Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 1/2016

01.09.2015 | 50th Anniversary

Hardening in non-stoichiometric (1 − x)Bi0.5Na0.5TiO3–xBaTiO3 lead-free piezoelectric ceramics

verfasst von: Sasiporn Prasertpalichat, David P. Cann

Erschienen in: Journal of Materials Science | Ausgabe 1/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The role of A-site non-stoichiometry was investigated in lead-free piezoelectric ceramics based on compositions in the 1 − x(Bi0.5Na0.5TiO3)–xBaTiO3 system near the morphotropic phase boundary, where x = 0.055, 0.06, and 0.07. Donor doping was introduced through the addition of excess Bi, however, there were no changes in the crystal structure. In contrast, acceptor doping was introduced through the addition of excess Na and was found to promote rhombohedral distortions. A significant improvement of dielectric properties was observed in donor-doped compositions and, in contrast, a degradation in properties was observed in acceptor-doped compositions. Compared to the stoichiometric composition, the acceptor-doped compositions displayed a significant increase in coercive field (E c) which is an indication of domain wall pinning as found in hard Pb(Zr x Ti1−x )O3. This result was further confirmed via remanent polarization hysteresis analyses. Moreover, all A-site acceptor-doped compositions also exhibited an increase in mechanical quality factor (Q m) as well as a decrease in piezoelectric coefficient (d 33), dielectric loss (tan δ), remanent polarization (P r), and dielectric permittivity, which are all the typical characteristics of the effects of “hardening.” The mechanism for the observed hardening in A-site acceptor-doped BNT-based systems is linked to changes in the long-range domain structure and defect chemistry.
Vorheriger Artikel The mechanism of grain boundary motion in SrTiO3
Nächster Artikel Low-voltage ferroelectric–paraelectric superlattices as gate materials for field-effect transistors

