Skip to main content
Erschienen in: Journal of Materials Science 7/2018

20.12.2017 | Energy materials

Improved electrochemical performance of bagasse and starch-modified LiNi0.5Mn0.3Co0.2O2 materials for lithium-ion batteries

verfasst von: Caijian Zhu, Jun Chen, Shanshan Liu, Boming Cheng, Yong Xu, Pengwei Zhang, Qian Zhang, Yutao Li, Shengwen Zhong

Erschienen in: Journal of Materials Science | Ausgabe 7/2018

Einloggen

Aktivieren Sie unsere intelligente Suche um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Organic carbon-coated LiNi0.5Mn0.3Co0.2O2 materials are prepared by mixing 2 or 5% starch or bagasse evenly with the synthesized LiNi0.5Mn0.3Co0.2O2 material and calcining for 10 h at 750 °C. The microstructures and electrochemical performance are investigated by X-ray diffraction, scanning electron microscopy, carbon/sulfur analysis, transmission electron microscopy and electrochemical testing. The results indicate that the organic carbon coated on the surface of LiNi0.5Mn0.3Co0.2O2 material does not change the surface morphology and crystal structure, but greatly improves the conductivity, rate and cycle performance of the LiNi0.5Mn0.3Co0.2O2 cathode in a Li-ion battery. The initial discharge capacity of the synthesized LiNi0.5Mn0.3Co0.2O2 material is 147.8 mAh g−1, which increases to 152.4 and 153.3 mAh g−1 for 2% starch and bagasse, respectively. After 100 cycles, the capacity retention rates are 70.7% (uncoated), 83.3% (coated with 2% starch), 90.1% (coated with 2% bagasse), 83.1% (coated with 5% starch) and 91.1% (coated with 5% bagasse). The influence of the percentage of coated carbon and its dispersion uniformity on the performance of the battery is analyzed. A small coating capacity and uniform carbon film can achieve better performance. Rational organic carbon coating technology is an effective way to improve the electrochemical performance of LiNi1−xy Mn x Co y O2-based material.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Armand M, Tarascon JM (2008) Building better batteries. Nature 451:652–657CrossRef Armand M, Tarascon JM (2008) Building better batteries. Nature 451:652–657CrossRef
2.
Zurück zum Zitat Goodenough JB, Kim Y (2010) Challenges for rechargeable Li batteries. Chem Mater 22:587–603CrossRef Goodenough JB, Kim Y (2010) Challenges for rechargeable Li batteries. Chem Mater 22:587–603CrossRef
3.
Zurück zum Zitat Hayashi T, Miyazaki T, Matsuda Y, Kuwata N, Saruwatari M (2016) Effect of lithium-ion diffusibility on interfacial resistance of LiCoO2 thin film electrode modified with lithium tungsten oxides. J Power Sources 305:46–53CrossRef Hayashi T, Miyazaki T, Matsuda Y, Kuwata N, Saruwatari M (2016) Effect of lithium-ion diffusibility on interfacial resistance of LiCoO2 thin film electrode modified with lithium tungsten oxides. J Power Sources 305:46–53CrossRef
4.
Zurück zum Zitat Yan ZQ, Yao WL, Hu L, Liu DD, Wang CD, Lee CS (2015) Progress in the preparation and application of three-dimensional graphene-based porous nanocomposites. Nanoscale 7:5563–5577CrossRef Yan ZQ, Yao WL, Hu L, Liu DD, Wang CD, Lee CS (2015) Progress in the preparation and application of three-dimensional graphene-based porous nanocomposites. Nanoscale 7:5563–5577CrossRef
5.
Zurück zum Zitat Lee MJ, Lee S, Oh P, Kim Y, Cho J (2014) High performance LiMn2O4 cathode materials grown with epitaxial layered nanostructure for Li-ion batteries. Nano Lett 14:993–999CrossRef Lee MJ, Lee S, Oh P, Kim Y, Cho J (2014) High performance LiMn2O4 cathode materials grown with epitaxial layered nanostructure for Li-ion batteries. Nano Lett 14:993–999CrossRef
7.
Zurück zum Zitat Qiu S, Zhang X, Li Y, Sun T, Wang C (2016) Facile synthesis and electrochemical performances of secondary carbon-coated LiFePO4–C composite for Li-ion capacitors based on neutral aqueous electrolytes. J Mater Sci 27:7255–7264. https://doi.org/10.1007/s10854-016-4692-1 Qiu S, Zhang X, Li Y, Sun T, Wang C (2016) Facile synthesis and electrochemical performances of secondary carbon-coated LiFePO4–C composite for Li-ion capacitors based on neutral aqueous electrolytes. J Mater Sci 27:7255–7264. https://​doi.​org/​10.​1007/​s10854-016-4692-1
8.
Zurück zum Zitat Zhang X, Mauger A, Qi L, Groult H, Perrigaud L (2010) Synthesis and characterization of LiNi1/3Mn1/3Co1/3O2 by wet-chemical method. Electrochim Acta 55:6440–6449CrossRef Zhang X, Mauger A, Qi L, Groult H, Perrigaud L (2010) Synthesis and characterization of LiNi1/3Mn1/3Co1/3O2 by wet-chemical method. Electrochim Acta 55:6440–6449CrossRef
9.
Zurück zum Zitat Li D, Sasaki Y, Kageyama M, Kobayakawa K, Sato Y (2005) Structure, morphology and electrochemical properties of LiNi0.5Mn0.5−x Co x O2 prepared by solid state reaction. J Power Sources 148:85–89CrossRef Li D, Sasaki Y, Kageyama M, Kobayakawa K, Sato Y (2005) Structure, morphology and electrochemical properties of LiNi0.5Mn0.5−x Co x O2 prepared by solid state reaction. J Power Sources 148:85–89CrossRef
10.
Zurück zum Zitat Mun J, Park JH, Choi W, Benayad A, Park JH, Lee JM, Doo SG, Oh SM (2014) New dry carbon nanotube coating of over-lithiated layered oxide cathode for lithium ion batteries. J Mater Chem A 2:19670–19677CrossRef Mun J, Park JH, Choi W, Benayad A, Park JH, Lee JM, Doo SG, Oh SM (2014) New dry carbon nanotube coating of over-lithiated layered oxide cathode for lithium ion batteries. J Mater Chem A 2:19670–19677CrossRef
11.
Zurück zum Zitat Belharouak I, Sun YK, Liu J (2003) LiCo1/3Ni1/3Mn1/3O2 as a suitable cathode for high power application. J Power Sources 132:247–252CrossRef Belharouak I, Sun YK, Liu J (2003) LiCo1/3Ni1/3Mn1/3O2 as a suitable cathode for high power application. J Power Sources 132:247–252CrossRef
12.
Zurück zum Zitat Kim Y, Kim HS, Martin SW (2006) Synthesis and electrochemical characteristics of Al2O3-coated LiNi1/3Co1/3Mn1/3O2 cathode materials for lithium ion batteries. Electrochim Acta 52:1316–1322CrossRef Kim Y, Kim HS, Martin SW (2006) Synthesis and electrochemical characteristics of Al2O3-coated LiNi1/3Co1/3Mn1/3O2 cathode materials for lithium ion batteries. Electrochim Acta 52:1316–1322CrossRef
13.
Zurück zum Zitat Qiu XY, Zhuang QC, Zhang QQ, Cao R, Qiang YH (2012) Investigation of layered LiNi1/3Co1/3Mn1/3O2 cathode of lithium ion battery by electrochemical impedance spectroscopy. J Electroanal Chem 687:35–44CrossRef Qiu XY, Zhuang QC, Zhang QQ, Cao R, Qiang YH (2012) Investigation of layered LiNi1/3Co1/3Mn1/3O2 cathode of lithium ion battery by electrochemical impedance spectroscopy. J Electroanal Chem 687:35–44CrossRef
14.
Zurück zum Zitat Jouanneau J, Macneil D, Lu Z (2003) Morphology and safety of Li[Ni x Co1−2x Mn x ]O2 (0 < x < 1/2). J Electrochem Soc 150:A1299–A1304CrossRef Jouanneau J, Macneil D, Lu Z (2003) Morphology and safety of Li[Ni x Co1−2x Mn x ]O2 (0 < x < 1/2). J Electrochem Soc 150:A1299–A1304CrossRef
15.
Zurück zum Zitat Zhong SW, Lai MZ, Yao WL, Li ZC (2016) Synthesis and electrochemical properties of LiNi0.8Co x Mn0.2−x O2 positive-electrode material for lithium-ion batteries. Electrochim Acta 212:343–351CrossRef Zhong SW, Lai MZ, Yao WL, Li ZC (2016) Synthesis and electrochemical properties of LiNi0.8Co x Mn0.2−x O2 positive-electrode material for lithium-ion batteries. Electrochim Acta 212:343–351CrossRef
16.
