolites in the purification and separation of gases. Microporous Mesoporous Mater. 61, 25–42 (2003), https://doi.org/10.1016/S1387-1811(03)00353-6 CrossRef

Al-Harahsheh, M.S., Al Zboon, K., Al-Makhadmeh, L., Hararah, M., Mahasneh, M.: Fly ash based geopolymer for heavy metal removal: a case study on copper removal. J. Environ. Chem. Eng. 3, 1669–1677 (2015). https://doi.org/10.1016/j.jece.2015.06.005 CrossRef

Allahverdi, A., Mahinroosta, M.: Mechanical activation of chemically activated high phosphorous slag content cement. Powder Technol. 245, 182–188 (2013). https://doi.org/10.1016/j.powtec.2013.04.037 CrossRef

Allahverdi, A., Mahinroosta, M.: A model for prediction of compressive strength of chemically activated high phosphorous slag content cement. Int. J. Civ. Eng. 12, 481–487 (2014)

Allahverdi, A., Najafi Kani, E.: Application of FTIR-spectroscopy technique in characterizing molecular structure of natural pozzolan-based geoplymer cement. Iran. J. Mater. Sci. Eng. 6, 1–10 (2009)

Allahverdi, A., Akhondi, M., Mahinroosta, M.: Superior sodium sulfate resistance of a chemically activated phosphorus slag-based composite cement. J. Mater. Civ. Eng. 29(3), 04016231 (2016a). https://doi.org/10.1061/(ASCE)MT.1943-5533.0001762 CrossRef

Allahverdi, A., Pilehvar, S., Mahinroosta, M.: Influence of curing conditions on the mechanical and physical properties of chemically-activated phosphorous slag cement. Powder Technol. 288, 132–139 (2016b). https://doi.org/10.1016/j.powtec.2015.10.053.CrossRef

Amaral, C.N.R., Feiteira, F.N., Cruz, R.C., Cravo, V.O., Cassella, R.J., Pacheco, W.F.: Removal of basic violet 3 dye from aqueous media using a steel industry residue as solid phase. J. Environ. Chem. Eng. 4, 4184–4193 (2016). https://doi.org/10.1016/j.jece.2016.09.023 CrossRef

Andrejkovičová, S., Sudagar, A., Rocha, J., Patinha, C., Hajjaji, W., da Silva, E.F., Velosa, A., Rocha, F.: The effect of natural zeolite on microstructure, mechanical and heavy metals adsorption properties of metakaolin based geopolymers. Appl. Clay Sci. 126, 141–152 (2016). https://doi.org/10.1016/j.clay.2016.03.009 CrossRef

Balistrieri, L.S., Murray, J.W.: The surface chemistry of goethite (alpha FeOOH) in major ion seawater. Am. J. Sci. 281, 788–806 (1981). https://doi.org/10.2475/ajs.281.6.788 CrossRef

Bingol, D., Tekin, N., Alkan, M.: Brilliant Yellow dye adsorption onto sepiolite using a full factorial design. Appl Clay Sci. 50, 315–321 (2010). https://doi.org/10.1016/j.clay.2010.08.015 CrossRef

Box, G.E.P., Behnken, D.W.: American society for quality some New three level designs for the study of quantitative variables society for quality stable. Technometrics 2, 455–475 (1960)CrossRef

Cheng, T.W., Chiu, J.P.: Fire-resistant geopolymer produce by granulated blast furnace slag. Miner. Eng. 16, 205–210 (2003). https://doi.org/10.1016/S0892-6875(03)00008-6 CrossRef

Cheng, T.W., Lee, M.L., Ko, M.S., Ueng, T.H., Yang, S.F.: The heavy metal adsorption characteristics on metakaolin-based geopolymer. Appl. Clay Sci. 56, 90–96 (2012). https://doi.org/10.1016/j.clay.2011.11.027 CrossRef

Ciesielczyk, F., Bartczak, P., Wieszczycka, K., Siwinska-Stefanska, K., Nowacka, M., Jesionowski, T.: Adsorption of Ni(II) from model solutions using co-precipitated inorganic oxides. Adsorption 19, 423–434 (2013)CrossRef

Ciesielczyk, F., Bartczak, P., Jesionowski, T.: Removal of nickel(II) and cadmium(II) ions from aqueous solutions using an oxide adsorbent of MgO·SiO₂ type. Desalin. Water Treat. (2014). https://doi.org/10.1080/19443994.2014.925832 CrossRef

Ciesielczyk, F., Bartczak, P., Jesionowski, T.: Removal of cadmium(II) and lead(II) ions from model aqueous solutions using sol–gel-derived inorganic oxide adsorbent. Adsorption 22, 445–458 (2016)CrossRef

Ciesielczyk, F., Bartczak, P., Zdarta, J., Jesionowski, T.: Active MgO-SiO₂ hybrid material for organic dye removal: a mechanism and interaction study of the adsorption of C.I. Acid Blue 29 and C.I. Basic Blue 9. J. Environ. Manag. 204, 123–135 (2017)CrossRef

Diagboya, P.N.E., Dikio, E.D.: Silica-based mesoporous materials; emerging designer adsorbents for aqueous pollutants removal and water treatment. Microporous Mesoporous Mater. (2018). Accepted 10 Mar 2018. https://doi.org/10.1016/j.micromeso.2018.03.008 CrossRef

Dou, B., Hu, Q., Li, J., Qiao, Sh, Hao, Zh: Adsorption performance of VOCs in ordered mesoporous silicas with different pore structures and surface chemistry. J. Hazard. Mater. 186, 1615–1624 (2011). https://doi.org/10.1016/j.jhazmat.2010.12.051 CrossRefPubMed

Fiol, N., Villaescusa, I.: Determination of sorbent point zero charge: usefulness in sorption studies. Environ. Chem. Lett. 7, 79–84 (2009). https://doi.org/10.1007/s10311-008-0139-0 CrossRef

Ge, Y., Cui, X., Liao, C., Li, Z.: Facile fabrication of green geopolymer/alginate hybrid spheres for efficient removal of Cu(II) in water: batch and column studies. Chem. Eng. J. 311, 126–134 (2017). https://doi.org/10.1016/j.cej.2016.11.079 CrossRef

Gholami, M., Vardini, M.T., Mahdavinia, G.R.: Investigation of the effect of magnetic particles on the Crystal Violet adsorption onto a novel nanocomposite based on κ-carrageenan-g-poly(methacrylic acid). Carbohydr. Polym. 136, 772–781 (2016). https://doi.org/10.1016/j.carbpol.2015.09.044 CrossRefPubMed

Iglesias, M.J., Jimenez, A., Laggoun-Defarge, F., Suarez-Ruiz, I.: FTIR study of pure vitrains and associated coals. Energy Fuels. 9, 458–466 (1995). https://doi.org/10.1021/ef00051a010 CrossRef

Jayasantha Kumari, H., Krishnamoorthy, P., Arumugam, T.K., Radhakrishnan, S., Vasudevan, D.: An efficient removal of crystal violet dye from waste water by adsorption onto TLAC/Chitosan composite: a novel low cost adsorbent. Int. J. Biol. Macromol. 96, 324–333 (2017). https://doi.org/10.1016/j.ijbiomac.2016.11.077 CrossRefPubMed

Kazak, O., Eker, Y.R., Akin, I., Bingol, H., Tor, A.: A novel red mud at sucrose based carbon composite: preparation, characterization and its adsorption performance toward methylene blue in aqueous solution. J. Environ. Chem. Eng. 5, 2639–2647 (2017). https://doi.org/10.1016/j.jece.2017.05.018 CrossRef

Khan, M.I., Min, T.K., Azizli, K., Sufian, S., Ullah, H., Man, Z.: Effective removal of methylene blue from water using phosphoric acid based geopolymers: synthesis, characterizations and adsorption studies. RSC Adv. 5, 61410–61420 (2015). https://doi.org/10.1039/C5RA08255B CrossRef

