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2016 | OriginalPaper | Buchkapitel

3. Heteropolyacid-Based Heterogeneous Photocatalysts for Environmental Application

verfasst von : Elisa I. García-López, Giuseppe Marcì, Leonardo Palmisano

Erschienen in: Heterogeneous Photocatalysis

Verlag: Springer Berlin Heidelberg

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Abstract

Polyoxometalates (POMs) are a wide class of discrete nanosized transition metal–oxygen clusters. The synthesis of POMs has received great interest not only because they present intriguing architectures but also because they have potential applications in catalysis, medicine, electrochemistry, materials design or models for self-assembling nanoscale systems. Recently, POMs have also been studied as green and cheap photocatalysts. The potentialities of POMs are attributed to their unique structural features; indeed, POMs are photostable and non-toxic, have oxygen-rich surfaces and excellent redox properties and possess photochemical characteristics similar to those of the semiconductor photocatalysts. Heteropolyacids (HPAs), including their anions, are a POM subclass. In this chapter their photocatalytic properties when they are immobilized on various supports are described citing a part of the existing literature.

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Vorheriges Kapitel Photocatalytic Water Oxidation

Nächstes Kapitel Alternative Materials to TiO2

Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38CrossRef

Schiavello M (ed) (1998) Photocatalysis and environment. Trends and applications. Kluwer, Dordrecht

Chen H, Nanayakkara CE, Grassian VH (2012) Titanium oxide photocatalysis in atmospheric chemistry. Chem Rev 112:5919–5948CrossRef

Kubacka A, Fernández-García M, Colón G (2012) Advanced nanoarchitectures for solar photocatalytic applications. Chem Rev 112:1555–1614CrossRef

Palmisano L, Augugliaro V, Bellardita M, Di Paola A, García-López E, Loddo V, Marcì G, Palmisano G, Yurdakal S (2011) Titania photocatalyst for selective oxidations in water. ChemSusChem 4:1431–1438CrossRef

Palmisano G, García-López EI, Marcì G, Loddo V, Yurdakal S, Augugliaro V, Palmisano L (2010) Advances in selective conversions by heterogeneous photocatalysis. Chem Commun 46:7074–7089CrossRef

Marcì G, Addamo M, Augugliaro V, Coluccia S, García-López EI, Loddo V, Martra G, Palmisano L, Schiavello M (2003) Photocatalytic oxidation of toluene on irradiated TiO₂: comparison of degradation performance in humidified air, in water and in water containing a zwitterionic surfactant. J Photochem Photobiol A 160:105–114CrossRef

Di Paola A, García-López EI, Marcì G, Palmisano L (2012) A survey of photocatalytic materials for environmental remediation. J Hazard Mater 211–212:3–29CrossRef

Katsoulis DE (1998) A survey of applications of polyoxometalates. Chem Rev 98:359–387CrossRef

10.

Long D, Burkholder E, Cronin L (2007) Polyoxometalate clusters, nanostructures and materials: from self assembly to designer materials and devices. Chem Soc Rev 36:105–121CrossRef

11.

Pope MT, Müller A (1991) Polyoxometalate chemistry: an old field with new dimensions in several disciplines. Angew Chem Int Ed Engl 30:34–48CrossRef

12.

Pope MT (1983) Heteropoly and isopoly oxometalates. Springer, BerlinCrossRef

13.

Errington RJ, Wingad RL, Clegg W, Elsegood MRJ (2000) Direct bromination of Keggin fragments to give [PW₉O₂₈Br₆]³⁻: a polyoxotungstate with a hexabrominated face. Angew Chem Int Ed Engl 39:3884–3886CrossRef

14.

Mizuno N, Misono M (1998) Heterogeneous catalysis. Chem Rev 98:199–217CrossRef

15.

Okuhara T, Mizuno N, Misono M (1996) Catalytic chemistry of heteropoly compounds. Adv Catal 41:113–252

16.

Misono M (2001) Unique acid catalysis of heteropoly compounds (heteropolyoxometalates) in the solid state. Chem Commun 1141–1152

17.

Briand LE, Baronetti GT, Thomas HJ (2003) The state of the art on Wells–Dawson heteropoly-compounds: a review of their properties and applications. Appl Catal A 256:37–50CrossRef

18.

Micek-Ilnicka A (2009) The role of water in the catalysis on solid heteropolyacids. J Mol Catal A 308:1–14CrossRef

19.

Kozhevnikov IV (2002) Catalysis for fine chemical synthesis. Vol. 2: catalysis by polyoxometalates. Wiley, Chichester

20.

Anastas PT, Warner JC (1998) Green chemistry: theory and practice. Oxford University Press, New York

21.

Boglio C, Lemière G, Hasenknopf B, Thorimbert S, Lacôte E, Malacria M (2006) Lanthanide complexes of the monovacant Dawson polyoxotungstate [a1-P2W17O61]10 as selective and recoverable Lewis acid catalysts. Angew Chem 118:3402–3405

22.

Kozhevnikov IV (1998) Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions. Chem Rev 98:171–198CrossRef

23.

Zhou Y, Chen G, Long Z, Wang J (2014) Recent advances in polyoxometalate-based heterogeneous catalytic materials for liquid-phase organic transformations. RSC Adv 4:42092–42113CrossRef

24.

Pope MT, Müller A (2001) Polyoxometalate chemistry from topology via self-assembly to applications. Kluwer, New York

25.

Borrás-Almenar JJ, Coronado E, Müller A, Pope MT (2003) Polyoxometalate molecular science. Kluwer, DordrechtCrossRef

26.

Yamase T, Pope MT (2004) Polyoxometalate chemistry for nano-composite design. Kluwer, New YorkCrossRef

27.

Hill CL (1998) Introduction: polyoxometalates multicomponent molecular vehicles to probe fundamental issues and practical problems. Chem Rev 98:1–2CrossRef

28.

Cronin L, Müller A (2012) From serendipity to design of polyoxometalates at the nanoscale, aesthetic beauty and applications. Chem Soc Rev 41:7333–7334CrossRef

29.

Omwoma S, Chen W, Tsunashima R, Song YF (2014) Recent advances on polyoxometalates intercalated layered double hydroxides: from synthetic approaches to functional material applications. Coord Chem Rev 258–259:58–71CrossRef

30.

Omwoma S, Gore CT, Ji Y, Hu C, Song Y (2015) Environmentally benign polyoxometalate materials. Coord Chem Rev 286:17–29CrossRef

31.

Hill CL (ed) (1996) Polyoxometalates in catalysis. J Mol Catal A 114:1–359

32.

Hill CL (ed) (1998) Polyoxometalates multicomponent molecular vehicles to probe fundamental issues and practical problems. Chem Rev 98:1–390

33.

Kiricsi I, Molnár A (eds) (2003) Heteropolyacids in catalysis. App Catal A 256:1–328

34.

Guo Y, Hu C (2007) Heterogeneous photocatalysis by solid polyoxometalates. J Mol Catal A 262:136–148CrossRef

35.

Sivakumar R, Thomas J, Yoon M (2012) Polyoxometalate-based molecular/nano composites: advances in environmental remediation by photocatalysis and biomimetic approaches to solar energy conversion. J Photochem Photobiol C 13:277–298CrossRef

36.

Okuhara T, Mizuno N, Misono M (2001) Catalysis by heteropoly compounds-recent developments. Appl Catal A 222:63–77CrossRef

37.

Kozhevnikov IV (2007) Sustainable heterogeneous acid catalysis by heteropoly acids. J Mol Catal A 262:86–92CrossRef

38.

Itagaki S, Kamata K, Yamaguchi K, Mizuno N (2013) A monovacant lacunary silicotungstate as an efficient heterogeneous catalyst for dehydration of primary amides to nitriles. ChemCatChem 5:1725–1728CrossRef

39.

Izumi Y, Ogawa M, Urabe K (1995) Alkali metal salts and ammonium salts of Keggin-type heteropolyacids as solid acid catalysts for liquid-phase Friedel-Crafts reactions. Appl Catal A 132:127–140CrossRef

40.

Pizzio LR, Cáceres CV, Blanco MN (1998) Acid catalysts prepared by impregnation of tungstophosphoric acid solutions on different supports. Appl Catal A 167:283–294CrossRef

41.

Vazquez P, Pizzio LR, Romanelli G, Autino J, Caceres CV, Blanco MN (2002) Mo and W heteropolyacid based catalysts applied to the preparation of flavones and substituted chromones by cyclocondensation of o-hydroxyphenyl aryl 1,3-propanediones. Appl Catal A 235:233–240CrossRef

42.

Kozhevnikov IV, Sinnema A, Jansen RJJ, Pamin K, van Bekkum H (1994) New acid catalyst comprising heteropoly acid on a mesoporous molecular sieve MCM-41. Catal Lett 30:241–252CrossRef

43.

Marme F, Coudurier G, Vedrine JC (1998) Acid-type catalytic properties of heteropolyacid H₃PW₁₂O₄₀ supported on various porous silica-based materials. Micropor Mesopor Mater 22:151–163CrossRef

44.

Kim W, Kim M, Kim J, Seo G (2003) Dispersion measurement of heteropoly acid supported on KIT-1 mesoporous material. Micropor Mesopor Mater 2003(57):113–120CrossRef

45.