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Jaffe B (1971) Piezoelectric ceramics, vol 3. Academic Press, London
2.
Berlincourt D, Mattiat OE, Kikuchi Y (1971) Ultrasonic transducer materials. Plenum Pub Corp, New York
3.
Gerson R (1960) Variation in ferroelectric characteristics of lead zirconate titanate ceramics due to minor chemical modifications. J Appl Phys 31(1):188–194CrossRef
4.
Chandrasekaran A, Damjanovic D, Setter N, Marzari N (2013) Defect ordering and defect–domain-wall interactions in PbTiO3: a first-principles study. Phys Rev B 88(21):214116CrossRef
5.
He L, Vanderbilt D (2003) First-principles study of oxygen-vacancy pinning of domain walls in PbTiO3. Phys Rev B 68(13):134103CrossRef
6.
Moulson AJ, Herbert JM (2003) Electroceramics: materials, properties, applications. Wiley, New YorkCrossRef
7.
Zhang S, Lim JB, Lee HJ, Shrout TR (2009) Characterization of hard piezoelectric lead-free ceramics. IEEE Trans Ultrason Ferroelectr Freq Control 56(8):1523–1527CrossRef
8.
Shrout TR, Zhang SJ (2007) Lead-free piezoelectric ceramics: alternatives for PZT? J Electroceram 19(1):113–126CrossRef
9.
Lambeck P, Jonker G (1986) The nature of domain stabilization in ferroelectric perovskites. J Phys Chem Solids 47(5):453–461CrossRef
10.
Lupascu DC, Genenko YA, Balke N (2006) Aging in ferroelectrics. J Am Ceram Soc 89(1):224–229CrossRef
11.
Genenko YA, Glaum J, Hirsch O, Kungl H, Hoffmann M, Granzow T (2009) Aging of poled ferroelectric ceramics due to relaxation of random depolarization fields by space-charge accumulation near grain boundaries. Phys Rev B 80(22):224109CrossRef
12.
Robels U, Arlt G (1993) Domain wall clamping in ferroelectrics by orientation of defects. J Appl Phys 73(7):3454–3460CrossRef
13.
Smolenskii G, Isupov V, Agranovskaya A, Krainik N (1961) New ferroelectrics of complex composition. Sov Phys Solid State 2(11):2651–2654
14.
Takenaka T, Maruyama K-I, Sakata K (1991) (Bi1/2Na1/2)TiO3-BaTiO3 system for lead-free piezoelectric ceramics. Jpn J Appl Phys 30(9B):2236–2239CrossRef
15.
Yoshii K, Hiruma Y, Nagata H, Takenaka T (2006) Electrical properties and depolarization temperature of (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3 lead-free piezoelectric ceramics. Jpn J Appl Phys 45:4493CrossRef
16.
Takenaka T, Okuda T, Takegahara K (1997) Lead-free piezoelectric ceramics based on (Bi1/2Na1/2)TiO3-NaNbO3. Ferroelectrics 196(1):175–178CrossRef
17.
Xu C, Lin D, Kwok K (2008) Structure, electrical properties and depolarization temperature of (Bi0.5Na0.5)TiΟ3-BaTiΟ3 lead-free piezoelectric ceramics. Solid State Sci 10(7):934–940CrossRef
18.
Ranjan R, Dviwedi A (2005) Structure and dielectric properties of (Na0.50Bi0.50)1−xBaxTiO3:0 ≤ x ≤ 0.10. Solid State Commun 135(6):394–399CrossRef
19.
Simons H, Daniels J, Jo W, Dittmer R, Studer A, Avdeev M, Jr Rödel, Hoffman M (2011) Electric-field-induced strain mechanisms in lead-free 94%(Bi1/2Na1/2)TiO3–6%BaTiO3. Appl Phys Lett 98(8):082901. doi:10.​1063/​1.​3557049 CrossRef
20.
Daniels JE, Jo W, Rödel J, Jones JL (2009) Electric-field-induced phase transformation at a lead-free morphotropic phase boundary: case study in a 93% (Bi0.5Na0.5)TiO3–7%BaTiO3 piezoelectric ceramic. Appl Phys Lett 95:3. doi:10.​1063/​1.​3182679 CrossRef
21.
Schmitt LA, Kling J, Hinterstein M, Hoelzel M, Jo W, Kleebe H-J, Fuess H (2011) Structural investigations on lead-free Bi1/2Na1/2TiO3-based piezoceramics. J Mater Sci 46(12):4368–4376. doi:10.​1007/​s10853-011-5427-6 CrossRef
22.
23.
Ma C, Tan X, Dul’Kin E, Roth M (2010) Domain structure-dielectric property relationship in lead-free (1 − x)(Bi1/2Na1/2)TiO3-xBaTiO3 ceramics. J Appl Phys 108(10):104105–104108CrossRef
24.
25.
26.