Lee, N.K., Khalid, H.R., Lee, H.K.: Adsorption characteristics of cesium onto mesoporous geopolymers containing nano-crystalline zeolites. Microporous Mesoporous Mater. 242, 238–244 (2017). https://doi.org/10.1016/j.micromeso.2017.01.030 CrossRef

Li, L., Wang, S., Zhu, Z.: Geopolymeric adsorbents from fly ash for dye removal from aqueous solution. J. Colloid Interface Sci. 300, 52–59 (2006). https://doi.org/10.1016/j.jcis.2006.03.062 CrossRefPubMed

Liu, J., Wang, D.: The role of phosphorus slag in steam-cured concrete. Adv. Mater. Sci. Eng. (2017). https://doi.org/10.1155/2017/8392435 CrossRef

Low, L.W., Teng, T.T., Rafatullah, M., Morad, N., Azahari, B.: Adsorption studies of methylene blue and malachite green from aqueous solutions by pretreated lignocellulosic materials. Sep. Sci. Technol. 48, 1688–1698 (2013). https://doi.org/10.1080/01496395.2012.756912 CrossRef

Maghsoodloorad, H., Allahverdi, A.: Alkali-activation kinetics of phosphorus slag cement using compressive strength data. Ceram-Silikaty 59, 250–260 (2015)

Maghsoodloorad, H., Khalili, H., Allahverdi, A.: Alkali-activated phosphorous slag performance under different curing conditions: compressive strength, hydration products, and microstructure. J. Mater. Civ. Eng. 30, 4017253 (2018). https://doi.org/10.1061/(ASCE)MT.1943-5533.0002101 CrossRef

Mahat, M.K., Illias, R.M., Rahman, R.A., Rashid, N.A.A., Mahmood, N.A.N., Hassan, O., Aziz, S.A., Kamaruddin, K.: Production of cyclodextrin glucanotransferase (CGTase) from alkalophilic Bacillus sp. TS1-1: media optimization using experimental design. Enzyme Microb. Technol. 35, 467–473 (2004). https://doi.org/10.1016/j.enzmictec.2004.07.008 CrossRef

Mall, I.D., Srivastava, V.C., Kumar, G.V.A., Mishra, I.M.: Characterization and utilization of mesoporous fertilizer plant waste carbon for adsorptive removal of dyes from aqueous solution. Colloids Surf. A 278, 175–187 (2006). https://doi.org/10.1016/j.colsurfa.2005.12.017 CrossRef

Medri, V., Fabbri, S., Dedecek, J., Sobalik, Z., Tvaruzkova, Z., Vaccari, A.: Role of the morphology and the dehydroxylation of metakaolins on geopolymerization. Appl. Clay Sci. 50, 538–545 (2010). https://doi.org/10.1016/j.clay.2010.10.010 CrossRef

Montgomery, D.C.: Design and Analysis of Experiments. Wiley, Hoboken (1991)

Munthali, M.W., Elsheikh, M.A., Johan, E., Matsue, N.: Proton adsorption selectivity of zeolites in aqueous media: effect of Si/Al ratio of zeolites. Molecules 19, 20468–20481 (2014). https://doi.org/10.3390/molecules191220468 CrossRefPubMed

Naghsh, M., Shams, K.: Synthesis of a kaolin-based geopolymer using a novel fusion method and its application in effective water softening. Appl. Clay Sci. 146, 238–245 (2017). https://doi.org/10.1016/j.clay.2017.06.008 CrossRef

Najafi Kani, E., Allahverdi, A.: Effect of chemical composition on basic engineering properties of inorganic polymeric binder based on natural pozzolan. Ceram-Silikaty 53, 195–204 (2009a)

Najafi Kani, E., Allahverdi, A.: Effects of curing time and temperature on strength development of inorganic polymeric binder based on natural pozzolan. J. Mater. Sci. (2009b). https://doi.org/10.1007/s10853-009-3411-1 CrossRef