Bielanski A, Lubanska A, Pozniczek J, Micek-Ilnicka A (2003) Oxide supports for 12-tungstosilicic acid catalysts in gas phase synthesis of MTBE. Appl Catal A 238:239–250CrossRef

46.

Pizzio LR, Vazquez PG, Caceres CV, Blanco MN (2003) Supported Keggin type heteropolycompounds for ecofriendly reactions. Appl Catal A 256:125–139CrossRef

47.

Hernandez-Cortez JG, López T, Manriquez ME, Gómez R, Navarrete J (2003) Thermally induced phase transformation on 12-tungstophosphoric acid/ZrO₂ Sol–gel. J Sol–Gel Sci Technol 26:213–216CrossRef

48.

Bachiller-Baeza B, Anderson JA (2002) FTIR and reaction studies of styrene and toluene over silica-zirconia-supported heteropoly acid catalysts. J Catal 212:231–239CrossRef

49.

Jiang S, Guo Y, Wang C, Qu X, Li L (2007) One-step sol–gel preparation and enhanced photocatalytic activity of porous polyoxometalate-tantalum pentoxide nanocomposites. J Colloid Interface Sci 308:208–215CrossRef

50.

Mukai R, Sugiyama T, Tamon H (2003) Immobilization of heteropoly acids in the network structure of carbon gels. Appl Catal A 256:99–105CrossRef

51.

Hodjati S, Vaezzadeh K, Petit C, Pitchon V, Kiennemann A (2001) The mechanism of the selective NOx sorption on H₃PW₁₂O₄₀·6H₂O (HPW). Top Catal 16–17:151–155CrossRef

52.

Madhusudhan Rao P, Wolfson A, Kababya S, Vega S, Landau MV (2005) Immobilization of molecular H₃PW₁₂O₄₀ heteropolyacid catalyst in alumina-grafted silica-gel and mesostructured SBA-15 silica matrices. J Catal 232:210–225CrossRef

53.

Papacostantinou E (1989) Photochemistry of polyoxometalates of molybdenum and tungsten and/or vanadium. Chem Soc Rev 18:1–31CrossRef

54.

Park H, Choi W (2003) Photoelectrochemical investigation on electron transfer mediating behaviors of polyoxometalate in UV-illuminated suspensions of TiO₂ and Pt/TiO₂. J Phys Chem B 107:3885–3890CrossRef

55.

Marcì G, García-López EI, Palmisano L (2012) Comparison between catalytic and catalytic photo-assisted propene hydration by using supported heteropolyacid. Appl Catal A 421–422:70–78CrossRef

56.

Hiskia A, Mylonas A, Papaconstantinou E (2001) Comparison of the photoredox properties of polyoxometalates and semiconducting particles. Chem Soc Rev 30:62–69CrossRef

57.

Guo Y, Hu C (2007) Heterogeneous photocatalysis by solid polyoxometalates. J Mol Catal A: Chem 262:136–148CrossRef

58.

Guo Y, Hu C, Wang Y, Wang E, Zhou Y, Feng S (2000) Microporous polyoxometalates POMs/SiO₂: synthesis and photocatalytic degradation of aqueous organochlorine pesticides. Chem Mater 12:3501–3508CrossRef

59.

Guo Y, Yang Y, Hu C, Guo C, Wang E, Zhou Y, Feng S (2002) Preparation, characterization and photochemical properties of ordered macroporous hybrid silica materials based on monovacant Keggin-type polyoxometalates. J Mater Chem 12:3046–3052CrossRef

60.

Guo Y, Hu C, Jiang S, Guo C, Yang Y, Wang E (2002) Heterogeneous photodegradation of aqueous hydroxy butanedioic acid by microporous polyoxometalates. Appl Catal B 36:9–17CrossRef

61.

Guo Y, Hu C, Jiang C, Yang Y, Jiang S, Li X, Wang E (2003) Preparation and heterogeneous photocatalytic behaviors of the surface-modified porous silica materials impregnated with monosubstituted keggin units. J Catal 217:141–151

62.

Winter RS, Cameron JM, Cronin L (2014) Controlling the minimal self assembly of “complex” polyoxometalate clusters. J Am Chem Soc 136:12753–12761CrossRef

63.

Shen H, Mao H, Ying L, Xi Q (2007) Photocatalytic selective aerobic oxidation of alcohols to aldehydes and ketones by HPW/MCM-41 in ionic liquids. J Mol Catal A 276:73–79CrossRef

64.

Feng C, Li Y, Liu X (2012) Photocatalytic degradation of imidacloprid by phosphotungstic acid supported on a mesoporous sieve MCM-41. Chin J Chem 30:127–132CrossRef

65.

Tao S, Wang Y, Yu Y, An Y, Shi W (2013) Hierarchically porous tungstophosphoric acid/silica hybrid for high performance vis-light photocatalysis. J Environ Chem Eng 1:719–727

66.

Kim S, Choi W (2005) Visible-light-induced photocatalytic degradation of 4-chlorophenol and phenolic compounds in aqueous suspension of pure titania: demonstrating the existence of a surface-complex-mediated path. J Phys Chem B 109:5143–5149CrossRef

67.

Rochkind M, Pasternak S, Paz Y (2015) Using dyes for evaluating photocatalytic properties: a critical review. Molecules 20:88–110CrossRef

68.

Zhao L, Chi Y, Yuan Q, Li N, Yan W, Li X (2013) Phosphotungstic acid anchored to amino-functionalized core-shell magnetic mesoporous silica microspheres: a magnetically recoverable nanocomposite with enhanced photocatalytic activity. J Colloid Interface Sci 390:70–77CrossRef

69.

Li H, Gao S, Cao M, Cao R (2013) Self-assembly of polyoxometalate–thionine multilayer films on magnetic microspheres as photocatalyst for methyl orange degradation under visible light irradiation. J Colloid Interface Sci 394:434–440CrossRef

70.

Gamelas JAF, Evtyugina MG, Portugal I, Evtug DV (2012) New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications. RSC Adv 2:831–839CrossRef

71.

Ozer RR, Ferry JL (2002) Photocatalytic Oxidation of Aqueous 1,2-Dichlorobenzene by Polyoxometalates Supported on the NaY Zeolite. J Phys Chem B 106:4336–4342

72.

Leal Marchena C, Frenzel RA, Gomez S, Pierella LB, Pizzio LR (2013) Tungstophosphoric acid immobilized on ammonium Y and ZSM5 zeolites: Synthesis, characterization and catalytic evaluation. Appl Catal B 130–131:187–196

73.

Li S, Yu X, Zhang G, Ma Y, Yao J, Keita B, Nadjo L, Zhao H (2011) Green chemical decoration of multiwalled carbon nanotubes with polyoxometalate-encapsulated gold nanoparticles: visible light photocatalytic activities. J Mater Chem 21:2282–2287CrossRef

74.

Marcì G, García-López E, Bellardita M, Parisi F, Colbeau-Justin C, Sorgues S, Liotta LF, Palmisano L (2013) Keggin heteropolyacid H₃PW₁₂O₄₀ supported on different oxides for catalytic and catalytic photo-assisted propene hydration. Phys Chem Chem Phys 15:13329–13342CrossRef

75.

Marcì G, García-López EI, Palmisano L (2014) Heteropolyacid-based materials as heterogeneous photocatalysts. Eur J Inorg Chem 2014:21–35CrossRef

76.

Weinstock IA (1998) Homogeneous-phase electron-transfer reactions of polyoxometalates. Chem Rev 98:113–170CrossRef

77.

Dimitrievic NM, Savic D, Micic OI, Nozik AJ (1984) Interfacial electron-transfer equilibria and flatband potentials of alpha-ferric oxide and titanium dioxide colloids studied by pulse radiolysis. J Phys Chem 88:4278–4283CrossRef

78.

Yoon M, Chang JA, Kim Y, Choi JR, Kim K, Lee SJ (2001) Heteropoly acid-incorporated TiO₂ colloids as novel photocatalytic systems resembling the photosynthetic reaction center. J Phys Chem B 105:2539–2545CrossRef

79.

Tachikawa T, Fujitsuka M, Majima T (2007) Mechanistic insight into the TiO₂ photocatalytic reactions: design of new photocatalysts. J Phys Chem C 111:5259–5275CrossRef

80.

Tachikawa T, Tojo S, Fujitsuka M, Majima T (2006) One-electron redox processes during polyoxometalate-mediated photocatalytic reactions of TiO₂ studied by two-color two-laser flash photolysis. Chem Eur J 12:3124–3131CrossRef

81.

Ozer RR, Ferry JL (2001) Investigation of the photocatalytic activity of TiO₂-polyoxometalate systems. Environ Sci Technol 35:3242–3246CrossRef

82.

Akid R, Darwent JR (1985) Heteropolytungstates as catalysts for the photochemical reduction of oxygen and water. J Chem Soc Dalton Trans 395–399

83.

Renneke RF, Pasquali M, Hill CL (1990) Polyoxometalate systems for the catalytic selective production of nonthermodynamic alkenes from alkanes. Nature of excited-state deactivation processes and control of subsequent thermal processes in polyoxometalate photoredox chemistry. J Am Chem Soc 112:6585–6594CrossRef

84.

Chen C, Lei P, Ji H, Ma W, Zhao J, Hidaka H, Serpone N (2004) Photocatalysis by titanium dioxide and polyoxometalate/TiO₂ cocatalysts. Intermediates and mechanistic study. Environ Sci Technol 38:329–337CrossRef

85.

Yang Y, Wu Q, Guo Y, Hu C, Wang E (2005) Efficient degradation of dye pollutants on nanoporous polyoxotungstate–anatase composite under visible-light irradiation. J Mol Catal A 225:203–212CrossRef

86.

Li L, Wu Q, Guo Y, Hu C (2005) Nanosize and bimodal porous polyoxotungstate–anatase TiO₂ composites: preparation and photocatalytic degradation of organophosphorus pesticide using visible-light excitation. Microp Mesop Mater 87:1–9CrossRef

87.

Jin H, Wu Q, Pang W (2007) Photocatalytic degradation of textile dye X-3B using polyoxometalate-TiO₂ hybrid materials. J Hazard Mater 141:123–127CrossRef

88.

Yu X, Guo Y, Xu L, Yang X, Guo Y (2008) A novel preparation of mesoporous Cs_xH_3-xPW₁₂O₄₀/TiO₂ nanocomposites with enhanced photocatalytic activity. Colloids Surf A 316:110–118CrossRef

89.

Li J, Kang W, Yang X, Yu X, Xu L, Guo Y, Fang H, Zhang S (2010) Mesoporous titania-based H₃PW₁₂O₄₀ composite by a block copolymer surfactant-assisted templating route: preparation, characterization, and heterogeneous photocatalytic properties. Desalination 255:107–116CrossRef

90.

Xu L, Yang X, Guo Y, Ma F, Guo Y, Yuan X, Huo M (2010) Simulated sunlight photodegradation of aqueous phthalate esters catalyzed by the polyoxotungstate/titania nanocomposite. J Hazard Mater 178:1070–1077CrossRef

91.

Ma F, Shi T, Gao J, Chen L, Guo W, Guo Y, Wang S (2012) Comparison and understanding of the different simulated sunlight photocatalytic activity between the saturated and monovacant Keggin unit functionalized titania materials. Colloid Surf A 401:116–125CrossRef

92.

Proust A, Matt B, Villanneau R, Guillemot G, Gouzerh P, Izzet G (2012) Functionalization and post-functionalization: a step towards polyoxometalate-based materials. Chem Soc Rev 41:7605–7622CrossRef

93.

Lv K, Xu Y (2006) Effects of polyoxometalate and fluoride on adsorption and photocatalytic degradation of organic dye X3B on TiO₂: the difference in the production of reactive species. J Phys Chem B 110:6204–6212CrossRef

94.

Rengifo-Herrera JA, Blanco MN, Pizzio LR (2011) Photocatalytic bleaching of aqueous malachite green solutions by UV-A and blue-light-illuminated TiO₂ spherical nanoparticles modified with tungstophosphoric acid. Appl Catal B 110:126–132CrossRef

95.

Rengifo-Herrera JA, Pizzio LR, Blanco MN, Roussel C, Pulgarin C (2011) Photocatalytic discoloration of aqueous malachite green solutions by UV-illuminated TiO₂ nanoparticles under air and nitrogen atmospheres: effects of counter-ions and pH. Photochem Photobiol Sci 10:29–34CrossRef

96.

Blanco MN, Pizzio LR (2011) Influence of the thermal treatment on the physicochemical properties and photocatalytic degradation of 4-chlorophenol in aqueous solutions with tungstophosphoric acid-modified mesoporous titania. Appl Catal A 405:69–78CrossRef

97.

Ngo Biboum R, Nanseu Njiki CP, Zhang G, Kortz U, Mialane P, Dolbecq A, Mbomekalle IM, Nadjo L, Keita B (2011) High nuclearity Ni/Co polyoxometalates and colloidal TiO₂ assemblies as efficient multielectron photocatalysts under visible or sunlight irradiation. J Mater Chem 21:645–650CrossRef

98.

Lee H, Lee J, Lee YH, Lee J, Yoon M (2011) Formation of Ag⁺-N-TiO₂ nanochains and their HPA-composites as highly visible light-sensitive photocatalysts toward two-color solar cells. J Mater Chem 221:12829–12835CrossRef

99.

Shi H, Zhang T, An T, Li B, Wang X (2012) Enhancement of photocatalytic activity of nano-scale TiO₂ particles co-doped by rare earth elements and heteropolyacids. J Colloid Interf Sci 380:121–127CrossRef

100.

