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Biomass Conversion and Biorefinery
Erschienen in: Biomass Conversion and Biorefinery 4/2014

01.12.2014 | Original Article

Hydrogenation of levulinic acid and γ-valerolactone: steps towards biofuels

verfasst von: Sandip N. Derle, Parimal A. Parikh

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 4/2014

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Abstract

Several bifunctional catalysts (Pt, Au, Ni supported on ZSM-5, zeolite Beta, silica and alumina) were evaluated for hydrogenation of levulinic acid (LA) and γ-valerolactone (GVL). Among these, Pt supported on parent- and desilicated-zeolite Beta showed better catalytic activity for hydrogenation of gamma valerolactone to valeric acid (VA) with >98 % selectivity. Noteworthy catalytic activity of Au supported on desilicated zeolite Beta in GVL to VA hydrogenation was observed. Other catalysts such as Pt/γ-alumina, Ni/desilicated zeolite Beta and Ni/SiO2 did not exhibit significant catalytic activity in GVL hydrogenation. Pt and Au-supported zeolite catalysts were also tested for hydrogenation of LA to GVL. Pt supported on zeolites decomposed formic acid (FA) to CO2 and H2 and in situ produced H2 hydrogenated LA to GVL. Pt impregnated desilicated zeolite Beta was found to retain its integrity even after prolonged exposure to hot VA solution and neither Pt nor Al leached into solution.
Vorheriger Artikel Pretreatment and distilling processes of Eucalyptus globulus leaves for enhancing essential oil production
Nächster Artikel A synergistic effect of microwave/ultrasound and symmetrical acidic ionic liquids on transesterification of vegetable oils with high free fatty acid

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Metadaten
Titel
Hydrogenation of levulinic acid and γ-valerolactone: steps towards biofuels
verfasst von
Sandip N. Derle
Parimal A. Parikh
Publikationsdatum
01.12.2014
Verlag
Springer Berlin Heidelberg
Erschienen in
Biomass Conversion and Biorefinery / Ausgabe 4/2014
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI
https://doi.org/10.1007/s13399-013-0111-5

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