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Journal of Materials Science
Erschienen in: Journal of Materials Science 14/2019

11.04.2019 | Energy materials

Improved film morphology of (CH3NH3)3Bi2I9 via cation displacement approach for lead-free perovskite solar cells

verfasst von: Fengzhu Li, Haochen Fan, Pengcheng Wang, Xiangjun Li, Yanlin Song, Ke-Jian Jiang

Erschienen in: Journal of Materials Science | Ausgabe 14/2019

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Abstract

Methylammonium bismuth iodide (MA3Bi2I9) has been recently investigated as a light absorber in lead-free perovskite solar cells. However, the MA3Bi2I9 film fabricated via conventional one-step spin coating methods usually has poor surface morphology, limiting the device performance. Herein, a cation displacement approach was employed for the fabrication of MA3Bi2I9 film, where (CH3CH2CH2NH3)3Bi2I9 (PA3Bi2I9) film was first deposited from a solution containing CH3CH2CH2NH3I and BiI3 and then transformed into MA3Bi2I9 film in a methylamine atmosphere. With the technique, the MA3Bi2I9 film was realized with smooth, uniform, and compact surface morphology. Using the MA3Bi2I9 film as a light absorber, a mesoporous photovoltaic device was fabricated with a power conversion efficiency of 0.33%, which is about two times higher than the value (0.15%) obtained for the one-step spin coating MA3Bi2I9 device. Moreover, the facile film fabrication strategy utilized in this work paves the way for high reproducibility of lead-free organic–inorganic halide films and devices.
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Metadaten
Titel
Improved film morphology of (CH3NH3)3Bi2I9 via cation displacement approach for lead-free perovskite solar cells
verfasst von
Fengzhu Li
Haochen Fan
Pengcheng Wang
Xiangjun Li
Yanlin Song
Ke-Jian Jiang
Publikationsdatum
11.04.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 14/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03582-w

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