Wu D, Huo P, Lu Z, Gao X, Liu X, Shi W, Yan Y (2012) Preparation of heteropolyacid/TiO₂/fly-ash-cenosphere photocatalyst for the degradation of ciprofloxacin from aqueous solutions. Appl Surf Sci 258:7008–7015CrossRef

101.

Feng C, Xu G, Liu X (2013) Photocatalytic degradation of imidacloprid by composite catalysts H₃PW₁₂O₄₀/La-TiO₂. J Rare Earths 31:41–48

102.

Anandan S, Ryu S, Cho W, Yoon M (2003) Heteropolytungstic acid (H₃PW₁₂O₄₀)-encapsulated into the titanium-exchanged HY (TiHY) zeolite: a novel photocatalyst for photoreduction of methyl orange. J Mol Catal A 195:201–208CrossRef

103.

Dubey N, Rayalu SS, Labhsetwar NK, Naidu RR, Chatti RV, Devotta S (2006) Photocatalytic properties of zeolite-based materials for the photoreduction of methyl orange. Appl Catal A 303:152–157CrossRef

104.

Chatti R, Rayalu SS, Dubey N, Labhsetwar N, Devotta S (2007) Solar-based photoreduction of methyl orange using zeolite supported photocatalytic materials. Sol Energy Mater Sol Cells 91:180–190CrossRef

105.

Rengifo-Herrera JA, Blanco MN, Pizzio LR (2014) Visible light absorption of TiO₂ materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO₂ surfaces. Mater Res Bull 49:618–624CrossRef

106.

Rengifo-Herrera JA, Frenzel RA, Blanco MN, Pizzio LR (2014) Visible-light-absorbing mesoporous TiO₂ modified with tungstosilicic acid as photocatalyst in the photodegradation of 4-chlorophenol. J Photochem Photobiol A 289:22–30CrossRef

107.

Feng C, Shang H, Liu X (2014) Photocatalysis of dinitrotoluene decomposition by H₃PW₁₂O₄₀/TiO₂ and H₄SiW₁₂O₄₀/TiO₂ prepared by a modified sol‐gel synthesis and solvothermal treatment method. Chin J Catal 35:168–174CrossRef

108.

Wang Y, Lu K, Feng C (2013) Influence of inorganic anions and organic additives on photocatalytic degradation of methyl orange with supported polyoxometalates as photocatalyst. J Rare Earths 31:360–365CrossRef

109.

de Souza Lourenc RER, Passoni LC, Canela MC (2014) The synergistic effect of TiO₂ and H₅PW₁₀V₂O₄₀ in photocatalysis as a function of the irradiation source. J Mol Catal A 392:284–289CrossRef

110.

Lu L, Li L, Hu T, Zhang W, Huang X, Zhang J, Liu X (2014) Preparation, characterization, and photocatalytic activity of three-dimensionally ordered macroporous hybrid monosubstituted polyoxometalate K₅[Co(H₂O)PW₁₁O₃₉] amine functionalized titanium catalysts. J Mol Catal A 394:283–294CrossRef

111.

Navio A, Hidalgo MC, Colón G, Botta SG, Litter M (2001) Preparation and physicochemical properties of ZrO₂ and Fe/ZrO₂ prepared by a sol-gel technique. Langmuir 17:202–210CrossRef

112.

Qu X, Guo Y, Hu C (2007) Preparation and heterogeneous photocatalytic activity of mesoporous H₃PW₁₂O₄₀/ZrO₂ composites. J Mol Catal A 262:128–135CrossRef

113.

Jiang C, Guo Y, Hu C, Wang C, Li D (2004) Photocatalytic degradation of dye naphthol blue black in the presence of zirconia-supported Ti-substituted Keggin-type polyoxometalates. Mater Res Bull 39:251–257CrossRef

114.

Farhadi S, Zaidi M (2009) Polyoxometalate-zirconia (POM/ZrO₂) nanocomposite prepared by sol-gel process: a green and recyclable photocatalyst for efficient and selective aerobic oxidation of alcohols into aldehydes and ketones. Appl Catal A 354:119–126CrossRef

115.

Salavati H, Tavakkoli N, Hosseinpoor M (2012) Preparation and characterization of polyphosphotungstate/ZrO₂ nanocomposite and their sonocatalytic and photocatalytic activity under UV light. Ultrason Sonochem 19:546–553CrossRef

116.

Sayama K, Arakawa H (1994) Effect of Na₂CO₃ addition on photocatalytic decomposition of liquid water over various semiconductor catalysis. J Photochem Photobiol A 77:243–247CrossRef

117.

Murase T, Irie H, Hashimoto K (2004) Visible light sensitive photocatalysts, nitrogen-doped Ta₂O₅ powders. J Phys Chem B 108:15803–15807CrossRef

118.

Jiang S, Guo Y, Wang C, Qu X, Li L (2007) One-step sol–gel preparation and enhanced photocatalytic activity of porous polyoxometalate–tantalum pentoxide nanocomposites. J Colloid Interf Sci 308:208–215CrossRef

119.

Su FZ, Mathew SC, Lipner G, Fu XZ, Antonietti M, Blechert S, Wang XC (2010) mpg-C₃N₄-catalyzed selective oxidation of alcohols using O₂ and visible light. J Am Chem Soc 132:16299–16301CrossRef

120.

Jun YS, Park J, Lee SU, Thomas A, Hong WH, Stucky GD (2013) Three-dimensional macroscopic assemblies of low-dimensional carbon nitrides for enhanced hydrogen evolution. Angew Chem 125:11289–11293CrossRef

121.

Niu P, Zhang L, Liu G, Cheng H (2012) Graphene-like carbon nitride nanosheets for improved photocatalytic activities. Adv Funct Mater 224:763–4770

122.

Lin Z, Wang X (2013) Nanostructure engineering and doping of conjugated carbon nitride semiconductors for hydrogen photosynthesis. Angew Chem 125:1779–1782CrossRef

123.

Li K, Yan L, Zeng Z, Luo S, Luo X, Liu X, Guo H, Guo Y (2014) Fabrication of H3PW12O40-doped carbon nitride nanotubes by one-step hydrothermal treatment strategy and their efficient visible-light photocatalytic activity toward representative aqueous persistent organic pollutants degradation. Appl Catal B 156–157:141–152CrossRef

124.

Xing X, Liu R, Yu X, Zhang G, Cao H, Yao J, Ren B, Jiang Z, Zhao H (2012) Self-assembly of CdS quantum dots with polyoxometalate encapsulated gold nanoparticles: enhanced photocatalytic activities. J Mater Chem A 1:1488–1494CrossRef

125.

Kornarakis I, Lykakis IN, Vordos N, Armatas GS (2014) Efficient visible-light photocatalytic activity by band alignment in mesoporous ternary polyoxometalate-Ag₂S-CdS semiconductors. Nanoscale 6:8694–8703CrossRef

126.

Bian ZY, Zhu YQ, Zhang JX, Ding AZ, Wang H (2014) Visible-light driven degradation of ibuprofen using abundant metal-loaded BiVO₄ photocatalysts. Chemosphere 117:527–531CrossRef

127.

Zhang J, Li C, Wang B, Cui H, Zhai J, Li Q (2013) Synthesis, characterization and photocatalytic application of H3PW12O40/BiVO4 composite photocatalyst. Sci China Chem 56:1285–1292CrossRef

128.

Cao M, Lin J, Lu J, You Y, Liu T, Cao R (2011) Development of a polyoxometalate-based photocatalyst assembled with cucurbit[6]uril via hydrogen bonds for azo dyes degradation. J Hazard Mater 186:948–951CrossRef

129.

You Y, Gao S, Yang Z, Cao M, Cao R (2012) Facile synthesis of polyoxometalate–thionine composite via direct precipitation method and its photocatalytic activity for degradation of rhodamine B under visible light. J Colloid Interface Sci 365:198–203CrossRef

130.

Bonchio M, Carraro M, Scorrano G, Bagno A (2004) Photooxidation in water by new hybrid molecular photocatalysts integrating an organic sensitizer with a polyoxometalate core. Adv Synth Catal 346:648–654CrossRef

131.

Zhou W, Cao M, Li N, Su S, Zhao X, Wang J, Li X, Hu C (2013) Ag@AgHPW as a plasmonic catalyst for visible-light photocatalytic degradation of environmentally harmful organic pollutants. Mater Res Bull 48:2308–2316CrossRef

132.

Zhou W, Cao M, Su S, Li N, Zhao X, Wang J, Li X, Hu C (2013) A newly-designed polyoxometalate-based plasmonic visible-light catalyst for the photodegradation of methyl blue. J Mol Catal A 371:70–76CrossRef

133.

Corma A, García H, Llabrés i Xamena FX (2010) Engineering metal organic frameworks for heterogeneous catalysis. Chem Rev 110:4606–4655CrossRef

134.

An HY, Xiao DR, Wang EB, Li YGY, Wang XL, Xu L (2005) Open-framework polar compounds: synthesis and characterization of rare-earth polyoxometalates (C₆NO₂H₅)₂[Ln(H₂O)₅(CrMo₆H₆O₂₄)]·0.5H₂O (Ln = Ce and La). Eur J Inorg Chem 2005:854–859

135.

Sun CY, Liu SX, Liang DD, Shao KZ, Ren YH, Su ZM (2009) Highly stable crystalline catalysts based on a microporous metal-organic framework and polyoxometalates. J Am Chem Soc 131:1883–1888CrossRef

136.

Maksimchuk NV, Timofeeva MN, Melgunov MS, Shmakov AN, Chesalov YA, Dybtsev DN, Fedin VP, Kholdeeva OA (2008) Heterogeneous selective oxidation catalysts based on coordination polymer MIL-101 and transition metal-substituted polyoxometalates. J Catal 257:315–323CrossRef

137.

Dolbecq A, Dumas E, Mayer CR, Mialane P (2010) Hybrid organic-inorganic polyoxometalate compounds: from structural diversity to applications. Chem Rev 110:6009–6048CrossRef

138.

Marrot J, Mellot-Draznieks C, O’Keeffe M, Biboum RN, Lemaire J, Keita B, Nadjo L, Dolbecq A (2011) Polyoxometalate-Based Metal Organic Frameworks (POMOFs): structural trends, energetics, and high electrocatalytic efficiency for hydrogen evolution reaction. J Am Chem Soc 133:13363–13374CrossRef

139.

Zhu W, Yang XY, Li YH, Li JP, Wu D, Gao Y, Yi FY (2014) A novel porous molybdophosphate-based FeII,III-MOF showing selective dye degradation as a recyclable photocatalyst. Inorg Chem Commun 49:159–162

140.

Guo J, Yang J, Liu Y, Ma J (2013) Two new polyoxometalate-templated supramolecular compounds constructed by a new tridentate ligand 2,4,6-tris[1-(4-oxidroxypyridinium)-ylmethyl]-mesitylene. Inorg Chim Acta 400:51–58CrossRef

141.

Liu B, Yang J, Yang G, Ma J (2013) Four new three-dimensional polyoxometalate-based metal-organic frameworks constructed from [Mo₆O₁₈(O₃AsPh)₂]⁴⁻ polyoxoanions and copper(I)-organic fragments: syntheses, structures, electrochemistry, and photocatalysis properties. Inorg Chem 52:84–94CrossRef

142.

Meng B, You W, Sun X, Zhang F, Liu M (2011) A hydrotalcitelike Ce(III) coordination polymer pillared by Keggin anions: Synthesis, single crystal structure and photocatalysis. Inorg Chem Commun 14:35–37

143.

Ngo Biboum R, Doungmene R, Keita B, Oliveira P, Nadjo L, Lepoittevin B, Roger P, Brisset F, Mialane P, Dolbecq A, Mbomekalle IM, Pichon C, Yin P, Liu T, Contant R (2012) Poly(ionic liquid) and macrocyclic polyoxometalate ionic self-assemblies: new water-insoluble and visible light photosensitive catalysts. J Mater Chem 22:319–323CrossRef

144.

Fu Z, Zeng Y, Liu X, Song D, Liao S, Dai J (2012) Copper based metal-organic molecular ring with inserted Keggin-type polyoxometalate: a stable photofunctional host-guest molecular system. Chem Commun 48:6154–6156CrossRef

145.

Li T, Li Q, Yan J, Li F (2014) Photocatalytic degradation of organic dyes by La³⁺/Ce³⁺-H₃PW₁₂O₄₀ under different light irradiation. Dalton Trans 43:9061–9069CrossRef

146.

Xue C, Li S, Zhang L, Sha J, Zheng T, Zhang Q, Li L (2013) Hydrothermal synthesis, characterization and electrocatalytic/photocatalytic activities of new polyoxometalate based hybrid compound. J Inorg Organomet Polym 23:1468–1476CrossRef

147.

Sheng F, Zhu X, Wang W, Bai H, Liu J, Wang P, Zhang R, Han L, Mu J (2014) Synthesis of novel polyoxometalate K₆ZrW₁₁O₃₉Sn·12H₂O and photocatalytic degradation aqueous azo dye solutions with solar irradiation. J Mol Catal A 393:232–239CrossRef

148.

Zhou S, Liu B, Li X, Shi T, Chen Y (2014) Two new helical compounds based on Keggin clusters and N-donor multidentate ligand: syntheses, structures and properties. J Solid State Chem 219:15–20CrossRef

Titel: Heteropolyacid-Based Heterogeneous Photocatalysts for Environmental Application
verfasst von: Elisa I. García-López
Giuseppe Marcì
Leonardo Palmisano
Verlag: Springer Berlin Heidelberg
Buch: Heterogeneous Photocatalysis
Print ISBN: 978-3-662-48717-4

Electronic ISBN: 978-3-662-48719-8

Copyright-Jahr: 2016
DOI: https://doi.org/10.1007/978-3-662-48719-8_3

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