Li Q, Wang H, Fan H, Long C, Liu X (2014) Ferroelectric, electromechanical, and dielectric properties of (Na0.5Bi0.5)0.94Ba0.06TiO3 co-doped MnO2 and La2O3 lead-free ceramics. J Mater Sci 49(1):211–217. doi:10.​1007/​s10853-013-7694-x CrossRef
27.
Yu Z, Krstic VD, Mukherjee BK (2007) Microstructure and properties of lead-free (Bi1/2Na1/2)TiO3 based piezoelectric ceramics doped with different cations. J Mater Sci 42(10):3544–3551. doi:10.​1007/​s10853-007-1558-1 CrossRef
28.
Aksel E, Erdem E, Jakes P, Jones JL, Eichel R-A (2010) Defect structure and materials “hardening” in FeO-doped [BiNa]TiO ferroelectrics. Appl Phys Lett 97:012903CrossRef
29.
Jo W, Erdem E, Eichel R-A, Glaum J, Granzow T, Damjanovic D, Rodel J (2010) Effect of Nb-donor and Fe-acceptor dopants in (Bi1/2Na1/2)TiO3–BaTiO3–(K0.5Na0.5)NbO3 lead-free piezoceramics. J Appl Phys 108(1):014110–014116CrossRef
30.
Zhu M, Liu L, Hou Y, Wang H, Yan H (2007) Microstructure and electrical properties of MnO-doped (Na0.5Bi0.5)0.92Ba0.08TiO3 lead-free piezoceramics. J Am Ceram Soc 90(1):120–124CrossRef
31.
Hiruma Y, Nagata H, Takenaka T (2009) Thermal depoling process and piezoelectric properties of bismuth sodium titanate ceramics. J Appl Phys 105(8):084112–084118CrossRef
32.
Sung Y, Kim J, Cho J, Song T, Kim M, Chong H, Park T, Do D, Kim S (2010) Effects of Na nonstoichiometry in Bi0.5Na0.5+x)TiO3 ceramics. Appl Phys Lett 96(2):022901–022903CrossRef
33.
Sung Y, Kim J, Cho J, Song T, Kim M, Park T (2011) Effects of Bi nonstoichiometry in (Bi0.5+xNa)TiO3 ceramics. Appl Phys Lett 98(1):012902CrossRef
34.
Jaffe H, Berlincourt D, Kinsley T, Lambert T, Schwartz D, Gerber E, Fair I (1961) IRE standards on piezoelectric crystals: measurements of piezoelectric ceramics. Proc IRE 49:1161–1169CrossRef
35.
Hammer M, Monty C, Endriss A, Hoffmann MJ (1998) Correlation between surface texture and chemical composition in undoped, hard, and soft piezoelectric PZT ceramics. J Am Ceram Soc 81(3):721–724CrossRef
36.
Ma C, Tan X (2010) Phase diagram of unpoled lead-free-ceramics. Solid State Commun 150(33):1497–1500CrossRef
37.
Ma C, Guo H, Tan X (2013) A new phase boundary in (Bi1/2Na1/2)TiO3 − BaTiO3 Revealed via a novel method of electron diffraction analysis. Adv Funct Mater 23(42):5261–5266. doi:10.​1002/​adfm.​201300640 CrossRef
38.
Spreitzer M, Valant M, Suvorov D (2007) Sodium deficiency in Na0.5Bi0.5TiO3. J Mater Chem 17(2):185–192CrossRef
39.
Kofstad P (1972) Nonstoichiometry, diffusion, and electrical conductivity in binary metal oxides. Wiley Interscience, New York
40.
Li M, Pietrowski MJ, De Souza RA, Zhang H, Reaney IM, Cook SN, Kilner JA, Sinclair DC (2014) A family of oxide ion conductors based on the ferroelectric perovskite Na0.5Bi0.5TiO3. Nat Mater 13(1):31–35CrossRef
41.
Rödel J, Jo W, Seifert KT, Anton EM, Granzow T, Damjanovic D (2009) Perspective on the development of lead-free piezoceramics. J Am Ceram Soc 92(6):1153–1177CrossRef
42.
Smyth DM (2000) The defect chemistry of metal oxides. The defect chemistry of metal oxides, by DM Smyth, pp 304 Foreword by DM Smyth Oxford University Press, Jun 2000 ISBN-10: 0195110145 ISBN-13: 9780195110142 1
43.
Zuo R, Su S, Wu Y, Fu J, Wang M, Li L (2008) Influence of A-site nonstoichiometry on sintering, microstructure and electrical properties of (Bi0.5Na0.5)TiO3 ceramics. Mater Chem Phys 110(2):311–315CrossRef
44.
Eichel R-A (2011) Structural and dynamic properties of oxygen vacancies in perovskite oxides—analysis of defect chemistry by modern multi-frequency and pulsed EPR techniques. Phys Chem Chem Phys 13(2):368–384CrossRef
45.
Rt Shannon (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr Sect A: Cryst Phys Diffr, Theor General Crystallogr 32(5):751–767CrossRef
46.
Carter J, Aksel E, Iamsasri T, Forrester JS, Chen J, Jones JL (2014) Structure and ferroelectricity of nonstoichiometric (Na0.5Bi0.5)TiO3. Appl Phys Lett 104(11):112904CrossRef
47.
Chen M, Xu Q, Kim BH, Ahn BK, Ko JH, Kang WJ, Nam OJ (2008) Structure and electrical properties of (Na0.5Bi0.5)1−xBaxTiO3 piezoelectric ceramics. J Eur Ceram Soc 28(4):843–849CrossRef
48.
Chu B-J, Chen D-R, Li G-R, Yin Q-R (2002) Electrical properties of Na1/2Bi1/2TiO3-BaTiO3 ceramics. J Eur Ceram Soc 22(13):2115–2121CrossRef
49.
Zhang Q, Zhao J, Cross L (1996) Aging of the dielectric and piezoelectric properties of relaxor ferroelectric lead magnesium niobate–lead titanate in the electric field biased state. J Appl Phys 79(6):3181–3187CrossRef
50.
Arlt G, Robels U (1993) Aging and fatigue in bulk ferroelectric perovskite ceramics. Integr Ferroelectr 3(4):343–349CrossRef
51.
Takahashi S, Takahashi M (1972) Effects of impurities on the mechanical quality factor of lead zirconate titanate ceramics. Jpn J Appl Phys 11(1):31CrossRef
52.
Damjanovic D (1998) Ferroelectric, dielectric and piezoelectric properties of ferroelectric thin films and ceramics. Rep Prog Phys 61(9):1267CrossRef
53.
Pohanka RC, Smith P (1987) Recent advances in piezoelectric ceramics. Electron Ceram 45–146
54.
Lin D, Kwok K, Chan H (2008) Piezoelectric and ferroelectric properties of Cu-doped K0.5Na0.5NbO3 lead-free ceramics. J Phys D Appl Phys 41(4):045401CrossRef
55.
Rubio-Marcos F, Marchet P, Romero J, Fernández J (2011) Structural, microstructural and electrical properties evolution of (K, Na, Li)(Nb, Ta, Sb)O3 lead-free piezoceramics through NiO doping. J Eur Ceram Soc 31(13):2309–2317CrossRef
56.
Rubio-Marcos F, Marchet P, Vendrell X, Romero J, Rémondière F, Mestres L, Fernández J (2011) Effect of MnO doping on the structure, microstructure and electrical properties of the (K, Na, Li)(Nb, Ta, Sb)O3 lead-free piezoceramics. J Alloy Compd 509(35):8804–8811CrossRef
57.
Rubio-Marcos F, Reinosa J, Vendrell X, Romero J, Mestres L, Leret P, Fernández J, Marchet P (2013) Structure, microstructure and electrical properties of Cu2+ doped (K, Na, Li)(Nb, Ta, Sb)O3 piezoelectric ceramics. Ceram Int 39(4):4139–4149CrossRef
58.
Rubio-Marcos F, Romero JJ, Fernández JF, Marchet P (2011) Control of the crystalline structure and piezoelectric properties of (K, Na, Li)(Nb, Ta, Sb)O3 ceramics through transition metal oxide doping. Appl Phys Exp 4(10):101501CrossRef
59.
Zhang L, Ren X (2006) Aging behavior in single-domain Mn-doped BaTiO3 crystals: implication for a unified microscopic explanation of ferroelectric aging. Phys Rev B 73(9):094121CrossRef
60.
Sapper E, Dittmer R, Damjanovic D, Erdem E, Keeble DJ, Jo W, Granzow T, Rödel J (2014) Aging in the relaxor and ferroelectric state of Fe-doped (1 − x)(Bi1/2Na1/2)TiO3-xBaTiO3 piezoelectric ceramics. J Appl Phys 116(10):104102CrossRef
Metadaten
Titel
Hardening in non-stoichiometric (1 − x)Bi0.5Na0.5TiO3–xBaTiO3 lead-free piezoelectric ceramics
verfasst von
Sasiporn Prasertpalichat
David P. Cann
Publikationsdatum
01.09.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 1/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-9235-2

Weitere Artikel der Ausgabe 1/2016

Journal of Materials Science 1/2016 Zur Ausgabe

50th Anniversary

Magnetic nanoparticles: material engineering and emerging applications in lithography and biomedicine

50th Anniversary

Review: grain boundary faceting–roughening phenomena

50th Anniversary

Nanostructured Al and Cu alloys with superior strength and electrical conductivity

50th Anniversary

A review of exfoliated graphite

50th Anniversary

Review: achieving superplastic properties in ultrafine-grained materials at high temperatures

50th Anniversary

The performance of austenitic and duplex stainless steels in cracked concrete exposed to concentrated chloride brine

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise