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Journal of Materials Engineering and Performance
Erschienen in: Journal of Materials Engineering and Performance 9/2020

18.09.2020

Green Process for Preparation of Nickel Hydroxide Films and Membranes

verfasst von: Audrey Vecoven, Dewan Russel Rahman, Allen W. Apblett

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 9/2020

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Abstract

Nickel hydroxides have numerous applications including as battery electrodes, electrochromic devices, electrochemical sensors, and supercapacitors and in such processes as photocatalysis, electrocatalysis, and electrosynthesis. A simple solution growth process for production of beta-Ni(OH)2 has been developed. The process involves dissolution of nickel hydroxide powders in concentrated ammonia to form [Ni(NH3)6](OH)2. If ammonia is allowed to evaporate from the resulting solution, the dissolution process is reversed and crystalline films of beta-Ni(OH)2 are deposited that consist of closely packed micron-sized clumps of thin plates. Addition of sodium aluminate to the solution makes it possible to also prepare alpha nickel hydroxide as free standing membranes at air–water interface. The overall procedure can be described as a green process since it eliminates the environmental burden of by-product production because Ni(OH)2 is simply dissolved and transformed into the desired material without producing waste salts such as ammonium nitrate or ammonium chloride that would be produced by a conventional precipitation approach for Ni(OH)2 membrane or film preparation.
Vorheriger Artikel A Study on the Sintering of a Mixed Powder Containing Alumina and Aluminum for Control of Volume Shrinkage during Sintering
Nächster Artikel Multi-Objective Optimization for Energy Absorption of Carbon Fiber-Reinforced Plastic/Aluminum Hybrid Circular Tube under Both Transverse and Axial Loading

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Metadaten
Titel
Green Process for Preparation of Nickel Hydroxide Films and Membranes
verfasst von
Audrey Vecoven
Dewan Russel Rahman
Allen W. Apblett
Publikationsdatum
18.09.2020
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 9/2020
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-020-05100-5

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