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Topics in Catalysis
Erschienen in: Topics in Catalysis 4-6/2015

01.04.2015 | Original Paper

Higher Chemical Stability of α-Li3N than β-Li3N in Atmosphere

verfasst von: Junqing Zhang, Yun Hang Hu

Erschienen in: Topics in Catalysis | Ausgabe 4-6/2015

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Abstract

Lithium nitride (Li3N), which generally consists of α-Li3N and β-Li3N, is a promising material for catalysis and energy applications. It is generally recognized that Li3N can be easily oxidized by air at room temperature. However, herein, it was found that O2 can not oxidize Li3N even at 170 °C. In contrast, H2O in atmosphere can cause the degradation of Li3N due to its reaction with H2O to LiOH, followed by further reaction with CO2 to Li2CO3 at room temperature. Furthermore, it was revealed that H2O reacted with β-Li3N much faster than α-Li3N, indicating that α-Li3N is more stable than β-Li3N in atmosphere.
Vorheriger Artikel Synthesis and Properties of Al2O3@Al Metal–Ceramic Core–Shell Microstructures for Catalyst Applications

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Literatur
1.
vonderGonna J, Meurer HJ, Nover G, Peun T, Schonbohm D, Will G (1998) In-situ investigations of the reversible hBN-cBN-hBN-transformation in the Li3N-BN catalyst system using synchrotron radiation. Mater Lett 33(5-6):321–326CrossRef
2.
Hu YH, Huo Y (2011) Fast and exothermic reaction of CO2 and Li3N into C-N-containing solid Materials. J Phys Chem A 115(42):11678–11681CrossRef
3.
Gregory DH (2008) Lithium nitrides as sustainable energy materials. Chem Rec 8(4):229–239CrossRef
4.
Gregory DH (2008) Lithium nitrides, imides and amides as lightweight, reversible hydrogen stores. J Mater Chem 18(20):2321–2330CrossRef
5.
Markmaitree T, Ren R, Shaw LL (2006) Enhancement of lithium amide to lithium imide transition via mechanical activation. J Phys Chem B 110(41):20710–20718CrossRef
6.
Nakamori Y, Orimo S (2004) Li–N based hydrogen storage materials. Mater Sci Eng B 108(1–2):48–50CrossRef
7.
Nakamori Y, Yamagishi T, Yokoyama M, S-i Orimo (2004) Synthesis of LiNH2 films by vacuum evaporation. J Alloys Compd 377(1–2):L1–L3CrossRef
8.
Ichikawa T, Isobe S, Hanada N, Fujii H (2004) Lithium nitride for reversible hydrogen storage. J Alloys Compd 365(1–2):271–276CrossRef
9.
Ichikawa T, Hanada N, Isobe S, Leng HY, Fujii H (2005) Hydrogen storage properties in Ti catalyzed Li–N–H system. J Alloys Compd 404–406:435–438CrossRef
10.
Ichikawa T, Hanada N, Isobe S, Leng H, Fujii H (2004) Mechanism of novel reaction from LiNH2 and LiH to Li2NH and H2 as a promising hydrogen storage system. J Phys Chem B 108(23):7887–7892CrossRef
11.
Hu YH, Ruckenstein E (2003) Ultrafast reaction between LiH and NH3 during H2 storage in Li3N. J Phys Chem A 107(46):9737–9739CrossRef
12.
Hu YH, Ruckenstein E (2004) Highly effective Li2O/Li3N with ultrafast kinetics for H2 storage. Ind Eng Chem Res 43(10):2464–2467CrossRef
13.
Hu YH, Yu NY, Ruckenstein E (2005) Hydrogen storage in Li3N: deactivation caused by a high dehydrogenation temperature. Ind Eng Chem Res 44(12):4304–4309CrossRef
14.
Hu YH, Yu NY, Ruckenstein E (2004) Effect of the heat pretreatment of Li3N on its H2 storage performance. Ind Eng Chem Res 43(15):4174–4177CrossRef
15.
Hu YH, Ruckenstein E (2005) High reversible hydrogen capacity of LiNH2/Li3N mixtures. Ind Eng Chem Res 44(5):1510–1513CrossRef
16.
Hu YH, Ruckenstein E (2006) Ultrafast reaction between Li3N and LiNH2 to prepare the effective hydrogen storage material Li2NH. Ind Eng Chem Res 45(14):4993–4998CrossRef
17.
Hu YH, Ruckenstein E (2006) Hydrogen storage of Li2NH prepared by reacting Li with NH3. Ind Eng Chem Res 45(1):182–186CrossRef
18.
Yao JH, Shang C, Aguey-Zinsou KF, Guo ZX (2007) Desorption characteristics of mechanically and chemically modified LiNH2 and (LiNH2 + LiH). J Alloys Compd 432(1–2):277–282CrossRef
19.
Chen P, Xiong Z, Luo J, Lin J, Tan KL (2002) Interaction of hydrogen with metal nitrides and imides. Nature 420(6913):302–304CrossRef
20.
Kojima Y, Kawai Y (2004) Hydrogen storage of metal nitride by a mechanochemical reaction. Chem Commun 0(19):2210–2211CrossRef
21.
Dolotko O, Zhang H, Ugurlu O, Wiench JW, Pruski M, Scott Chumbley L, Pecharsky V (2007) Mechanochemical transformations in Li(Na)AlH4–Li(Na)NH2 systems. Acta Mater 55(9):3121–3130CrossRef
22.
Lapp T, Skaarup S, Hooper A (1983) Ionic conductivity of pure and doped Li3N. Solid State Ion 11(2):97–103CrossRef
