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Erschienen in: Cellulose 2/2013

01.04.2013 | Original Paper

Highly flexible, transparent cellulose composite films used in UV imprint lithography

verfasst von: Shilin Liu, Dandan Tao, Tengfei Yu, Hang Shu, Ren Liu, Xiaoya Liu

Erschienen in: Cellulose | Ausgabe 2/2013

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Abstract

Highly flexible, optically transparent epoxy resin/cellulose composites were prepared by using the solution impregnation method firstly and then thermal cured. The composite contained 60 wt% resin was still mechanically stable and flexible, and it integrated the merits of cellulose and resin, but the highly hydrophilic behavior of cellulose has been reduced. Contact angle measurements with water demonstrated that the composite films had obvious hydrophobic properties, and a decrease in the water uptake and the permeability towards water vapor gas was also observed. The transmittance of the composite films at 550 nm was about 85–88 %. The thermal and mechanical properties of the composite films were improved. Moreover, the composite films could be used in UV imprint lithography for circuit, and the definition could be compared with that of widely used glass plate.

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Literatur
Zurück zum Zitat Choi SJ, Yoo PJ, Baek SJ, Kim TW, Lee HH (2004) An ultraviolet-curable mold for sub-100-nm lithography. J Am Chem Soc 126:7744–7745CrossRef Choi SJ, Yoo PJ, Baek SJ, Kim TW, Lee HH (2004) An ultraviolet-curable mold for sub-100-nm lithography. J Am Chem Soc 126:7744–7745CrossRef
Zurück zum Zitat Fernandes SCM, Oliveira L, Freire CSR, Silvestre AJD, Neto CP, Gandini A, Desbriéres J (2009) Novel transparent nanocomposite films based on chitosan and bacterial cellulose. Green Chem 11:2023–2029CrossRef Fernandes SCM, Oliveira L, Freire CSR, Silvestre AJD, Neto CP, Gandini A, Desbriéres J (2009) Novel transparent nanocomposite films based on chitosan and bacterial cellulose. Green Chem 11:2023–2029CrossRef
Zurück zum Zitat Fidalgo A, Ilharco LM (2001) The defect structure of sol-gel derived silica/polytetrahydrofuran hybrid film by FTIR. J Non-Cryst Solids 283:144–154CrossRef Fidalgo A, Ilharco LM (2001) The defect structure of sol-gel derived silica/polytetrahydrofuran hybrid film by FTIR. J Non-Cryst Solids 283:144–154CrossRef
Zurück zum Zitat Fujisawa S, Ikeuchi T, Takeuchi M, Saito T, Isogai A (2012) Superior reinforcement effect of TEMPO-oxidized cellulose nanofibrils in polystyrene matrix: optical, thermal, and mechanical studies. Biomacromolecules 13:2188–2194CrossRef Fujisawa S, Ikeuchi T, Takeuchi M, Saito T, Isogai A (2012) Superior reinforcement effect of TEMPO-oxidized cellulose nanofibrils in polystyrene matrix: optical, thermal, and mechanical studies. Biomacromolecules 13:2188–2194CrossRef
Zurück zum Zitat Iwamoto S, Nakagaito AN, Yano H, Nogi M (2005) Optically transparent composites reinforced with plant fiber-based nanofibers. Appl Phys A 81:1109–1112CrossRef Iwamoto S, Nakagaito AN, Yano H, Nogi M (2005) Optically transparent composites reinforced with plant fiber-based nanofibers. Appl Phys A 81:1109–1112CrossRef
Zurück zum Zitat Iwamoto S, Nakagaito AN, Yano H (2007) Nano-fibrillation of pulp fibers for the processing of transparent nanocomposites. Appl Phys A 89:461–466CrossRef Iwamoto S, Nakagaito AN, Yano H (2007) Nano-fibrillation of pulp fibers for the processing of transparent nanocomposites. Appl Phys A 89:461–466CrossRef
Zurück zum Zitat Kattumenu R, Rebros M, Joyce M, Fleming P, Neelgund G (2009) Effect of substrate properties on conductive traces printed with silver-based flexographic ink. Nord Pulp Pap Res J 24:101–106CrossRef Kattumenu R, Rebros M, Joyce M, Fleming P, Neelgund G (2009) Effect of substrate properties on conductive traces printed with silver-based flexographic ink. Nord Pulp Pap Res J 24:101–106CrossRef
