Skip to main content
Erschienen in: Journal of Materials Science 15/2019

06.05.2019 | Metals

High ductility induced by un-DRXed grains in a Mg–Zn–Mn–La–Ce alloy

verfasst von: Ke Hu, Qiyu Liao, Chunyu Li, Qichi Le, Weiyang Zhou, Chunlong Cheng, Shaochen Ning, Xingrui Chen, Fuxiao Yu

Erschienen in: Journal of Materials Science | Ausgabe 15/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

An approach of achieving high ductility as well as respectable high strength for low-Zn-containing wrought Mg alloy is presented in this paper. A low-cost and industry-compatible Mg–2Zn–0.3Mn–0.2La–0.1Ce alloy with highest yield strength (YS) of 289 MPa, ultimate tensile strength (UTS) of 300 MPa and excellent elongation (EL) of 32.7% is developed by traditional indirect extrusion. The microstructure and macro-textures of this alloy under various extrusion temperatures are characterized by OM, EBSD and XRD analysis. High quantity of dispersed elongated un-DRXed grains with various orientations form at relatively low extrusion temperatures, and many of them possess high basal Schmidt Factors (SFs) toward transverse directions. TEM analysis reveals a large number of networked dislocations passing through the deformation bands along transverse directions within the un-DRXed grains, which suggests the integral deformation (bending) is achievable by dislocation motion. It is believed that the high ductility along extrusion direction is induced by the bendable elongated un-DRXed grains during tensile deformation by embodying the easy-to-failure regions, preventing the subsequent generation of micro-cracks and accommodating the stress concentration.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Sabat RK, Mishra RK, Sachdev AK, Suwas S (2015) The deciding role of texture on ductility in a Ce containing Mg alloy. Mater Lett 153:158–161CrossRef Sabat RK, Mishra RK, Sachdev AK, Suwas S (2015) The deciding role of texture on ductility in a Ce containing Mg alloy. Mater Lett 153:158–161CrossRef
2.
Zurück zum Zitat Liu P, Jiang H, Cai Z, Kang Q, Zhang Y (2016) The effect of Y, Ce and Gd on texture, recrystallization and mechanical property of Mg–Zn alloys. J Magn Alloy 4(3):188–196CrossRef Liu P, Jiang H, Cai Z, Kang Q, Zhang Y (2016) The effect of Y, Ce and Gd on texture, recrystallization and mechanical property of Mg–Zn alloys. J Magn Alloy 4(3):188–196CrossRef
3.
Zurück zum Zitat Du YZ, Qiao XG, Zheng MY, Wu K, Xu SW (2015) Development of high-strength, low-cost wrought Mg–2.5mass% Zn alloy through micro-alloying with Ca and La. Mater Des 85:549–557CrossRef Du YZ, Qiao XG, Zheng MY, Wu K, Xu SW (2015) Development of high-strength, low-cost wrought Mg–2.5mass% Zn alloy through micro-alloying with Ca and La. Mater Des 85:549–557CrossRef
4.
Zurück zum Zitat Langelier B, Nasiri AM, Lee SY, Gharghouri MA, Esmaeili S (2015) Improving microstructure and ductility in the Mg–Zn alloy system by combinational Ce–Ca microalloying. Mater Sci Eng A 620:76–84CrossRef Langelier B, Nasiri AM, Lee SY, Gharghouri MA, Esmaeili S (2015) Improving microstructure and ductility in the Mg–Zn alloy system by combinational Ce–Ca microalloying. Mater Sci Eng A 620:76–84CrossRef
5.
Zurück zum Zitat Tong LB, Zhang QX, Jiang ZH, Zhang JB, Meng J, Cheng LR, Zhang HJ (2016) Microstructures, mechanical properties and corrosion resistances of extruded Mg–Zn–Ca–xCe/La alloys. J Mech Behav Biomed 62:57–70CrossRef Tong LB, Zhang QX, Jiang ZH, Zhang JB, Meng J, Cheng LR, Zhang HJ (2016) Microstructures, mechanical properties and corrosion resistances of extruded Mg–Zn–Ca–xCe/La alloys. J Mech Behav Biomed 62:57–70CrossRef
6.