23.
Brendecke H, Wagner E (1977) Electronic properties of superionic conductor Li3N. J Electrochem Soc 124(8):C305–C305
24.
Wahl J, Holland U (1978) Local ionic motion in the superionic conductor Li3N. Solid State Commun 27(3):237–241CrossRef
25.
Boukamp BA, Huggins RA (1976) Lithium ion conductivity in lithium nitride. Phys Lett A 58(4):231–233CrossRef
26.
Alpen UV, Rabenau A, Talat GH (1977) Ionic conductivity in Li3N single crystals. Appl Phys Lett 30(12):621–623CrossRef
27.
Brese NE, Okeeffe M (1992) Crystal chemistry of inorganic nitrides. Struct Bond 79:307–378CrossRef
28.
Zintl E, Brauer G (1935) Constitution of lithium nitride. Z Elektrochem 41:102–107
29.
Rabenau A, Schulz H (1976) Re-evaluation of the lithium nitride structure. J Less Common Met 50(1):155–159CrossRef
30.
Schulz H, Thiemann KH (1979) Defect structure of the ionic conductor lithium nitride (Li3N). Acta Crystallogr Sect A 35:309–314CrossRef
31.
Mali M, Roos J, Brinkmann D (1987) Nuclear-magnetic-resonance evidence for a new phase induced by pressure in the superionic conductor Li3N. Phys Rev B 36(7):3888–3890CrossRef
32.
Schon JC, Wevers MAC, Jansen M (2001) Prediction of high pressure phases in the systems Li3N, Na3N, (Li, Na)3N, Li2S and Na2S. J Mater Chem 11(1):69–77CrossRef
33.
Beister HJ, Haag S, Kniep R, Strössner K, Syassen K (1988) Phase transformations of lithium nitride under pressure. Angew Chem Int Ed 27(8):1101–1103CrossRef
34.
Huo Y, Hu YH (2012) UV–visible absorption spectrum determination of optical energy gaps of α and β lithium nitrides. J Phys Chem Solids 73(8):999–1002CrossRef
35.
Ho AC, Granger MK, Ruoff AL, Van Camp PE, Van Doren VE (1999) Experimental and theoretical study of Li3N at high pressure. Phys Rev B 59(9):6083–6086CrossRef
36.
Lazicki A, Maddox B, Evans WJ, Yoo CS, McMahan AK, Pickett WE, Scalettar RT, Hu MY, Chow P (2005) New cubic phase of Li3N: stability of the N3− ion to 200 GPa. Phys Rev Lett 95(16):165503CrossRef
37.
Brendecke H, Bludau W (1979) Optical absorption of lithium nitride. J Appl Phys 50(7):4743–4746CrossRef
38.
Brendecke H, Bludau W (1980) Photoluminescence properties of lithium nitride. Phys Rev B 21(2):805–815CrossRef
39.
Kerker G (1981) Electronic structure of Li3N. Phys Rev B 23(12):6312–6318CrossRef
40.
Dovesi R, Pisani C, Ricca F, Roetti C, Saunders VR (1984) Hartree–Fock study of crystalline lithium nitride. Phys Rev B 30(2):972–979CrossRef
41.
Lazicki A, Yoo CW, Evans WJ, Hu MY, Chow P, Pickett WE (2008) Pressure-induced loss of electronic interlayer state and metallization in the ionic solid Li3N: experiment and theory. Phys Rev B 78(15):155133CrossRef
42.
Fister TT, Seidler GT, Shirley EL, Vila FD, Rehr JJ, Nagle KP, Linehan JC, Cross JO (2008) The local electronic structure of α-Li3N. J Chem Phys 129(4):044702CrossRef
43.
Wu SN, Dong ZL, Boey F, Wu P (2009) Electronic structure and vacancy formation of Li3N. Appl Phys Lett 94(17):172104CrossRef
44.
Cui S, Feng W, Hu H, Feng Z, Wang Y (2009) Structural transition of Li3N under high pressure: A first-principles study. Solid State Commun 149(15–16):612–615CrossRef
45.
Li W, Chen JF, Wang T (2010) Electronic and elastic properties of Li3N under different pressure. Phys B 405(1):400–403CrossRef
46.
Cullity BD (1956) Elements of X-Ray diffraction, 3rd edn. Addison–Wesley publishing company Inc, Massachusetts
47.
Chandrasekhar HR, Bhattacharya G, Migoni R, Bilz H (1977) Phonon spectra and lattice dynamics of lithium nitride. Solid State Commun 22(11):681–684CrossRef
48.
Chandrasekhar HR, Bhattacharya G, Migoni R, Bilz H (1978) Infrared and raman-spectra and lattice-dynamics of superionic conductor Li3N. Phys Rev B 17(2):884–893CrossRef
49.
Brooker MH, Bates JB (1971) Raman and infrared spectral studies of anhydrous Li2CO3 and Na2CO3. J Chem Phys 54(11):4788–4796CrossRef
50.
Pasierb P, Komornicki S, Rokita M, Rȩkas M (2001) Structural properties of Li2CO3–BaCO3 system derived from IR and Raman spectroscopy. J Mol Struct 596(1–3):151–156CrossRef
51.
Jones LH (1954) The infrared spectra and structure of LiOH, LiOHH2O and the deuterium species. Remark on fundamental frequency of OH−. J Chem Phys 22(2):217–219CrossRef
Metadaten
Titel
Higher Chemical Stability of α-Li3N than β-Li3N in Atmosphere
verfasst von
Junqing Zhang
Yun Hang Hu
Publikationsdatum
01.04.2015
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 4-6/2015
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-015-0379-8

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