Zurück zum Zitat Li R, Chang C, Zhou J, Zhang L, Gu W, Li C, Liu S, Kuga S (2010) Primarily industrialized trial of novel fibers spun from cellulose dope in NaOH/Urea aqueous solution. Ind Eng Chem Res 49:11380–11384CrossRef Li R, Chang C, Zhou J, Zhang L, Gu W, Li C, Liu S, Kuga S (2010) Primarily industrialized trial of novel fibers spun from cellulose dope in NaOH/Urea aqueous solution. Ind Eng Chem Res 49:11380–11384CrossRef
Zurück zum Zitat Liao H, Wu Y, Wu M, Zhan X, Liu H (2012) Aligned electrospun cellulose fibers reinforced epoxy resin composite films with high visible light transmittance. Cellulose 19:111–119CrossRef Liao H, Wu Y, Wu M, Zhan X, Liu H (2012) Aligned electrospun cellulose fibers reinforced epoxy resin composite films with high visible light transmittance. Cellulose 19:111–119CrossRef
Zurück zum Zitat Liu S, Zhou J, Zhang L, Guan J, Wang J (2006) Synthesis and alignment of iron oxide nanoparticles in a regenerated cellulose film. Macromol Rapid Commun 27:2084–2089CrossRef Liu S, Zhou J, Zhang L, Guan J, Wang J (2006) Synthesis and alignment of iron oxide nanoparticles in a regenerated cellulose film. Macromol Rapid Commun 27:2084–2089CrossRef
Zurück zum Zitat Liu S, Zhang L, Zhou J, Wu R (2008a) Structure and properties of cellulose/Fe2O3 nanocomposite fibers spum via an effective pathway. J Phys Chem C 112:4538–4544CrossRef Liu S, Zhang L, Zhou J, Wu R (2008a) Structure and properties of cellulose/Fe2O3 nanocomposite fibers spum via an effective pathway. J Phys Chem C 112:4538–4544CrossRef
Zurück zum Zitat Liu S, Zhang L, Zhou J, Xiang J, Sun J, Guan J (2008b) Fiberlikelike Fe2O3 macroporous nanomaterials fabricated by calcinating regenerated cellulose composite fibers. Chem Mater 20:3623–3628CrossRef Liu S, Zhang L, Zhou J, Xiang J, Sun J, Guan J (2008b) Fiberlikelike Fe2O3 macroporous nanomaterials fabricated by calcinating regenerated cellulose composite fibers. Chem Mater 20:3623–3628CrossRef
Zurück zum Zitat Liu S, Zhang L, Sun Y, Lin Y, Nishiyama Y (2009) Supramolecular structure and properties of high strength regenerated cellulose films. Macromol Biosci 9:29–35CrossRef Liu S, Zhang L, Sun Y, Lin Y, Nishiyama Y (2009) Supramolecular structure and properties of high strength regenerated cellulose films. Macromol Biosci 9:29–35CrossRef
Zurück zum Zitat Liu H, Liu D, Yao F, Wu Q (2010a) Fabrication and properties of transparent polymethylmethacrylate/cellulose nanocrystals composites. Bioresour Technol 101:5685–5692CrossRef Liu H, Liu D, Yao F, Wu Q (2010a) Fabrication and properties of transparent polymethylmethacrylate/cellulose nanocrystals composites. Bioresour Technol 101:5685–5692CrossRef
Zurück zum Zitat Liu S, Zeng J, Tao D, Zhang L (2010b) Microfiltration performance of regenerated cellulose membrane prepared at low temperature for wastewater treatment. Cellulose 17:1159–1169CrossRef Liu S, Zeng J, Tao D, Zhang L (2010b) Microfiltration performance of regenerated cellulose membrane prepared at low temperature for wastewater treatment. Cellulose 17:1159–1169CrossRef
Zurück zum Zitat Liu S, Ke D, Zeng J, Zhou J, Peng T, Zhang L (2011a) Creation of inorganic nanoparticles by micro-nano-porous structure of cellulose matrix. Cellulose 18:945–956CrossRef Liu S, Ke D, Zeng J, Zhou J, Peng T, Zhang L (2011a) Creation of inorganic nanoparticles by micro-nano-porous structure of cellulose matrix. Cellulose 18:945–956CrossRef
Zurück zum Zitat Liu S, Zhou J, Zhang L (2011b) In situ synthesis of plate-like Fe2O3 nanoparticles in porous cellulose films with obvious magnetic anisotropy. Cellulose 18:663–673CrossRef Liu S, Zhou J, Zhang L (2011b) In situ synthesis of plate-like Fe2O3 nanoparticles in porous cellulose films with obvious magnetic anisotropy. Cellulose 18:663–673CrossRef
Zurück zum Zitat Liu S, Zhou J, Zhang L (2011c) Effects of crystalline phase and particle size on the properties of plate-like Fex nanoparticles during γtoα-phase transformation. J Phys Chem C 115:3602–3611CrossRef Liu S, Zhou J, Zhang L (2011c) Effects of crystalline phase and particle size on the properties of plate-like Fex nanoparticles during γtoα-phase transformation. J Phys Chem C 115:3602–3611CrossRef
Zurück zum Zitat Luo X, Liu S, Zhou J, Zhang L (2009) In situ synthesis of Fe3O4/cellulose microspheres with magnetic- induced protein delivery. J Mater Chem 19:3538–3545CrossRef Luo X, Liu S, Zhou J, Zhang L (2009) In situ synthesis of Fe3O4/cellulose microspheres with magnetic- induced protein delivery. J Mater Chem 19:3538–3545CrossRef
Zurück zum Zitat Mark JE (ed) (2007) Physical properties of polymers handbook, 2nd edn. Springer, New York Mark JE (ed) (2007) Physical properties of polymers handbook, 2nd edn. Springer, New York
Zurück zum Zitat Maury P, Turkenburg D, Stroeks N, Giesen P, Barbu I, Meinders E, Van Bremen A, Iosad N, Van der Werf R, Onvlee H (2011) Roll-to-roll UV imprint lithography for flexible electronics. Microelectron Eng 88:2052–2055CrossRef Maury P, Turkenburg D, Stroeks N, Giesen P, Barbu I, Meinders E, Van Bremen A, Iosad N, Van der Werf R, Onvlee H (2011) Roll-to-roll UV imprint lithography for flexible electronics. Microelectron Eng 88:2052–2055CrossRef
Zurück zum Zitat Nogi M, Yano H (2008) Transparent nanocomposites based on cellulose produced by bacteria offer potential innovation in the electronics device industry. Adv Mater 20:1849–1852CrossRef Nogi M, Yano H (2008) Transparent nanocomposites based on cellulose produced by bacteria offer potential innovation in the electronics device industry. Adv Mater 20:1849–1852CrossRef
Zurück zum Zitat Nogi M, Handa K, Nakagaito AN, Yano H (2005) Optically transparent bionanofiber composites with low sensitivity to refractive index of the polymer matrix. Appl Phys Lett 87:243110–243112CrossRef Nogi M, Handa K, Nakagaito AN, Yano H (2005) Optically transparent bionanofiber composites with low sensitivity to refractive index of the polymer matrix. Appl Phys Lett 87:243110–243112CrossRef
Zurück zum Zitat Nogi M, Ifuku S, Abe K, Handa K, Nakagaito AN, Yano H (2006) Fiber-content dependency of the optical transparency and thermal expansion of bacterial nanofiber reinforced composites. Appl Phys Lett 88:133124CrossRef Nogi M, Ifuku S, Abe K, Handa K, Nakagaito AN, Yano H (2006) Fiber-content dependency of the optical transparency and thermal expansion of bacterial nanofiber reinforced composites. Appl Phys Lett 88:133124CrossRef
Zurück zum Zitat Ou SY, Kwok KC, Kang YJ (2004) Changes in vitro digestibility and available lysine of soy protein isolate after formation of film. J Food Eng 64:301–305CrossRef Ou SY, Kwok KC, Kang YJ (2004) Changes in vitro digestibility and available lysine of soy protein isolate after formation of film. J Food Eng 64:301–305CrossRef
Zurück zum Zitat Phukon P, Saikia JP, Konwar BK (2012) Bio-plastic (P-3HB-co-3HV) from Bacillus circulans (MTCC 8167) and its biodegradation. Colloids Surf B 92:30–34CrossRef Phukon P, Saikia JP, Konwar BK (2012) Bio-plastic (P-3HB-co-3HV) from Bacillus circulans (MTCC 8167) and its biodegradation. Colloids Surf B 92:30–34CrossRef
Zurück zum Zitat Pojanavaraphan T, Magaraphan R (2008) Prevulcanized natural rubber latex/clay aerogel nanocomposites. Eur Polym J 44:1968–1977CrossRef Pojanavaraphan T, Magaraphan R (2008) Prevulcanized natural rubber latex/clay aerogel nanocomposites. Eur Polym J 44:1968–1977CrossRef
Zurück zum Zitat Pojanavaraphan T, Schiraldi DA, Magaraphan R (2010) Mechanical, rheological, and swelling behavior of natural rubber/montmorillonite aerogels prepared by freeze-drying. Appl Clay Sci 50:271–279CrossRef Pojanavaraphan T, Schiraldi DA, Magaraphan R (2010) Mechanical, rheological, and swelling behavior of natural rubber/montmorillonite aerogels prepared by freeze-drying. Appl Clay Sci 50:271–279CrossRef
Zurück zum Zitat Pojanavaraphan T, Liu L, Ceylan D, Okay O, Magaraphan R, Schiraldi DA (2011) Solution cross-linked natural rubber (NR)/clay aerogel composites. Macromolecules 44:923–931CrossRef Pojanavaraphan T, Liu L, Ceylan D, Okay O, Magaraphan R, Schiraldi DA (2011) Solution cross-linked natural rubber (NR)/clay aerogel composites. Macromolecules 44:923–931CrossRef
Zurück zum Zitat Shimazaki Y, Miyazaki Y, Takezawa Y, Nogi M, Abe K, Ifuku S, Yano H (2007) Excellent thermal conductivity of transparent cellulose nanofiber/epoxy resin nanocomposites. Biomacromolecules 8:2976–2978CrossRef Shimazaki Y, Miyazaki Y, Takezawa Y, Nogi M, Abe K, Ifuku S, Yano H (2007) Excellent thermal conductivity of transparent cellulose nanofiber/epoxy resin nanocomposites. Biomacromolecules 8:2976–2978CrossRef
Zurück zum Zitat Tang CY, Liu HQ (2008) Cellulose nanofiber reinforced poly(vinyl alcohol) composite film with high visible light transmittance. Compos A 39:1638–1643CrossRef Tang CY, Liu HQ (2008) Cellulose nanofiber reinforced poly(vinyl alcohol) composite film with high visible light transmittance. Compos A 39:1638–1643CrossRef
Zurück zum Zitat Toméa LC, Goncalvesa CMB, Boaventurab M, Brandãb L, Mendesb AM, Silvestrea AJD, Netoa CP, Gandinia A, Freirea CSR, Marrucho IM (2011) Preparation and evaluation of the barrier properties of cellophane membranes modified with fatty acids. Carbohydr Polym 83:836–842CrossRef Toméa LC, Goncalvesa CMB, Boaventurab M, Brandãb L, Mendesb AM, Silvestrea AJD, Netoa CP, Gandinia A, Freirea CSR, Marrucho IM (2011) Preparation and evaluation of the barrier properties of cellophane membranes modified with fatty acids. Carbohydr Polym 83:836–842CrossRef
Zurück zum Zitat Valentín JL, Mora-Barrantes I, Carretero-González J, López-Manchado MA, Sotta P, Long DR, Saalwächter K (2010) Novel experimental approach to evaluate filler–elastomer interactions. Macromolecules 43:334–346CrossRef Valentín JL, Mora-Barrantes I, Carretero-González J, López-Manchado MA, Sotta P, Long DR, Saalwächter K (2010) Novel experimental approach to evaluate filler–elastomer interactions. Macromolecules 43:334–346CrossRef
Zurück zum Zitat Yano H, Sugiyama J, Nakagaito AN, Nogi M, Matsuura T, Hikita M, Handa K (2005) Optically transparent composites reinforced with networks of bacterial nanofibers. Adv Mater 17:153–155CrossRef Yano H, Sugiyama J, Nakagaito AN, Nogi M, Matsuura T, Hikita M, Handa K (2005) Optically transparent composites reinforced with networks of bacterial nanofibers. Adv Mater 17:153–155CrossRef
Zurück zum Zitat Zhang LN, Ruan D, Zhou JP (2001) Structure and properties of regenerated cellulose films prepared from cotton linters in NaOH/urea aqueous solution. Ind Eng Chem Res 40:5923–5928CrossRef Zhang LN, Ruan D, Zhou JP (2001) Structure and properties of regenerated cellulose films prepared from cotton linters in NaOH/urea aqueous solution. Ind Eng Chem Res 40:5923–5928CrossRef
Metadaten
Titel
Highly flexible, transparent cellulose composite films used in UV imprint lithography
verfasst von
Shilin Liu
Dandan Tao
Tengfei Yu
Hang Shu
Ren Liu
Xiaoya Liu
Publikationsdatum
01.04.2013
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 2/2013
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-013-9877-7

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