Zurück zum Zitat Park SH, You BS, Mishra RK, Sachdev AK (2014) Effects of extrusion parameters on the microstructure and mechanical properties of Mg–Zn–(Mn)–Ce/Gd alloys. Mater Sci Eng A 598:396–406CrossRef Park SH, You BS, Mishra RK, Sachdev AK (2014) Effects of extrusion parameters on the microstructure and mechanical properties of Mg–Zn–(Mn)–Ce/Gd alloys. Mater Sci Eng A 598:396–406CrossRef
7.
Zurück zum Zitat Zhang BP, Geng L, Huang LJ, Zhang XX, Dong CC (2010) Enhanced mechanical properties in fine-grained Mg–1.0Zn–0.5Ca alloys prepared by extrusion at different temperatures. Scr Mater 63(10):1024–1027CrossRef Zhang BP, Geng L, Huang LJ, Zhang XX, Dong CC (2010) Enhanced mechanical properties in fine-grained Mg–1.0Zn–0.5Ca alloys prepared by extrusion at different temperatures. Scr Mater 63(10):1024–1027CrossRef
8.
Zurück zum Zitat Gupta M, Sharon NML (2011) Magnesium, magnesium alloys, and magnesium composites. John Wiley & Sons, Inc., Hoboken, New JerseyCrossRef Gupta M, Sharon NML (2011) Magnesium, magnesium alloys, and magnesium composites. John Wiley & Sons, Inc., Hoboken, New JerseyCrossRef
9.
Zurück zum Zitat She Q, Yan H, Chen J, Su B, Yu Z, Chen C, Xia W (2017) Microstructure characteristics and liquation behavior of fiber laser welded joints of Mg-5Zn-1Mn-0.6Sn alloy sheets. Trans Nonferr Metal Soc 27(4):812–819CrossRef She Q, Yan H, Chen J, Su B, Yu Z, Chen C, Xia W (2017) Microstructure characteristics and liquation behavior of fiber laser welded joints of Mg-5Zn-1Mn-0.6Sn alloy sheets. Trans Nonferr Metal Soc 27(4):812–819CrossRef
10.
Zurück zum Zitat Bohlen J, Nürnberg MR, Senn JW, Letzig D, Agnew SR (2007) The texture and anisotropy of magnesium–zinc–rare earth alloy sheets. Acta Mater 55(6):2101–2112CrossRef Bohlen J, Nürnberg MR, Senn JW, Letzig D, Agnew SR (2007) The texture and anisotropy of magnesium–zinc–rare earth alloy sheets. Acta Mater 55(6):2101–2112CrossRef
11.
Zurück zum Zitat Somekawa H, Mukai T (2007) High strength and fracture toughness balance on the extruded Mg–Ca–Zn alloy. Mater Sci Eng A 459(1):366–370CrossRef Somekawa H, Mukai T (2007) High strength and fracture toughness balance on the extruded Mg–Ca–Zn alloy. Mater Sci Eng A 459(1):366–370CrossRef
12.
Zurück zum Zitat Bu F, Yang Q, Guan K, Qiu X, Zhang D, Sun W, Zheng T, Cui X, Sun S, Tang Z, Liu X, Meng J (2016) Study on the mutual effect of La and Gd on microstructure and mechanical properties of Mg-Al-Zn extruded alloy. J Alloy Compd 688:1241–1250CrossRef Bu F, Yang Q, Guan K, Qiu X, Zhang D, Sun W, Zheng T, Cui X, Sun S, Tang Z, Liu X, Meng J (2016) Study on the mutual effect of La and Gd on microstructure and mechanical properties of Mg-Al-Zn extruded alloy. J Alloy Compd 688:1241–1250CrossRef
13.