Najafi Kani, E., Mehdizadeh, H.: Investigating gel molecular structure and its relation with mechanical strength in geopolymer cement based on natural pozzolan using in situ ATR-FTIR spectroscopy. J. Mater. Civ. Eng. 29, 4017078 (2017). https://doi.org/10.1061/(ASCE)MT.1943-5533.0001917 CrossRef

Najafi Kani, E., Allahverdi, A., Provis, J.L.: Efflorescence control in geopolymer binders based on natural pozzolan. Cem. Concr. Compos. J. 34, 2181–2190 (2012). https://doi.org/10.1016/j.cemconcomp.211.07.007 CrossRef

Nikolov, A., Rostovsky, I., Nugteren, H.: Geopolymer materials based on natural zeolite. Case Stud. Constr. Mater. 6, 198–205 (2017). https://doi.org/10.1016/j.cscm.2017.03.001 CrossRef

Novais, R.M., Buruberri, L.H., Seabra, M.P., Labrincha, J.A.: Novel porous fly-ash containing geopolymer monoliths for lead adsorption from wastewaters. J. Hazard. Mater. 318, 631–640 (2016a). https://doi.org/10.1016/j.jhazmat.2016.07.059.CrossRefPubMed

Novais, R.M., Buruberri, L.H., Ascensão, G., Seabra, M.P., Labrincha, J.A.: Porous biomass fly ash-based geopolymers with tailored thermal conductivity. J. Clean Prod. 119, 99–107 (2016b). https://doi.org/10.1016/j.jclepro.2016.01.083.CrossRef

Rajabi, M., Mirza, B., Mahanpoor, K., Mirjalili, M., Najafi, F., Moradi, O., Sadegh, H., Shahryari-ghoshekandi, R., Asif, M., Tyagi, I., Agarwal, S., Gupta, V.K.: Adsorption of malachite green from aqueous solution by carboxylate group functionalized multi-walled carbon nanotubes: determination of equilibrium and kinetics parameters. J. Ind. Eng. Chem. 34, 130–138 (2016). https://doi.org/10.1016/j.jiec.2015.11.001 CrossRef

Runtti, H., Luukkonen, T., Niskanen, M., Tuomikoski, S., Kangas, T., Tynjälä, P., Tolonen, E.T., Sarkkinen, M., Kemppainen, K., Rämö, J., Lassi, U.: Sulphate removal over barium-modified blast-furnace-slag geopolymer. J. Hazard. Mater. 317, 373–384 (2016). https://doi.org/10.1016/j.jhazmat.2016.06.001 CrossRefPubMed

Saif Ur Rehman, M., Munir, M., Ashfaq, M., Rashid, N., Nazar, M.F., Danish, M., Han, J.I.: Adsorption of Brilliant Green dye from aqueous solution onto red clay. Chem. Eng. J. 228, 54–62 (2013). https://doi.org/10.1016/j.cej.2013.04.094 CrossRef

Santos, S.C.R., Boaventura, R.A.R.: Adsorption modelling of textile dyes by sepiolite. Appl Clay Sci. 42, 137–145 (2008). https://doi.org/10.1016/j.clay.2008.01.002 CrossRef

Segurola, J., Allen, N.S., Edge, M., Mc Mahon, A.: Design of eutectic photoinitiator blends for UV/visible curable acrylated printing inks and coatings. Prog. Org. Coatings 37, 23–37 (1999). https://doi.org/10.1016/S0300-9440(99)00052-1 CrossRef

Shi, Q., Zhang, J., Zhang, C., Nie, W., Zhang, B., Zhang, H.: Adsorption of Basic Violet 14 in aqueous solutions using KMnO4-modified activated carbon. J. Colloid Interface Sci. 343, 188–193 (2010). https://doi.org/10.1016/j.jcis.2009.08.021 CrossRefPubMed

Smičiklas, I.D., Milonjić, S.K., Pfendt, P., Raičević, S.: The point of zero charge and sorption of cadmium(II) and strontium(II) ions on synthetic hydroxyapatite. Sep. Purif. Technol. 18, 185–194 (2000). https://doi.org/10.1016/S1383-5866(99)00066-0 CrossRef

