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Journal of Materials Science
Erschienen in: Journal of Materials Science 18/2016

16.06.2016 | Original Paper

Hypercrosslinked polymers: controlled preparation and effective adsorption of aniline

verfasst von: Yin Liu, Xinlong Fan, Xiangkun Jia, Baoliang Zhang, Hepeng Zhang, Aibo Zhang, Qiuyu Zhang

Erschienen in: Journal of Materials Science | Ausgabe 18/2016

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Abstract

A series of microporous polymers was produced via the self-condensation of dichloroxylene which is a typical bischloromethyl monomer for a one-step synthetic process. The influences of experimental conditions including type of solvent, reaction time, and addition amount of catalyst on the polymer properties were systematically investigated. The results showed that Brunauer–Emmett–Teller (BET) specific surface areas and pore volumes of the hypercrosslinked polymers (HCPs) increased rapidly as the increase of reaction time at first and then remained nearly constant. In addition, there is a threshold concentration of catalyst for producing HCPs with high BET specific surface areas and big pore volumes. Under optimal reaction conditions, when 1, 2-dichloroethane was used as solvent, reaction time was 21 h and the molar ratio of catalyst to dichloroxylene was one; the microporous polymer with maximum BET specific surface area of up to 1446.32 m2/g was obtained. Furthermore, the adsorption performance of the as-prepared HCPs was studied using aniline as model adsorbate. The adsorption of aniline followed a pseudo-second-order model, and the adsorption isotherm was proved to fit the Langmuir adsorption model (R 2 > 0.99). The maximum adsorption capacity of aniline could reach 769.23 mg/g at 20 °C.
Vorheriger Artikel Carbon nanotube-reinforced glass fiber epoxy composite laminates exposed to hygrothermal conditioning
Nächster Artikel Electrospinning and electrospraying techniques for designing novel antibacterial poly(3-hydroxybutyrate)/zinc oxide nanofibrous composites

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Literatur
1.
Xu S, Luo Y, Tan B (2013) Recent development of hypercrosslinked microporous organic polymers. Macromol Rapid Commun 34:471–484CrossRef
2.
Abbott LJ, Colina CM (2014) Formation of microporosity in hyper-cross-linked polymers. Macromolecules 47:5409–5415CrossRef
3.
Wickramaratne NP, Jaroniec M (2013) Activated carbon spheres for CO2 adsorption. ACS Appl Mat Interfaces 5:1849–1855CrossRef
4.
Hao W, Björkman E, Lilliestrale M, Hedin N (2013) Activated carbons prepared from hydrothermally carbonized waste biomass used as adsorbents for CO2. Appl Energy 112:526–532CrossRef
5.
Chen B, Xiang S, Qian G (2010) Metal-organic frameworks with functional pores for recognition of small molecules. Acc Chem Res 43:1115–1124CrossRef
6.
Ratvijitvech T, Dawson R, Laybourn A, Khimyak YZ, Adams DJ, Cooper AI (2014) Post-synthetic modification of conjugated microporous polymers. Polymer 55:321–325CrossRef
7.
Dang D, Wu P, He C, Xie Z, Duan C (2010) Homochiral metal-organic frameworks for heterogeneous asymmetric catalysis. JACS 132:14321–14323CrossRef
8.
Xu C, Hedin N (2013) Synthesis of microporous organic polymers with high CO2-over-N2 selectivity and CO2 adsorption. J Mater Chem A 1:3406–3414CrossRef
9.
Hu L, Pasta M, Mantia FL, Cui L, Jeong S, Deshazer HD, Choi JW, Han SM, Cui Y (2010) Stretchable, porous, and conductive energy textiles. Nano Lett 10:708–714CrossRef
10.
Dawson R, Stöckel E, Holst JR, Adams DJ, Cooper AI (2011) Microporous organic polymers for carbon dioxide capture. Energy Environ Sci 4:4239–4245CrossRef
11.
Wen Q, Zhou TY, Zhao QL, Fu J, Ma Z, Zhao X (2015) A triptycene-based microporous organic polymer bearing tridentate ligands and its application in suzuki-miyaura cross-coupling reaction. Macromol Rapid Commun 36:413–418CrossRef
12.
Chen Q, Liu DP, Luo M, Feng LJ, Zhao YC, Han BH (2014) Nitrogen-containing microporous conjugated polymers via carbazole-based oxidative coupling polymerization: preparation, porosity, and gas uptake. Small 10(2):308–315CrossRef
13.
Wang J, Liu Q (2014) An efficient one-step condensation and activation strategy to synthesize porous carbons with optimal micropore sizes for highly selective CO2 adsorption. Nanoscale 6:4148–4156CrossRef
14.
Wu D, Xu F, Sun B, Fu R, He H, Matyjaszewski K (2012) Design and preparation of porous polymers. Chem Rev 112:3959–4015CrossRef
15.
McKeown NB (2012) Polymers of intrinsic microporosity. ISRN Mater Sci 2012:1–16CrossRef
16.
Tsyurupa M, Davankov V (2006) Porous structure of hypercrosslinked polystyrene: state-of-the-art mini-review. React Funct Polym 66:768–779CrossRef
17.
Huang J, Zhou X, Turner SR (2015) Nanoporous hypercrosslinked polymers containing Tg enhancing comonomers. Polymer 59:42–48CrossRef
18.
Weng X, Baez JE, Khiterer M, Hoe MY, Bao Z, Shea KJ (2015) Chiral polymers of intrinsic microporosity: selective membrane permeation of enantiomers. Angew Chem Int Ed 54:11214–11218CrossRef
19.
Cheng G, Bonillo B, Sprick RS, Adams DJ, Hasell T, Cooper AI (2014) Conjugated polymers of intrinsic microporosity (C-PIMs). Adv Funct Mater 24:5219–5224CrossRef
20.
Zhuang X, Gehrig D, Forler N, Liang H, Wagner M, Hansen MR, Laquai F, Zhang F, Feng X (2015) Conjugated microporous polymers with dimensionality-controlled heterostructures for green energy devices. Adv Mater 27:3789–3796CrossRef
21.
Zhang Q, Zhang S, Li S (2012) Novel functional organic network containing quaternary phosphonium and tertiary phosphorus. Macromolecules 45:2981–2988CrossRef
22.
Zhu Y, Long H, Zhang W (2013) Imine-linked porous polymer frameworks with high small gas (H2, CO2, CH4, C2H2) uptake and CO2/N2 selectivity. Chem Mater 25:1630–1635CrossRef
23.
Arab P, Rabbani MG, Sekizkardes AK, İslamoğlu T, El Kaderi HM (2014) Copper (I)-catalyzed synthesis of nanoporous azo-linked polymers: impact of textural properties on gas storage and selective carbon dioxide capture. Chem Mater 26:1385–1392CrossRef
24.
Peng Y, Krungleviciute V, Eryazici I, Hupp JT, Farha OK, Yildirim T (2013) Methane storage in metal-organic frameworks: current records, surprise findings, and challenges. J Am Chem Soc 135:11887–11894CrossRef
25.
Ma Y, Zhou Q, Li A, Shuang C, Shi Q, Zhang M (2014) Preparation of a novel magnetic microporous adsorbent and its adsorption behavior of p-nitrophenol and chlorotetracycline. J Hazard Mater 266:84–93CrossRef
26.
Kuhn P, Antonietti M, Thomas A (2008) Porous, covalent triazine-based frameworks prepared by ionothermal synthesis. Angew Chem Int Ed 47:3450–3453CrossRef
27.
Lu AH, Hao GP (2013) Porous materials for carbon dioxide capture. Annu. Rep Prog Chem Sect A: Inorg. Chem 109:484–503CrossRef
28.
Germain J, Fréchet JM, Svec F (2007) Hypercrosslinked polyanilines with nanoporous structure and high surface area: potential adsorbents for hydrogen storage. J Mater Chem 17:4989–4997CrossRef
29.
Davankov V, Tsyurupa M (1990) Structure and properties of hypercrosslinked polystyrene-the first representative of a new class of polymer networks. React Polym 13:27–42CrossRef
30.
Ahn JH, Jang JE, Oh CG, Ihm SK, Cortez J, Sherrington DC (2006) Rapid generation and control of microporosity, bimodal pore size distribution, and surface area in Davankov-type hyper-cross-linked resins. Macromolecules 39:627–632CrossRef
31.
Li B, Gong R, Luo Y, Tan B (2011) Tailoring the pore size of hypercrosslinked polymers. Soft Matter 7:10910–10916CrossRef
32.
Zeng SZ, Guo L, He Q, Chen Y, Jiang P, Shi J (2010) Facile one-pot synthesis of nanoporous hypercrosslinked hydroxybenzene formaldehyde resins with high surface area and adjustable pore texture. Microporous Mesoporous Mater 131:141–147CrossRef
33.
Martín CF, Stöckel E, Clowes R, Adams DJ, Cooper AI, Pis JJ, Rubiera F, Pevida C (2011) Hypercrosslinked organic polymer networks as potential adsorbents for pre-combustion CO2 capture. J Mater Chem 21:5475–5483CrossRef
34.
Li B, Gong R, Wang W, Huang X, Zhang W, Li H, Hu C, Tan B (2011) A new strategy to microporous polymers: knitting rigid aromatic building blocks by external cross-linker. Macromolecules 44:2410–2414CrossRef
35.
Dawson R, Stevens LA, Drage TC, Snape CE, Smith MW, Adams DJ, Cooper AI (2012) Impact of water coadsorption for carbon dioxide capture in microporous polymer sorbents. JACS 134:10741–10744CrossRef
36.
Yao S, Yang X, Yu M, Zhang Y, Jiang JX (2014) High surface area hypercrosslinked microporous organic polymer networks based on tetraphenylethylene for CO2 capture. J Mater Chem A 2:8054–8059CrossRef
37.
Liu G, Wang Y, Shen C, Ju Z, Yuan D (2015) A facile synthesis of microporous organic polymers for efficient gas storage and separation. J Mater Chem A 3:3051–3058CrossRef
38.
Luo Y, Li B, Wang W, Wu K, Tan B (2012) Hypercrosslinked aromatic heterocyclic microporous polymers: a new class of highly selective CO2 capturing materials. Adv Mater 24:5703–5707CrossRef
39.
Zhang Y, Li Y, Wang F, Zhao Y, Zhang C, Wang X, Jiang JX (2014) Hypercrosslinked microporous organic polymer networks derived from silole-containing building blocks. Polymer 55:5746–5750CrossRef
40.
Gonell S, Poyatos M, Peris E (2014) Main-chain organometallic microporous polymers bearing triphenylene-tris (N-heterocyclic carbene)-gold species: catalytic properties. Chem Eur J 20:5746–5751CrossRef
41.
Saleh M, Lee HM, Kemp KC, Kim KS (2014) Highly stable CO2/N2 and CO2/CH4 selectivity in hyper-cross-linked heterocyclic porous polymers. ACS Appl Mat Interfaces 6:7325–7333CrossRef
42.
Xu S, Song K, Li T, Tan B (2015) Palladium catalyst coordinated in knitting N-heterocyclic carbene porous polymers for efficient Suzuki-Miyaura coupling reactions. J. Mater. Chem. A 3:1272–1278CrossRef
43.
Karthikeyan S, Viswanathan K, Boopathy R, Maharaja P, Sekaran G (2015) Three dimensional electro catalytic oxidation of aniline by boron doped mesoporous activated carbon. J Ind Eng Chem 21:942–950CrossRef
44.
Liu YB, Qu D, Wen YJ, Ren HJ (2015) Low-temperature biodegradation of aniline by freely suspended and magnetic modified Pseudomonas migulae AN-1. Appl Microbiol Biotechnol 99:5317–5326CrossRef
45.
Li C, Zhang X, Hao X, Wang M, Ding C, Wang Z, Wang Y, Guan G, Abudula A (2015) Efficient recovery of high-purity aniline from aqueous solutions using pervaporation-fractional condensation system. AlChE J 61:4445–4455CrossRef
46.
Jiang L, Liu L, Xiao S, Chen J (2016) Preparation of a novel manganese oxide-modified diatomite and its aniline removal mechanism from solution. Chem Eng J 284:609–619CrossRef
47.
Amatore C, Gaubert F, Jutand A, Utley JH (1996) Mechanistic and synthetic aspects of a novel route to poly-p-xylylene (PPX) via nickel complex catalysed electropolymerisation of 1, 4-bis (chloromethyl) benzene. J Chem Soc Perkin Trans 2:2447–2452CrossRef
48.
Abbott LJ, Colina CM (2011) Atomistic structure generation and gas adsorption simulations of microporous polymer networks. Macromolecules 44:4511–4519CrossRef
49.
Yang Sl WuZH, Yang W, Yang MB (2008) Thermal and mechanical properties of chemical crosslinked polylactide (PLA). Polym. Test 27:957–963CrossRef
50.
Tang L, Zhang S, Zeng GM (2015) Rapid adsorption of 2, 4-dichlorophenoxyacetic acid by iron oxide nanoparticles-doped carboxylic ordered mesoporous carbon. J Colloid Interface Sci 445:1–8CrossRef
51.
Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465CrossRef
Metadaten
Titel
Hypercrosslinked polymers: controlled preparation and effective adsorption of aniline
verfasst von
Yin Liu
Xinlong Fan
Xiangkun Jia
Baoliang Zhang
Hepeng Zhang
Aibo Zhang
Qiuyu Zhang
Publikationsdatum
16.06.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 18/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0118-y

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