Zurück zum Zitat Jeong HY, Kim B, Kim SG, Kim HJ, Park SS (2014) Effect of Ce addition on the microstructure and tensile properties of extruded Mg–Zn–Zr alloys. Mater Sci Eng A 612:217–222CrossRef Jeong HY, Kim B, Kim SG, Kim HJ, Park SS (2014) Effect of Ce addition on the microstructure and tensile properties of extruded Mg–Zn–Zr alloys. Mater Sci Eng A 612:217–222CrossRef
14.
Zurück zum Zitat Tong LB, Zhang JB, Zhang QX, Jiang ZH, Xu C, Kamado S, Zhang DP, Meng J, Cheng LR, Zhang HJ (2016) Effect of warm rolling on the microstructure, texture and mechanical properties of extruded Mg–Zn–Ca–Ce/La alloy. Mater Charact 115:1–7CrossRef Tong LB, Zhang JB, Zhang QX, Jiang ZH, Xu C, Kamado S, Zhang DP, Meng J, Cheng LR, Zhang HJ (2016) Effect of warm rolling on the microstructure, texture and mechanical properties of extruded Mg–Zn–Ca–Ce/La alloy. Mater Charact 115:1–7CrossRef
15.
Zurück zum Zitat Yu H, Kim YM, You BS, Yu HS, Park SH (2013) Effects of cerium addition on the microstructure, mechanical properties and hot workability of ZK60 alloy. Mater Sci Eng A 559:798–807CrossRef Yu H, Kim YM, You BS, Yu HS, Park SH (2013) Effects of cerium addition on the microstructure, mechanical properties and hot workability of ZK60 alloy. Mater Sci Eng A 559:798–807CrossRef
16.
Zurück zum Zitat Medina J, Pérez P, Garcés G, Adeva P (2017) Effects of calcium, manganese and cerium-rich mischmetal additions on the mechanical properties of extruded Mg-Zn-Y alloy reinforced by quasicrystalline I-phase. Mater Charact 129:195–206CrossRef Medina J, Pérez P, Garcés G, Adeva P (2017) Effects of calcium, manganese and cerium-rich mischmetal additions on the mechanical properties of extruded Mg-Zn-Y alloy reinforced by quasicrystalline I-phase. Mater Charact 129:195–206CrossRef
17.
Zurück zum Zitat Zengin H, Turen Y (2018) Effect of La content and extrusion temperature on microstructure, texture and mechanical properties of Mg-Zn-Zr magnesium alloy. Mater Chem Phys 214:421–430CrossRef Zengin H, Turen Y (2018) Effect of La content and extrusion temperature on microstructure, texture and mechanical properties of Mg-Zn-Zr magnesium alloy. Mater Chem Phys 214:421–430CrossRef
18.
Zurück zum Zitat Ke H, Chunyu L, Guojun X, Ruizhen G, Qichi L, Qiyu L (2019) Effect of extrusion temperature on the microstructure and mechanical properties of low Zn containing wrought Mg alloy micro-alloying with Mn and La-rich misch metal. Mater Sci Eng A. 742:692–703 Ke H, Chunyu L, Guojun X, Ruizhen G, Qichi L, Qiyu L (2019) Effect of extrusion temperature on the microstructure and mechanical properties of low Zn containing wrought Mg alloy micro-alloying with Mn and La-rich misch metal. Mater Sci Eng A. 742:692–703
19.
Zurück zum Zitat Koike J (2005) Enhanced deformation mechanisms by anisotropic plasticity in polycrystalline Mg alloys at room temperature. Metall Mater Trans A 36(7):1689–1696CrossRef Koike J (2005) Enhanced deformation mechanisms by anisotropic plasticity in polycrystalline Mg alloys at room temperature. Metall Mater Trans A 36(7):1689–1696CrossRef
20.