Soleimani, M.A., Naghizadeh, R., Mirhabibi, A.R., Golestanifard, F.: The influence of phosphorus slag addition on microstructure and mechanical properties of metakaolin-based geopolymer pastes. Ceram-Silikaty 57, 33–38 (2013)

Tripathi, P., Srivastava, V.C., Kumar, A.: Optimization of an azo dye batch adsorption parameters using Box-Behnken design. Desalination 249, 1273–1279 (2009). https://doi.org/10.1016/j.desal.2009.03.010 CrossRef

Van Jaarsveld, J.G.S., Van Deventer, J.S.J., Lorenzen, L.: The potential use of geopolymeric materials to immobilise toxic metals: part I. Theory and applications. Miner. Eng. 10, 659–669 (1997). https://doi.org/10.1016/S0892-6875(97)00046-0 CrossRef

Van Jaarsveld, J.G., Van Deventer, J.S., Lukey, G.: The effect of composition and temperature on the properties of fly ash- and kaolinite-based geopolymers. Chem. Eng. J. 89, 63–73 (2002). https://doi.org/10.1016/S1385-8947(02)00025-6 CrossRef

Wang, H., Li, H., Yan, F.: Synthesis and mechanical properties of metakaolinite-based geopolymer. Colloids Surf. A 268, 1–6 (2005). https://doi.org/10.1016/j.colsurfa.2005.01.016 CrossRef

Wang, Z., Li, X., Liang, H., Ning, J., Zhou, Z., Li, G.: Equilibrium, kinetics and mechanism of Au³⁺, Pd²⁺ and Ag⁺ ions adsorption from aqueous solutions by graphene oxide functionalized persimmon tannin. Mater. Sci. Eng. C 79, 227–236 (2017). https://doi.org/10.1016/j.msec.2017.05.038 CrossRef

Xu, H., Van Deventer, J.S.J.: The geopolymerisation of alumino-silicate minerals. Int. J. Miner. Process. 59, 247–266 (2000). https://doi.org/10.1016/S0301-7516(99)00074-5 CrossRef

Xu, H., Allard, B., Grimvall, A.: Effects of acidification and natural organic materials on the mobility of arsenic in the environment. Water Air Soil Pollut. 57–58, 269–278 (1991). https://doi.org/10.1007/BF00282890 CrossRef

Yao, X., Zhang, Z., Zhu, H., Chen, Y.: Geopolymerization process of alkali-metakaolinite characterized by isothermal calorimetry. Thermochim. Acta 493, 49–54 (2009). https://doi.org/10.1016/j.tca.2009.04.002 CrossRef

Yavuz, O., Altunkaynak, Y., Uzel, F.G.: Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite. Water Res. 37, 948–952 (2003). https://doi.org/10.1016/S0043-1354(02)00409-8 CrossRefPubMed

Yu, M., Han, Y., Li, J., Wang, L.: CO₂-activated porous carbon derived from cattail biomass for removal of malachite green dye and application as supercapacitors. Chem. Eng. J. 317, 493–502 (2017). https://doi.org/10.1016/j.cej.2017.02.105 CrossRef

Zhang, F., Wei, Z., Zhang, W., Cui, H.: Effective adsorption of malachite green using magnetic barium phosphate composite from aqueous solution. Spectrochim. Acta A 182, 116–122 (2017). https://doi.org/10.1016/j.saa.2017.03.066 CrossRef

Zuhua, Z., Xiao, Y., Huajun, Z., Yue, C.: Role of water in the synthesis of calcined kaolin-based geopolymer. Appl. Clay Sci. 43, 218–223 (2009). https://doi.org/10.1016/j.clay.2008.09.003 CrossRef

Titel: Green cylindrical mesoporous adsorbent based on alkali-activated phosphorous slag: synthesis, dye removal, and RSM modeling
verfasst von: Ali Salehi
Ebrahim Najafi Kani
Publikationsdatum: 05.09.2018
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 7/2018
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-018-9972-z

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