Zurück zum Zitat Chen Y, Wang GX, Konstantinov K (2003) Synthesis and characterization of LiCo x Mn y Ni1−x−y O2 as a cathode material for secondary lithium batteries. J Power Sources 119–121:184–188CrossRef Chen Y, Wang GX, Konstantinov K (2003) Synthesis and characterization of LiCo x Mn y Ni1−xy O2 as a cathode material for secondary lithium batteries. J Power Sources 119–121:184–188CrossRef
17.
Zurück zum Zitat Verma P, Maire P, Novák P (2010) A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries. Electrochim Acta 55:6332–6341CrossRef Verma P, Maire P, Novák P (2010) A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries. Electrochim Acta 55:6332–6341CrossRef
18.
Zurück zum Zitat Li JL, Yao RM, Cao CB (2014) LiNi1, 3Co1, 3Mn1, 3O2 nanoplates with 010 active lanes exposing prepared in polyol medium as a high-performance cathode for Li-ion battery. ACS Appl Mater Interfaces 6:5075–5082CrossRef Li JL, Yao RM, Cao CB (2014) LiNi1, 3Co1, 3Mn1, 3O2 nanoplates with 010 active lanes exposing prepared in polyol medium as a high-performance cathode for Li-ion battery. ACS Appl Mater Interfaces 6:5075–5082CrossRef
19.
Zurück zum Zitat Liang CH, Liu LB, Jia Z, Dai C, Xiong Y (2015) Synergy of Nyquist and bode electrochemical impedance spectroscopy studies to particle size effect on the electrochemical properties of LiNi0.5Co0.2Mn0.3O2. Electrochim Acta 186:413–419CrossRef Liang CH, Liu LB, Jia Z, Dai C, Xiong Y (2015) Synergy of Nyquist and bode electrochemical impedance spectroscopy studies to particle size effect on the electrochemical properties of LiNi0.5Co0.2Mn0.3O2. Electrochim Acta 186:413–419CrossRef
20.
Zurück zum Zitat Cho YH, Jang D, Yoon J (2013) Thermal stability of charged LiNi0.5Co0.2Mn0.3O2 cathode for Li-ion batteries investigated by synchrotron based in situ X-ray diffraction. J Alloys Compd 562:219–223CrossRef Cho YH, Jang D, Yoon J (2013) Thermal stability of charged LiNi0.5Co0.2Mn0.3O2 cathode for Li-ion batteries investigated by synchrotron based in situ X-ray diffraction. J Alloys Compd 562:219–223CrossRef
21.
Zurück zum Zitat Wu KC, Wang F, Gao LL, Li MR, Xiao LL (2012) Effect of precursor and synthesis temperature on the structural and electrochemical properties of LiNi0.5Co0.2Mn0.3O2. Electrochim Acta 75:393–398CrossRef Wu KC, Wang F, Gao LL, Li MR, Xiao LL (2012) Effect of precursor and synthesis temperature on the structural and electrochemical properties of LiNi0.5Co0.2Mn0.3O2. Electrochim Acta 75:393–398CrossRef
23.
Zurück zum Zitat Wang J, Zhang YJ, Dong P, Xia SB (2014) Progess in surface coating of temporary cathode materials Li[Ni Co, Mn]O2 for lithium batteries. Chin J Power Sources 38:560–563 Wang J, Zhang YJ, Dong P, Xia SB (2014) Progess in surface coating of temporary cathode materials Li[Ni Co, Mn]O2 for lithium batteries. Chin J Power Sources 38:560–563
24.
Zurück zum Zitat Ding Y, Chen LH, Pan P, Du J, Wang F (2017) Nitrogen-doped carbon coated MnO nanopeapods as superior anode materials for lithium ion batteries. Appl Surf Sci 422:1113–1119CrossRef Ding Y, Chen LH, Pan P, Du J, Wang F (2017) Nitrogen-doped carbon coated MnO nanopeapods as superior anode materials for lithium ion batteries. Appl Surf Sci 422:1113–1119CrossRef
25.
Zurück zum Zitat Hua WB, Zhang JB, Zheng Z, Liu WY, Guo XD, Zhong BH, Wang YJ, Wang XL (2014) Na-doped Ni-rich LiNi0.5Co0.2Mn0.3O2 cathode material with both high rate capability and high tap density for lithium ion batteries. Dalton Trans 43:14824–14832CrossRef Hua WB, Zhang JB, Zheng Z, Liu WY, Guo XD, Zhong BH, Wang YJ, Wang XL (2014) Na-doped Ni-rich LiNi0.5Co0.2Mn0.3O2 cathode material with both high rate capability and high tap density for lithium ion batteries. Dalton Trans 43:14824–14832CrossRef
26.
Zurück zum Zitat Karan NK, Balasubramanian M, Abraham DP, Furczon MM, Pradhan DK, Saavedra-Arias JJ, Thomas R, Katiyar RS (2009) Structural characteristics and electrochemical performance of layered Li[Mn0.5−x Cr2x Ni0.5−x ]O2 cathode materials. J Power Sources 187:586–590CrossRef Karan NK, Balasubramanian M, Abraham DP, Furczon MM, Pradhan DK, Saavedra-Arias JJ, Thomas R, Katiyar RS (2009) Structural characteristics and electrochemical performance of layered Li[Mn0.5−x Cr2x Ni0.5−x ]O2 cathode materials. J Power Sources 187:586–590CrossRef
28.
Zurück zum Zitat Ni JF, Zhou HH, Chen JT (2008) Improved electrochemical performance of layered LiNi0.4Co0.2Mn0.4O2 via Li2ZrO3 coating. Electrochim Acta 53:3075–3083CrossRef Ni JF, Zhou HH, Chen JT (2008) Improved electrochemical performance of layered LiNi0.4Co0.2Mn0.4O2 via Li2ZrO3 coating. Electrochim Acta 53:3075–3083CrossRef
29.
Zurück zum Zitat Li N, Wang YP, Rao RC, Dong XZ, Zhu S (2017) The preparation and graphene surface coating NaTi2(PO4)3 as cathode material for lithium ion batteries. Appl Surf Sci 399:624–629CrossRef Li N, Wang YP, Rao RC, Dong XZ, Zhu S (2017) The preparation and graphene surface coating NaTi2(PO4)3 as cathode material for lithium ion batteries. Appl Surf Sci 399:624–629CrossRef
31.
Zurück zum Zitat Yang K, Fan LZ, Guo J (2012) Significant improvement of electrochemical properties of AlF3-coated LiNi0.5Co0.2Mn0.3O2 cathode materials. Electrochim Acta 63:363–368CrossRef Yang K, Fan LZ, Guo J (2012) Significant improvement of electrochemical properties of AlF3-coated LiNi0.5Co0.2Mn0.3O2 cathode materials. Electrochim Acta 63:363–368CrossRef
33.
Zurück zum Zitat Huang YH, Chou HL, Wang FM, Hwang BJ (2013) Synergy between experiment and simulation in describing the electro-chemical performance of Mg-doped LiNi x Co y Mn z O2 cathode material of lithium ion battery. Int J Electrochem Sci 8:8005–8018 Huang YH, Chou HL, Wang FM, Hwang BJ (2013) Synergy between experiment and simulation in describing the electro-chemical performance of Mg-doped LiNi x Co y Mn z O2 cathode material of lithium ion battery. Int J Electrochem Sci 8:8005–8018
34.
Zurück zum Zitat Woo SW, Myung ST, Bang H, Kim DW, Sun YK (2009) Improvement of electrochemical and thermal properties of Li[Ni0.8Co0.1Mn0.1]O2 positive electrode materials by multiple metal (Al, Mg) substitution. Electrochim Acta 54:3851–3856CrossRef Woo SW, Myung ST, Bang H, Kim DW, Sun YK (2009) Improvement of electrochemical and thermal properties of Li[Ni0.8Co0.1Mn0.1]O2 positive electrode materials by multiple metal (Al, Mg) substitution. Electrochim Acta 54:3851–3856CrossRef
35.
Zurück zum Zitat Zhong SK, Wang Y, Liu JQ, Wan K (2011) Synthesis and electrochemical properties of Ce-doped LiNi1/3Mn1/3O2 cathode material for Li-ion batteries. J Rare Earths 29:891–895CrossRef Zhong SK, Wang Y, Liu JQ, Wan K (2011) Synthesis and electrochemical properties of Ce-doped LiNi1/3Mn1/3O2 cathode material for Li-ion batteries. J Rare Earths 29:891–895CrossRef
36.
Zurück zum Zitat Wang D, Li XH, Wang ZX, Guo HJ, Xu Y, Fan YL, Ru JJ (2015) Role of zirconium dopant on the structure and high voltage electrochemical performances of LiNi0.5Co0.2Mn0.3O2 cathode materials for lithium ion batteries. Electrochim Acta 188:48–56CrossRef Wang D, Li XH, Wang ZX, Guo HJ, Xu Y, Fan YL, Ru JJ (2015) Role of zirconium dopant on the structure and high voltage electrochemical performances of LiNi0.5Co0.2Mn0.3O2 cathode materials for lithium ion batteries. Electrochim Acta 188:48–56CrossRef
37.
Zurück zum Zitat Liu J, Reeja-Jayan B, Manthiram A (2010) Conductive surface modification with aluminum of high capacity layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathodes. J Phys Chem C 114:9528–9533CrossRef Liu J, Reeja-Jayan B, Manthiram A (2010) Conductive surface modification with aluminum of high capacity layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathodes. J Phys Chem C 114:9528–9533CrossRef
39.
Zurück zum Zitat Zhang S, Deng C, Fu BL (2010) Synthetic optimization of spherical LiCo1/3Ni1/3Mn1/3O2 prepared by a carbonate co-precipitation method. Powder Technol 198:373–380CrossRef Zhang S, Deng C, Fu BL (2010) Synthetic optimization of spherical LiCo1/3Ni1/3Mn1/3O2 prepared by a carbonate co-precipitation method. Powder Technol 198:373–380CrossRef
40.
Zurück zum Zitat Deng C, Liu L, Zhou W (2008) Effect of synthesis condition on the structure and electrochemical properties LiCo1/3Ni1/3Mn1/3O2 prepared by hydroxide co-precipitation method. Electrochim Acta 53:2441–2447CrossRef Deng C, Liu L, Zhou W (2008) Effect of synthesis condition on the structure and electrochemical properties LiCo1/3Ni1/3Mn1/3O2 prepared by hydroxide co-precipitation method. Electrochim Acta 53:2441–2447CrossRef
41.
Zurück zum Zitat Han YM, Zhang ZF, Zhang LB, Peng JH, Fu MB, Du J (2013) Influence of carbon coating prepared by microwave pyrolysis on properties of LiNi1/3Mn1/3Co1/3O2. Trans Nonferrous Met Soc China 23:2971–2976CrossRef Han YM, Zhang ZF, Zhang LB, Peng JH, Fu MB, Du J (2013) Influence of carbon coating prepared by microwave pyrolysis on properties of LiNi1/3Mn1/3Co1/3O2. Trans Nonferrous Met Soc China 23:2971–2976CrossRef
42.
Zurück zum Zitat Xiong XH, Ding D, Wang ZX, Huang B, Guo HJ, Li XH (2014) Surface modification of LiNi0.8Co0.1Mn0.1O2 with conducting polypyrrole. J Solid State Electrochem 18:2619–2624CrossRef Xiong XH, Ding D, Wang ZX, Huang B, Guo HJ, Li XH (2014) Surface modification of LiNi0.8Co0.1Mn0.1O2 with conducting polypyrrole. J Solid State Electrochem 18:2619–2624CrossRef
43.
Zurück zum Zitat Churikov AV, Romanova VO (2013) Determination of diffusion coefficient of lithium in substituted LiMn1.95Cr0.05O4 spinel using impedance technique. Russ J Electrochem 49:272–277CrossRef Churikov AV, Romanova VO (2013) Determination of diffusion coefficient of lithium in substituted LiMn1.95Cr0.05O4 spinel using impedance technique. Russ J Electrochem 49:272–277CrossRef
44.
Zurück zum Zitat Zou BK, Ding CX, Chen CH (2014) Research progress in ternary cathode materials Li(Ni Co, Mn)O2 for lithium ion batteries. Sci Sin Chim 44:1104–1115 Zou BK, Ding CX, Chen CH (2014) Research progress in ternary cathode materials Li(Ni Co, Mn)O2 for lithium ion batteries. Sci Sin Chim 44:1104–1115
Metadaten
Titel
Improved electrochemical performance of bagasse and starch-modified LiNi0.5Mn0.3Co0.2O2 materials for lithium-ion batteries
verfasst von
Caijian Zhu
Jun Chen
Shanshan Liu
Boming Cheng
Yong Xu
Pengwei Zhang
Qian Zhang
Yutao Li
Shengwen Zhong
Publikationsdatum
20.12.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 7/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1926-4

Weitere Artikel der Ausgabe 7/2018

Journal of Materials Science 7/2018 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.