Zurück zum Zitat Rong W, Zhang Y, Wu Y, Chen Y, Sun M, Chen J, Peng L (2019) The role of bimodal-grained structure in strengthening tensile strength and decreasing yield asymmetry of Mg-Gd-Zn-Zr alloys. Mater Sci Eng A 740–741:262–273CrossRef Rong W, Zhang Y, Wu Y, Chen Y, Sun M, Chen J, Peng L (2019) The role of bimodal-grained structure in strengthening tensile strength and decreasing yield asymmetry of Mg-Gd-Zn-Zr alloys. Mater Sci Eng A 740–741:262–273CrossRef
21.
Zurück zum Zitat Homma T, Hinata J, Kamado S (2012) Development of an extruded Mg–Zn–Ca-based alloy: new insight on the role of Mn addition in precipitation. Philos Mag 92(12):1569–1582CrossRef Homma T, Hinata J, Kamado S (2012) Development of an extruded Mg–Zn–Ca-based alloy: new insight on the role of Mn addition in precipitation. Philos Mag 92(12):1569–1582CrossRef
22.
Zurück zum Zitat Wang J-Y, Saufan A, Lin PH, Bor HY, Lee S, Kawamura Y (2014) Mechanical properties and strengthening behavior of Mg–Zn–MM alloy. Mater Chem Phys 148(1):28–31CrossRef Wang J-Y, Saufan A, Lin PH, Bor HY, Lee S, Kawamura Y (2014) Mechanical properties and strengthening behavior of Mg–Zn–MM alloy. Mater Chem Phys 148(1):28–31CrossRef
23.
Zurück zum Zitat Huang ML, Li HX, Ding H, Ren YP, Hao SM (2008) Isothermal section of Mg-Zn-La system in Mg rich corner at 350°C. Acta Metall Sin-Engl 21(5):329–335CrossRef Huang ML, Li HX, Ding H, Ren YP, Hao SM (2008) Isothermal section of Mg-Zn-La system in Mg rich corner at 350°C. Acta Metall Sin-Engl 21(5):329–335CrossRef
24.
Zurück zum Zitat Basu I, Al-Samman T (2015) Twin recrystallization mechanisms in magnesium-rare earth alloys. Acta Mater 96:111–132CrossRef Basu I, Al-Samman T (2015) Twin recrystallization mechanisms in magnesium-rare earth alloys. Acta Mater 96:111–132CrossRef
25.
Zurück zum Zitat Pan H, Yang C, Yang Y, Dai Y, Zhou D, Chai L, Huang Q, Yang Q, Liu S, Ren Y, Qin G (2019) Ultra-fine grain size and exceptionally high strength in dilute Mg–Ca alloys achieved by conventional one-step extrusion. Mater Lett 237:65–68CrossRef Pan H, Yang C, Yang Y, Dai Y, Zhou D, Chai L, Huang Q, Yang Q, Liu S, Ren Y, Qin G (2019) Ultra-fine grain size and exceptionally high strength in dilute Mg–Ca alloys achieved by conventional one-step extrusion. Mater Lett 237:65–68CrossRef
26.
Zurück zum Zitat Chino Y, Kado M, Mabuchi M (2008) Compressive deformation behavior at room temperature – 773K in Mg–0.2mass% (0.035at.%)Ce alloy. Acta Mater 56(3):387–394CrossRef Chino Y, Kado M, Mabuchi M (2008) Compressive deformation behavior at room temperature – 773K in Mg–0.2mass% (0.035at.%)Ce alloy. Acta Mater 56(3):387–394CrossRef
27.
Zurück zum Zitat Jiang MG, Xu C, Nakata T, Yan H, Chen RS, Kamado S (2017) Enhancing strength and ductility of Mg-Zn-Gd alloy via slow-speed extrusion combined with pre-forging. J Alloy Compd 694:1214–1223CrossRef Jiang MG, Xu C, Nakata T, Yan H, Chen RS, Kamado S (2017) Enhancing strength and ductility of Mg-Zn-Gd alloy via slow-speed extrusion combined with pre-forging. J Alloy Compd 694:1214–1223CrossRef
28.
Zurück zum Zitat Kim S-H, Bae SW, Lee SW, Moon BG, Kim HS, Kim YM, Yoon J, Park SH (2018) Microstructural evolution and improvement in mechanical properties of extruded AZ31 alloy by combined addition of Ca and Y. Mater Sci Eng A 725:309–318CrossRef Kim S-H, Bae SW, Lee SW, Moon BG, Kim HS, Kim YM, Yoon J, Park SH (2018) Microstructural evolution and improvement in mechanical properties of extruded AZ31 alloy by combined addition of Ca and Y. Mater Sci Eng A 725:309–318CrossRef
29.
Zurück zum Zitat Jiang MG, Xu C, Nakata T, Yan H, Chen RS, Kamado S (2016) Rare earth texture and improved ductility in a Mg-Zn-Gd alloy after high-speed extrusion. Mater Sci Eng A 667:233–239CrossRef Jiang MG, Xu C, Nakata T, Yan H, Chen RS, Kamado S (2016) Rare earth texture and improved ductility in a Mg-Zn-Gd alloy after high-speed extrusion. Mater Sci Eng A 667:233–239CrossRef
30.
Zurück zum Zitat Bohlen J, Yi S, Letzig D, Kainer KU (2010) Effect of rare earth elements on the microstructure and texture development in magnesium–manganese alloys during extrusion. Mater Sci Eng A 527(26):7092–7098CrossRef Bohlen J, Yi S, Letzig D, Kainer KU (2010) Effect of rare earth elements on the microstructure and texture development in magnesium–manganese alloys during extrusion. Mater Sci Eng A 527(26):7092–7098CrossRef
31.
Zurück zum Zitat Brömmelhoff K, Huppmann M, Reimers W (2011) The effect of heat treatments on the microstructure, texture and mechanical properties of the extruded magnesium alloy ME21. Int J Mater Res 102(9):1133–1141CrossRef Brömmelhoff K, Huppmann M, Reimers W (2011) The effect of heat treatments on the microstructure, texture and mechanical properties of the extruded magnesium alloy ME21. Int J Mater Res 102(9):1133–1141CrossRef
32.
Zurück zum Zitat Luo AA, Mishra RK, Sachdev AK (2011) High-ductility magnesium–zinc–cerium extrusion alloys. Scr Mater 64(5):410–413CrossRef Luo AA, Mishra RK, Sachdev AK (2011) High-ductility magnesium–zinc–cerium extrusion alloys. Scr Mater 64(5):410–413CrossRef
33.
Zurück zum Zitat Gao L, Yan H, Luo J, Luo AA, Chen R (2013) Microstructure and mechanical properties of a high ductility Mg–Zn–Mn–Ce magnesium alloy. J Magn Alloy 1(4):283–291CrossRef Gao L, Yan H, Luo J, Luo AA, Chen R (2013) Microstructure and mechanical properties of a high ductility Mg–Zn–Mn–Ce magnesium alloy. J Magn Alloy 1(4):283–291CrossRef
34.
Zurück zum Zitat Kim D-W, Suh B-C, Shim M-S, Bae JH, Kim DH, Kim NJ (2013) Texture evolution in Mg-Zn-Ca alloy sheets. Metall Mater Trans A 44(7):2950–2961CrossRef Kim D-W, Suh B-C, Shim M-S, Bae JH, Kim DH, Kim NJ (2013) Texture evolution in Mg-Zn-Ca alloy sheets. Metall Mater Trans A 44(7):2950–2961CrossRef
35.
Zurück zum Zitat Liu L, Chen X, Pan F, Gao S, Zhao C (2016) A new high-strength Mg-Zn-Ce-Y-Zr magnesium alloy. J Alloy Compd 688:537–541CrossRef Liu L, Chen X, Pan F, Gao S, Zhao C (2016) A new high-strength Mg-Zn-Ce-Y-Zr magnesium alloy. J Alloy Compd 688:537–541CrossRef
36.
