Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 13/2019

09.04.2019 | Polymers

Hydrophobic modification of cationic microblocked polyacrylamide and its enhanced flocculation performance for oily wastewater treatment

verfasst von: Yuhao Zhou, Huaili Zheng, Yaoyao Huang, Xinyu Zheng, Zenan Liu, Yanyan An, Chun Zhao, Yongzhi Liu

Erschienen in: Journal of Materials Science | Ausgabe 13/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this study, a novel amphiphilic flocculant TP-ADL was synthesized using acrylamide, methacryloxyethyltrimethyl ammonium chloride and lauryl acrylate as monomers through UV-light-initiating template copolymerization technology. Copolymerization conditions were optimized towards higher intrinsic viscosity and conversion rate. The Fourier transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy (NMR) analysis confirms the functional groups composition in TP-ADL, and the thermogravimetric (TGA) analysis indicates its good thermal stability. Furthermore, the detailed 1H NMR and TGA analysis confirms the microblock structure in polymer chain. The amphiphilic rheological characteristics of copolymer were detected according to apparent viscosity. TP-ADL displayed superior flocculation efficiency towards oily wastewater in terms of oil and turbidity removal rate, and zeta potential. The median floc size (d50) and fractal dimension (Df) results indicate a large and compact floc structure. The synergistic effect between cationic microblock structure and inter-molecular hydrophobic association is the main reason for the better treatment efficiency.
Vorheriger Artikel Glucose-responsive nanostructured hydrogels with enhanced elastic and swelling properties
Nächster Artikel Size-controlled graphite nanoplatelets: thermal conductivity enhancers for epoxy resin

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Yang T, Qiao B, Li GC, Yang QY (2015) Improving performance of dynamic membrane assisted by electrocoagulation for treatment of oily wastewater: effect of electrolytic conditions. Desalination 363:134–143CrossRef
2.
Sun YJ, Zhu CY, Zheng HL, Sun WQ, Xu YH, Xiao XF, You ZY, Liu CY (2017) Characterization and coagulation behavior of polymeric aluminum ferric silicate for high-concentration oily wastewater treatment. Chem Eng Res Des 119:23–32CrossRef
3.
Zhao CL, Zheng HL, Gao BY, Liu YZ, Zhai J, Zhang SX, Xu BC (2018) Ultrasound-initiated synthesis of cationic polyacrylamide for oily wastewater treatment: enhanced interaction between the flocculant and contaminants. Ultrason Sonochem 42:31–41CrossRef
4.
Liu XJ, Ge L, Li W, Wang XZ, Li F (2015) Layered double hydroxide functionalized textile for effective oil/water separation and selective oil adsorption. ACS Appl Mater Interfaces 7(1):791–800CrossRef
5.
Painmanakul P, Sastaravet P, Lersjintanakarn S, Khaodhiar S (2010) Effect of bubble hydrodynamic and chemical dosage on treatment of oily wastewater by Induced Air Flotation (IAF) process. Chem Eng Res Des 88(5-6A):693–702CrossRef
6.
Zhu XB, Dudchenko A, Gu XT, Jassby D (2017) Surfactant-stabilized oil separation from water using ultrafiltration and nanofiltration. J Membr Sci 529:159–169CrossRef
7.
Sarac N, Ugur A (2016) A green alternative for oily wastewater treatment: lipase from Acinetobacter haemolyticus NS02-30. Desalin Water Treat 57(42):19750–19759CrossRef
8.
Yang ZL, Gao BY, Li CX, Yue QY, Liu B (2010) Synthesis and characterization of hydrophobically associating cationic polyacrylamide. Chem Eng J 161(1–2):27–33CrossRef
9.
An CJ, Huang G, Yao Y, Zhao S (2017) Emerging usage of electrocoagulation technology for oil removal from wastewater: a review. Sci Total Environ 579:537–556CrossRef
10.
Ma JY, Shi J, Ding L, Zhang HW, Zhou S, Wang QJ, Fu X, Jiang LY, Fu K (2018) Removal of emulsified oil from water using hydrophobic modified cationic polyacrylamide flocculants synthesized from low-pressure UV initiation. Sep Purif Technol 197:407–417CrossRef
11.
Zhang YX, Wu FP, Li MZ, Wang EJ (2005) Novel approach to synthesizing hydrophobically associating copolymer using template copolymerization: the synthesis and behaviors of acrylamide and 4-((9-propenoyloxyethoxy) benzoic acid copolymer. J Phys Chem B 109(47):22250–22255CrossRef
12.
Popa I, Gillies G, Papastavrou G, Borkovec M (2009) Attractive electrostatic forces between identical colloidal particles induced by adsorbed polyelectrolytes. J Phys Chem 113(25):8458–8561CrossRef
13.
Zhou YH, Zheng HL, Gao BY, Gu YP, Li X, Liu BZ, Jimenez AM (2017) Waste activated sludge (WAS) dewatering properties of an original hydrophobically modified polyacrylamide containing a cationic microblock structure. RSC Adv 7(46):28733–28745CrossRef
14.
Li X, Zheng HL, Gao BY, Zhao C, Sun YJ (2017) UV-initiated polymerization of acid-and alkali-resistant cationic flocculant P(AM-MAPTAC): synthesis, characterization, and application in sludge dewatering. Sep Purif Technol 187:244–254CrossRef
15.
Li X, Zheng HL, Gao BY, Sun YJ, Liu BZ, Zhao CL (2017) UV-initiated template copolymerization of AM and MAPTAC: microblock structure, copolymerization mechanism, and flocculation performance. Chemosphere 167:71–81CrossRef
16.
Zhang ZA, Zheng HL, Huang F, Li X, He SY, Zhao C (2016) Template polymerization of a novel cationic polyacrylamide: sequence distribution, characterization, and flocculation performance. Ind Eng Chem Res 55(37):9819–9828CrossRef
17.
Guan QQ, Zheng HL, Zhai J, Zhao C, Zheng XK, Tang XM, Chen W, Sun YJ (2014) Effect of template on structure and properties of cationic polyacrylamide: characterization and mechanism. Ind Eng Chem Res 53(14):5624–5635CrossRef
18.
Shang HZ, Liu JP, Zheng YB, Wang LG (2010) Synthesis, characterization, and flocculation properties of poly(acrylamide-methacryloxyethyltrimethyl ammonium chloride-methacryloxypropyltrimethoxy silane). J Appl Polym Sci 111(3):1594–1599CrossRef
19.
Niranjan PS, Tiwari AK, Upadhyay SK (2011) Polymerization of acrylamide in a micellar medium: inhibition effect of surfactants. J Appl Polym Sci 122(2):981–986CrossRef
20.
Kundu P, Mishra IM (2013) Removal of emulsified oil from oily wastewater (oil-in-water emulsion) using packed bed of polymeric resin beads. Sep Purif Technol 118:519–529CrossRef
21.
Jarvis P, Jefferson A, Parsons SA (2005) Breakage, regrowth, and fractal nature of natural organic matter flocs. Environ Sci Technol 39(7):2307–2314CrossRef
22.
Greenwood J, Rainey T, Doherty WOS (2007) Light scattering study on the size and structure of calcium phosphate/hydroxyapatite flocs formed in sugar solutions. J Colloid Interface Sci 306(1):66–71CrossRef
23.
Wu YM, Zhang N (2009) Aqueous photo-polymerization of cationic polyacrylamide with hybrid photo-initiators. J Polym Res 16(6):647–653CrossRef
24.
Wang XN, Yue QY, Gao BY, Si XH, Sun X, Zhang SX (2011) Dispersion copolymerization of acrylamide and dimethyl diallyl ammonium chloride in ethanol-water solution. J Appl Polym Sci 120(3):1496–1502CrossRef
25.
Bao Y, Ma JZ, Li N (2011) Synthesis and swelling behaviors of sodium carboxymethyl cellulose-g-poly(AA-co-AM-co-AMPS)/MMT superabsorbent hydrogel. Carbohyd Polym 84(1):76–82CrossRef
26.
Zhu JR, Zheng HL, Jiang ZZ, Zhang Z, Liu LW, Sun YJ (2013) Synthesis and characterization of a dewatering reagent: cationic polyacrylamide (P(AM–DMC–DAC)) for activated sludge dewatering treatment. Desalin Water Treat 51(13–15):2791–2801CrossRef
27.
Chen W, Zheng HL, Guan QQ, Teng HK, Zhao CL, Zhao C (2016) Fabricating a flocculant with controllable cationic microblock structure: characterization and sludge conditioning behavior evaluation. Ind Eng Chem Res 55(10):2892–2902CrossRef
28.
Zheng HL, Sun YJ, Guo JS, Li FT, Fan W, Liao Y, Guan QQ (2014) Characterization and evaluation of dewatering properties of PADB, a highly efficient cationic flocculant. Ind Eng Chem Res 53(7):2572–2582CrossRef
29.
Gou SH, Li SW, Feng MM, Zhang Q, Pan QL, Wen J, Wu YP, Guo QP (2017) Novel biodegradable water-soluble graft-modified copolymer using acrylamide and konjac glucomannan for enhanced oil recovery. Ind Eng Chem Res 56(4):942–951CrossRef
30.
Yahaya GO, Ahdab AA, Ali SA, Abu-Sharkh BF, Hamad EZ (2001) Solution behavior of hydrophobically associating water-soluble block copolymers of acrylamide and N -benzylacrylamide. Polymer 42(8):3363–3372CrossRef
31.
Chen DN, Liu XG, Yue YM, Zhang WD, Wang PX (2006) Dispersion copolymerization of acrylamide with quaternary ammonium cationic monomer in aqueous salts solution. Eur Polym J 42(6):1284–1297CrossRef
32.
Abdollahi Z, Frounchi M, Dadbin S (2011) Synthesis, characterization and comparison of PAM, cationic PDMC and P(AM–DMC) based on solution polymerization. J Ind Eng Chem 17(3):580–586CrossRef
33.
Zheng HL, Sun YJ, Zhu CJ, Guo JS, Zhao C, Liao Y, Guan QQ (2013) UV-initiated polymerization of hydrophobically associating cationic flocculants: synthesis, characterization, and dewatering properties. Chem Eng J 234:318–326CrossRef
34.
Feng L, Zheng HL, Gao BY, Zhao CL, Zhang SX, Chen N (2017) Enhancement of textile-dyeing sludge dewaterability using a novel cationic polyacrylamide: role of cationic block structures. RSC Adv 7(19):11626–11635CrossRef
35.
Li JM, Hu CS, Shao JM, Li HJ, Li PY, Li XC, He WD (2017) Fabricating ternary hydrogels of P(AM-co-DMAEMA)/PVA/beta-CD based on multiple physical crosslinkage. Polymer 119:152–159CrossRef
36.
Wan XF, Li YM, Wang XJ, Chen SL, Gu XY (2007) Synthesis of cationic guar gum-graft-polyacrylamide at low temperature and its flocculating properties. Eur Polym J 43(8):3655–3661CrossRef
37.
Zheng HL, Ma JY, Zhu CJ, Zhang Z, Liu LW, Sun YJ, Tang XM (2014) Synthesis of anion polyacrylamide under UV initiation and its application in removing dioctyl phthalate from water through flocculation process. Sep Purif Technol 123:35–44CrossRef
38.
Liao Y, Zheng HL, Qian L, Sun YJ, Dai L, Xue WW (2014) UV-initiated polymerization of hydrophobically associating cationic polyacrylamide modified by a surface-active monomer: a comparative study of synthesis, characterization, and sludge dewatering performance. Ind Eng Chem Res 53(27):11193–11203CrossRef
39.
Zheng HL, Feng L, Gao BY, Zhou YH, Zhang SX, Xu BC (2017) Effect of the cationic block structure on the characteristics of sludge flocs formed by charge neutralization and patching. Materials 10(5):487CrossRef
40.
Niu MQ, Zhang WJ, Wang DS, Chen Y, Chen RL (2013) Correlation of physicochemical properties and sludge dewaterability under chemical conditioning using inorganic coagulants. Bioresour Technol 144:337–343CrossRef
41.
Chen Q, Wang YL (2015) Influence of single- and dual-flocculant conditioning on the geometric morphology and internal structure of activated sludge. Powder Technol 270:1–9CrossRef
42.
Chakraborti RK, Atkinson JF, Van Benschoten JE (2000) Characterization of alum floc by image analysis. Environ Sci Technol 34(18):3969–3976CrossRef
43.
Jarvis P, Jefferson B, Gregory J, Parsons SA (2005) A review of floc strength and breakage. Water Res 39(14):3121–3137CrossRef
44.
Zhao YX, Gao BY, Qi QB, Wang Y, Phuntsho S, Kim JH, Yue QY, Li Q, Shon HK (2013) Cationic polyacrylamide as coagulant aid with titanium tetrachloride for low molecule organic matter removal. J Hazard Mater 258(6):84–92CrossRef
Metadaten
Titel
Hydrophobic modification of cationic microblocked polyacrylamide and its enhanced flocculation performance for oily wastewater treatment
verfasst von
Yuhao Zhou
Huaili Zheng
Yaoyao Huang
Xinyu Zheng
Zenan Liu
Yanyan An
Chun Zhao
Yongzhi Liu
Publikationsdatum
09.04.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03601-w

Weitere Artikel der Ausgabe 13/2019

Journal of Materials Science 13/2019 Zur Ausgabe

Metals

Texture control of Inconel 718 superalloy in laser additive manufacturing by an external magnetic field

Energy materials

Reduced graphene oxide@CoSe2 interlayer as anchor of polysulfides for high properties of lithium–sulfur battery

Energy materials

Composite solid electrolyte PEO/SN/LiAlO2 for a solid-state lithium battery

Computation and theory

Defining the optimal morphology of Rhn nanoparticles for efficient hydrazine adsorption: a DFT-D3 study

Materials for life sciences

High sensitivity detection of human serum albumin using a novel magnetoelastic immunosensor

Metals

Correlation between homogenization treatment and subsequent hot extrusion of Al–Mg–Si alloy

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise