nach oben

Cellulose

Erschienen in:

28.04.2021 | Original Research

Highly-porous uniformly-sized amidoxime-functionalized cellulose beads prepared by microfluidics with N-methylmorpholine N-oxide

verfasst von: Seung-Yeop Baek, Soo-Young Park

Erschienen in: Cellulose | Ausgabe 9/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Uniformly-sized porous cellulose beads functionalized with amidoxime groups were prepared for the first time using a microfluidic method with N-methylmorpholine N-oxide (NMMO) monohydrate as a cellulose solvent. The molten state cellulose dope in NMMO monohydrate (cell/NMMO dope) as a disperse phase and hot mineral oil as a continuous phase were used in a T-junction microfluidic chip to produce uniformly-sized cell/NMMO droplets. Coagulation of the molten state cell/NMMO droplet at high temperature and amidoxime functionalization could prepare the highly-porous spherical amidoxime-functionalized cellulose beads with a uniform fibrous open internal structure. The prepared amidoxime-functionalized cellulose beads showed excellent metal adsorption properties with a maximum adsorption capacity of ~ 80 mg g⁻¹ in the case of Cu²⁺/phthalate ions. The newly developed highly-porous cellulose beads can open many new applications with other proper functionalization at the reactive hydroxyl groups of the cellulose.

Graphic abstract

Vorheriger Artikel Effect of the chemical and structural characteristics of pulps of Eucalyptus and Pinus on the deconstruction of the cell wall during the production of cellulose nanofibrils

Nächster Artikel Homogeneous and stable carbon nanotube dispersion assisted by cellulose in NaOH/thiourea aqueous solution

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Alam MN, Islam MS, Christopher LP (2019) Sustainable production of cellulose-based hydrogels with superb absorbing potential in physiological saline. ACS Omega 4:9419–9426. https://doi.org/10.1021/acsomega.9b00651CrossRefPubMedPubMedCentral

Biganska O, Navard P (2008) Morphology of cellulose objects regenerated from cellulose-N-methylmorpholine N-oxide–water solutions. Cellulose 16:179. https://doi.org/10.1007/s10570-008-9256-yCrossRef

Biganska O, Navard P, Bédué O (2002) Crystallisation of cellulose/N-methylmorpholine-N-oxide hydrate solutions. Polymer 43:6139–6145CrossRef

Boeden HF et al (1991) Bead cellulose derivatives as supports for immobilization and chromatographic purification of proteins. J Chromatogr A 552:389–414CrossRef

Bolto BA, Pawlowski L (1987) Wastewater treatment by ion-exchange

Dawson T (2012) Progress towards a greener textile industry. Color Technol 128:1–8CrossRef

Diviš P, Szkandera R, BrulíK L, Docekalova H, Matúš P, BujdoŠ M (2009) Application of new resin gels for measuring mercury by diffusive gradients in a thin-films technique. Anal Sci 25:575–578CrossRef

Fink HP, Weigel P, Purz HJ, Ganster J (2001) Structure formation of regenerated cellulose materials from NMMO-solutions. Prog Polym Sci 26:1473–1524CrossRef

Geckeler KE, Shkinev VM, Spivakov BY (1988) Liquid-phase polymer-based retention (LPR)-a new method for selective ion separation. Sep Purif Methods 17:105–140CrossRef

Gericke M, Trygg J, Fardim P (2013) Functional cellulose beads: preparation, characterization, and applications. Chem Rev 113:4812–4836CrossRef

Gough BM (1967) Interaction of wheat starch and epichlorohydrin. Starch-Stärke 19:240–243CrossRef

He YB, Meng LZ, Wu CT, Qian T (1999) Preparation and coordination behavior of cellulose beads derivative modified by 1, 5-diaminoethyl-3-hydroxy-1, 5-diazacycloheptane. J Appl Polym Sci 74:1278–1285CrossRef

Hirota M, Tamura N, Saito T, Isogai A (2009) Surface carboxylation of porous regenerated cellulose beads by 4-acetamide-TEMPO/NaClO/NaClO 2 system. Cellulose 16:841–851CrossRef

Hua J et al (2019) Highly porous cellulose microbeads and their adsorption for methylene blue. Fibers Polym 20:794–803CrossRef

Kahovec J, Matějka Z, Štamberg J (1980) EDTA ester of bead cellulose a fast-kinetics chelating sorbent. Polym Bull 3:13–17CrossRef

Klemm D, Kramer F, Moritz S, Lindström T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Ed 50:5438–5466CrossRef

Li W, Liu R, Kang H, Sun Y, Dong F, Huang Y (2013) Synthesis of amidoxime functionalized cellulose derivatives as a reducing agent and stabilizer for preparing gold nanoparticles. Polym Chem 4:2556–2563. https://doi.org/10.1039/C3PY00052DCrossRef

Lidhure A, Jadhav S, Ganvir V, Thakre S (2019) Modified lyocell process for producing biopolymer fiber. In: AIP conference proceedings, vol 1. AIP Publishing LLC, p 030062

Matúš P, Kubová J (2005) Complexation of labile aluminium species by chelating resins Iontosorb—a new method for Al environmental risk assessment. J Inorg Biochem 99:1769–1778CrossRef

Pawlowski L (2015) Physicochemical methods for water and wastewater treatment: proceedings of the second international conference, Lublin, June 1979. Elsevier

Pinnow M, Fink HP, Fanter C, Kunze J (2008) Characterization of highly porous materials from cellulose carbamate. In: Macromolecular symposia, vol 1. Wiley Online Library, pp 129–139

Rahman ML, Sarkar SM, Farid EM, Arshad SE, Sarjadi MS, Wid N (2018) Synthesis of tapioca cellulose-based poly (amidoxime) ligand for removal of heavy metal ions. J Macromol Sci Part B 57:83–99CrossRef

Rahman ML, Sarkar SM, Yusoff MM, Abdullah MH (2016) Efficient removal of transition metal ions using poly (amidoxime) ligand from polymer grafted kenaf cellulose. RSC Adv 6:745–757CrossRef

Rosenau T, Potthast A, Adorjan I, Hofinger A, Sixta H, Firgo H, Kosma P (2002) Cellulose solutions in N-methylmorpholine-N-oxide (NMMO)-degradation processes and stabilizers. Cellulose 9:283–291CrossRef

Rosenau T, Potthast A, Kosma P, Chen GJS (1999) Autocatalytic decomposition of N-methylmorpholine N-oxide induced by mannich intermediates. J Org Chem 64:2166–2167. https://doi.org/10.1021/jo982350yCrossRef

Rosenau T, Potthast A, Sixta H, Kosma P (2001) The chemistry of side reactions and byproduct formation in the system NMMO/cellulose (Lyocell process). Prog Polym Sci 26:1763–1837CrossRef

Rosenau T, Schmid P, Potthast A, Kosma P (2005) Stabilization of cellulose solutions in N-methylmorpholine-N-oxide (Lyocell dopes) by addition of an N-oxide as sacrificial substrate. Holzforschung 59:503–506. https://doi.org/10.1515/hf.2005.083CrossRef

Rosenberg P, Suominen I, Rom M, Janicki J, Fardim P (2007) Tailored cellulose beads for novel applications. Cellul Chem Technol 41:243–254

Saeed K, Haider S, Oh T-J, Park S-Y (2008) Preparation of amidoxime-modified polyacrylonitrile (PAN-oxime) nanofibers and their applications to metal ions adsorption. J Membr Sci 322:400–405CrossRef

Saliba R, Gauthier H, Gauthier R, Petit-Ramel M (2000) Adsorption of copper(II) and chromium(III) ions onto amidoximated cellulose. J Appl Polym Sci 75:1624–1631CrossRef

Seemann R, Brinkmann M, Pfohl T, Herminghaus S (2011) Droplet based microfluidics. Rep Progress Phys 75:016601CrossRef

Sharma RK, Agrawal M, Marshall F (2007) Heavy metal contamination of soil and vegetables in suburban areas of Varanasi, India. Ecotoxicol Environ Saf 66:258–266CrossRef

Trygg J, Fardim P, Gericke M, Mäkilä E, Salonen J (2013) Physicochemical design of the morphology and ultrastructure of cellulose beads. Carbohydr Polym 93:291–299CrossRef

Twu Y-K, Huang H-I, Chang S-Y, Wang S-L (2003) Preparation and sorption activity of chitosan/cellulose blend beads. Carbohydr Polym 54:425–430CrossRef

Udoetok IA, Dimmick RM, Wilson LD, Headley JV (2016) Adsorption properties of cross-linked cellulose-epichlorohydrin polymers in aqueous solution. Carbohydr Polym 136:329–340CrossRef

Wang P, Du M, Zhu H, Bao S, Yang T, Zou M (2015) Structure regulation of silica nanotubes and their adsorption behaviors for heavy metal ions: pH effect, kinetics, isotherms and mechanism. J Hazard Mater 286:533–544CrossRef

Yeomans-Reina H, Ruiz-Manriquez A, Wong BR, Mansir AT (2001) Selectivity of IMAC columns in trypsin inhibitor purification. Biotechnol Prog 17:729–733CrossRef

Zhang L, Cai J, Zhou J, Tang Y (2005) Adsorption of Cd2+ and Cu2+ on ion-exchange beads from cellulose/alginic acid blend. Sep Sci Technol 39:1203–1219CrossRef

Zhu P, Wang L (2017) Passive and active droplet generation with microfluidics: a review. Lab Chip 17:34–75. https://doi.org/10.1039/C6LC01018KCrossRef

Zulfiqar S et al (2011) Amidoximes: promising candidates for CO₂ capture energy and environmental. Science 4:4528–4531

Titel: Highly-porous uniformly-sized amidoxime-functionalized cellulose beads prepared by microfluidics with N-methylmorpholine N-oxide
verfasst von: Seung-Yeop Baek
Soo-Young Park
Publikationsdatum: 28.04.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 9/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-03872-0

Springer Professional

Abstract

Graphic abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 9/2021

Microfibrillated cellulose film with enhanced mechanical and water-resistant properties by glycerol and hot-pressing treatment

Environmentally-benign, water-based covalent polymer network for flame retardant cotton

Humidity-responsive thermal conduction properties of bacterial cellulose films

Molybdenum disulphide/cellulose acetate nanofiber composite on screen printed electrodes for detecting cardiac troponin by electrical impedance spectroscopy

The preparation and characterization of chemically deuterium incorporated cotton fibers

Modification of ZIF-8 on bacterial cellulose for an efficient selective capture of U(VI)