Zurück zum Zitat Jäger A, Gärtnerová V, Mukai T (2014) Micromechanisms of grain refinement during extrusion of Mg–0.3at.% Al at low homologous temperature. Mater Charact 93:102–109CrossRef Jäger A, Gärtnerová V, Mukai T (2014) Micromechanisms of grain refinement during extrusion of Mg–0.3at.% Al at low homologous temperature. Mater Charact 93:102–109CrossRef
37.
Zurück zum Zitat Pan F, Mao J, Zhang G, Tang A, She J (2016) Development of high-strength, low-cost wrought Mg–2.0mass% Zn alloy with high Mn content. Prog Nat Sci: Mater Int 26(6):630–635CrossRef Pan F, Mao J, Zhang G, Tang A, She J (2016) Development of high-strength, low-cost wrought Mg–2.0mass% Zn alloy with high Mn content. Prog Nat Sci: Mater Int 26(6):630–635CrossRef
38.
Zurück zum Zitat Pantleon W (2008) Resolving the geometrically necessary dislocation content by conventional electron backscattering diffraction. Scr Mater 58(11):994–997CrossRef Pantleon W (2008) Resolving the geometrically necessary dislocation content by conventional electron backscattering diffraction. Scr Mater 58(11):994–997CrossRef
39.
Zurück zum Zitat Griffiths D (2015) in Robson J (ed) The School of Materials. PhD Thesis, The University of Manchester, Manchester, UK Griffiths D (2015) in Robson J (ed) The School of Materials. PhD Thesis, The University of Manchester, Manchester, UK
40.
Zurück zum Zitat Wang Q, Shen Y, Jiang B, Tang A, Song J, Jiang Z, Yang T, Huang G, Pan F (2018) A micro-alloyed Mg-Sn-Y alloy with high ductility at room temperature. Mater Sci Eng A 735:131–144CrossRef Wang Q, Shen Y, Jiang B, Tang A, Song J, Jiang Z, Yang T, Huang G, Pan F (2018) A micro-alloyed Mg-Sn-Y alloy with high ductility at room temperature. Mater Sci Eng A 735:131–144CrossRef
41.
Zurück zum Zitat Bohlen J, Yi SB, Swiostek J, Letzig D, Brokmeier HG, Kainer KU (2005) Microstructure and texture development during hydrostatic extrusion of magnesium alloy AZ31. Scr Mater 53(2):259–264CrossRef Bohlen J, Yi SB, Swiostek J, Letzig D, Brokmeier HG, Kainer KU (2005) Microstructure and texture development during hydrostatic extrusion of magnesium alloy AZ31. Scr Mater 53(2):259–264CrossRef
42.
Zurück zum Zitat Alaneme KK, Okotete EA (2017) Enhancing plastic deformability of Mg and its alloys—a review of traditional and nascent developments. J Magn Alloy 5(4):460–475CrossRef Alaneme KK, Okotete EA (2017) Enhancing plastic deformability of Mg and its alloys—a review of traditional and nascent developments. J Magn Alloy 5(4):460–475CrossRef
43.
Zurück zum Zitat Kim S-H, Jo W-K, Hong W-H, Kim W, Yoon J, Park SH (2017) Microstructural evolution of extruded AZ31 alloy with bimodal structure during compression. Mater Sci Eng A 702:1–9CrossRef Kim S-H, Jo W-K, Hong W-H, Kim W, Yoon J, Park SH (2017) Microstructural evolution of extruded AZ31 alloy with bimodal structure during compression. Mater Sci Eng A 702:1–9CrossRef
Metadaten
Titel
High ductility induced by un-DRXed grains in a Mg–Zn–Mn–La–Ce alloy
verfasst von
Ke Hu
Qiyu Liao
Chunyu Li
Qichi Le
Weiyang Zhou
Chunlong Cheng
Shaochen Ning
Xingrui Chen
Fuxiao Yu
Publikationsdatum
06.05.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 15/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03624-3

Weitere Artikel der Ausgabe 15/2019

Journal of Materials Science 15/2019 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.