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Erschienen in: Colloid and Polymer Science 9/2011

01.06.2011 | Original Contribution

Improvement in hydrophobicity of polyester fabric finished with fluorochemicals via aminolysis and comparing with nano-silica particles

verfasst von: Zahra Mazrouei-Sebdani, Akbar Khoddami, Shadpour Mallakpour

Erschienen in: Colloid and Polymer Science | Ausgabe 9/2011

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Abstract

For the fabrication of the “lotus-type” fibers, a combination of two major requirements, low surface energy and the magnified of the degree of roughness, should be utilized. In this research, the possible surface roughening effect of aminolysis of the polyester fibers was applied to manipulated surface topography while fluorocarbon polymer layer generates low surface energy. The results were compared with the method that created variety of surface roughness by changing the size of the nano-silica particles using the 3M water/oil repellency test, sliding (tilt) angle, microscopy (SEM), decay of hydrophobicity, self-cleaning, and tensile properties. The results indicated the usefulness of the conventional polyester aminolysis process to control surface roughness for enhancement of fabric hydrophobicity with sliding angle as low as 12°.

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Literatur
1.
Zurück zum Zitat Minghua Yu, Guotuan Gu, Meng WD, Qing FL (2007) Superhydrophobic cotton fabric coating based on a complex layer of silica nanoparticles and perfluorooctylated quaternary ammonium silane coupling agent. Appl Surf Sci 253:3669–3673CrossRef Minghua Yu, Guotuan Gu, Meng WD, Qing FL (2007) Superhydrophobic cotton fabric coating based on a complex layer of silica nanoparticles and perfluorooctylated quaternary ammonium silane coupling agent. Appl Surf Sci 253:3669–3673CrossRef
2.
Zurück zum Zitat Feng L, Zhang Z, Mai Z, Ma Y, Liu B, Jiang L, Zhu D (2004) A superhydrophobic and superoleophilic coating mesh film for the separation of oil and water. Angew Chem Int Ed 43:2012–2014CrossRef Feng L, Zhang Z, Mai Z, Ma Y, Liu B, Jiang L, Zhu D (2004) A superhydrophobic and superoleophilic coating mesh film for the separation of oil and water. Angew Chem Int Ed 43:2012–2014CrossRef
3.
Zurück zum Zitat Gau H, Herminghaus S, Lenz P, Lipowsky R (1999) Liquid morphologies on structured surfaces: from microchannels to microchips. Science 283:46–49CrossRef Gau H, Herminghaus S, Lenz P, Lipowsky R (1999) Liquid morphologies on structured surfaces: from microchannels to microchips. Science 283:46–49CrossRef
4.
Zurück zum Zitat Feng X, Jiang L (2006) Design and creation of superwetting/antiwetting surfaces. Adv Mater 18:3063–3078CrossRef Feng X, Jiang L (2006) Design and creation of superwetting/antiwetting surfaces. Adv Mater 18:3063–3078CrossRef
5.
Zurück zum Zitat Yoon YI, Moon HS, Lyoo WS, Lee TS, Park WH (2009) Superhydrophobicity of cellulose triacetate fibrous mats produced by electrospinning and plasma treatment. Carbohydr Polym 75:246–250CrossRef Yoon YI, Moon HS, Lyoo WS, Lee TS, Park WH (2009) Superhydrophobicity of cellulose triacetate fibrous mats produced by electrospinning and plasma treatment. Carbohydr Polym 75:246–250CrossRef
6.
Zurück zum Zitat Zhao N, Xie Q, Kuang X, Wang S, Li Y, Lu X, Tan S, Shen J, Zhang XL, Zhang Y, Xu J, Han CC (2007) A novel ultra-hydrophobic surface: statically non-wetting but dynamically non-sliding. Adv Funct Mater 17:2739–2745CrossRef Zhao N, Xie Q, Kuang X, Wang S, Li Y, Lu X, Tan S, Shen J, Zhang XL, Zhang Y, Xu J, Han CC (2007) A novel ultra-hydrophobic surface: statically non-wetting but dynamically non-sliding. Adv Funct Mater 17:2739–2745CrossRef
7.
Zurück zum Zitat Bhushan B, Jung YC (2008) Wetting, adhesion and friction of superhydrophobic and hydrophilic leaves and fabricated micro/nano patterned surfaces. J Phys Condens Matter 20:24, 225010 Bhushan B, Jung YC (2008) Wetting, adhesion and friction of superhydrophobic and hydrophilic leaves and fabricated micro/nano patterned surfaces. J Phys Condens Matter 20:24, 225010
8.
Zurück zum Zitat Zhang BT, Liu BL, Deng XB, Cao SS, Hou XH, Chen HL (2008) Fabricating superhydrophobic surfaces by molecular accumulation of polysiloxane on the wool textile finishing. Prog Colloid Polym Sci 286:453–457 Zhang BT, Liu BL, Deng XB, Cao SS, Hou XH, Chen HL (2008) Fabricating superhydrophobic surfaces by molecular accumulation of polysiloxane on the wool textile finishing. Prog Colloid Polym Sci 286:453–457
9.
Zurück zum Zitat Zhang X, Shi F, Niu J, Jiang Y, Wang Z (2008) Superhydrophobic surfaces: from structural control to functional application. J Mater Chem 18:621–633CrossRef Zhang X, Shi F, Niu J, Jiang Y, Wang Z (2008) Superhydrophobic surfaces: from structural control to functional application. J Mater Chem 18:621–633CrossRef
10.
Zurück zum Zitat Luzinov I, Brown P, Chumanov G, Minko S (2004). National Textile Centre annual report. Ultrahydrophobic fibers: lotus approach. Project number: C04-CL06 Luzinov I, Brown P, Chumanov G, Minko S (2004). National Textile Centre annual report. Ultrahydrophobic fibers: lotus approach. Project number: C04-CL06
11.
Zurück zum Zitat Nishino N, Meguro M, Nakamae K, Matsushita M, Ueda Y (1999) The lowest surface free energy based on -CF3 alignment. Langmuir 15:4321–4323CrossRef Nishino N, Meguro M, Nakamae K, Matsushita M, Ueda Y (1999) The lowest surface free energy based on -CF3 alignment. Langmuir 15:4321–4323CrossRef
12.
Zurück zum Zitat Youngblood JP, McCarthy TJ (1999) Ultra-hydrophobic polymer surfaces prepared by simultaneous ablation of polypropylene and sputtering of poly(tetrafluoroethylene) using radio frequency plasma. Macromolecules 32(20):6800–6806CrossRef Youngblood JP, McCarthy TJ (1999) Ultra-hydrophobic polymer surfaces prepared by simultaneous ablation of polypropylene and sputtering of poly(tetrafluoroethylene) using radio frequency plasma. Macromolecules 32(20):6800–6806CrossRef
13.
Zurück zum Zitat Minko S, Müller M, Motornov M, Nitschke M, Grundke K, Stamm M (2003) Two-level structured self-adaptive surfaces with reversibly tunable properties. J Am Chem Soc 125(13):3896–3900CrossRef Minko S, Müller M, Motornov M, Nitschke M, Grundke K, Stamm M (2003) Two-level structured self-adaptive surfaces with reversibly tunable properties. J Am Chem Soc 125(13):3896–3900CrossRef
14.
Zurück zum Zitat Yoshimitsu Z, Nakajima A, Watanabe T, Hashimoto K (2002) Effects of surface structure on the hydrophobicity and sliding behaviors of water droplets. Langmuir 18:5818–5822CrossRef Yoshimitsu Z, Nakajima A, Watanabe T, Hashimoto K (2002) Effects of surface structure on the hydrophobicity and sliding behaviors of water droplets. Langmuir 18:5818–5822CrossRef
15.
Zurück zum Zitat Morra M, Occhiello E, Grabassi F (1989) Contact angle hysteresis in oxygen plasma treated poly (tetrafluoroethylene). Langmuir 5:872–876CrossRef Morra M, Occhiello E, Grabassi F (1989) Contact angle hysteresis in oxygen plasma treated poly (tetrafluoroethylene). Langmuir 5:872–876CrossRef
16.
Zurück zum Zitat Veeramasuneni S, Drelich J, Miller JD, Yamauchi G (1997) Hydrophobicity of ion-plated PTFE coatings. Prog Org Coat 15:265–270CrossRef Veeramasuneni S, Drelich J, Miller JD, Yamauchi G (1997) Hydrophobicity of ion-plated PTFE coatings. Prog Org Coat 15:265–270CrossRef
17.
Zurück zum Zitat Chen W, Fadeev AY, Hsieh MC, Öner D, Youngblood J, McCarthy TJ (1999) Ultra-hydrophobic and ultra-lyophobic surfaces: some comments and examples. Langmuir 15(10):3395–3399CrossRef Chen W, Fadeev AY, Hsieh MC, Öner D, Youngblood J, McCarthy TJ (1999) Ultra-hydrophobic and ultra-lyophobic surfaces: some comments and examples. Langmuir 15(10):3395–3399CrossRef
18.
Zurück zum Zitat Lee HJ, Michielsen S (2007) Preparation of a superhydrophobic rough surface. J Polym Sci B Polym Phys 45:253–261CrossRef Lee HJ, Michielsen S (2007) Preparation of a superhydrophobic rough surface. J Polym Sci B Polym Phys 45:253–261CrossRef
19.
Zurück zum Zitat Miwa M, Nakajima A, Fujishima A, Hashimoto K, Watanabe T (2000) Effects of the surface roughness on sliding angles of water droplets on superhydrophobic surfaces. Langmuir 16(13):5754–5760CrossRef Miwa M, Nakajima A, Fujishima A, Hashimoto K, Watanabe T (2000) Effects of the surface roughness on sliding angles of water droplets on superhydrophobic surfaces. Langmuir 16(13):5754–5760CrossRef
20.
Zurück zum Zitat Satoh K, Nakazumi H (2003) Preparation of super-water-repellent fluorinated inorganic-organic coating films on nylon66 by the sol-gel method using microphase separation. J Sol-Gel Sci Technol 27:327–332CrossRef Satoh K, Nakazumi H (2003) Preparation of super-water-repellent fluorinated inorganic-organic coating films on nylon66 by the sol-gel method using microphase separation. J Sol-Gel Sci Technol 27:327–332CrossRef
21.
Zurück zum Zitat Ma M, Mao Y, Gupta M, Gleason KK, Rutledge GC (2005) Superhydrophobic fabrics produced by electrospinning and chemical vapor deposition. Macromolecules 38:9742–9748CrossRef Ma M, Mao Y, Gupta M, Gleason KK, Rutledge GC (2005) Superhydrophobic fabrics produced by electrospinning and chemical vapor deposition. Macromolecules 38:9742–9748CrossRef
22.
Zurück zum Zitat Ma M, Hill RM, Lowery JL, Fridrikh SV, Rutledge GC (2005) Electrospun poly (Styrene-bloch-dimethylsiloxane) block copolymer fibers exhibiting superhydrophobicity. Langmuir 21:5549–5554CrossRef Ma M, Hill RM, Lowery JL, Fridrikh SV, Rutledge GC (2005) Electrospun poly (Styrene-bloch-dimethylsiloxane) block copolymer fibers exhibiting superhydrophobicity. Langmuir 21:5549–5554CrossRef
23.
Zurück zum Zitat Yang S, Chen S, Tian Y, Feng C, Chen L (2008) Facile transformation of a native polystyrene (PS) film into a stable superhydrophobic surface via sol–gel process. Chem Mater 20:1233–1235CrossRef Yang S, Chen S, Tian Y, Feng C, Chen L (2008) Facile transformation of a native polystyrene (PS) film into a stable superhydrophobic surface via sol–gel process. Chem Mater 20:1233–1235CrossRef
24.
Zurück zum Zitat National Textile Centre (2003) National Textile Centre annual report. Hybrid polymer nanolayer for surface modification of fibers. Project number: M01-CL03 National Textile Centre (2003) National Textile Centre annual report. Hybrid polymer nanolayer for surface modification of fibers. Project number: M01-CL03
25.
Zurück zum Zitat Xue CH, Jia ST, Zhang J, Tian LQ, Chen HZ, Wang M (2008) Preparation of superhydrophobic surfaces on cotton textiles. Sci Technol Adv Mater 9:1–7 Xue CH, Jia ST, Zhang J, Tian LQ, Chen HZ, Wang M (2008) Preparation of superhydrophobic surfaces on cotton textiles. Sci Technol Adv Mater 9:1–7
26.
Zurück zum Zitat Hoefnagels HF, Wu D, de With G, Ming W (2007) Biomimetic superhydrophobic and highly oleophobic cotton textiles. Langmuir 23(26):13158–13163CrossRef Hoefnagels HF, Wu D, de With G, Ming W (2007) Biomimetic superhydrophobic and highly oleophobic cotton textiles. Langmuir 23(26):13158–13163CrossRef
27.
Zurück zum Zitat Liu Y, Chen X, Xin JH (2008) Hydrophobic duck feathers and their simulation on textile substrates for water repellent treatment. Bioinspir Biomim 3:1–8 Liu Y, Chen X, Xin JH (2008) Hydrophobic duck feathers and their simulation on textile substrates for water repellent treatment. Bioinspir Biomim 3:1–8
28.
Zurück zum Zitat Xu B, Cai Z (2008) Fabrication of a superhydrophobic ZnONanorod array film on cotton fabrics via a wet chemical route and hydrophobic modification. Appl Surf Sci 254:5899–5904CrossRef Xu B, Cai Z (2008) Fabrication of a superhydrophobic ZnONanorod array film on cotton fabrics via a wet chemical route and hydrophobic modification. Appl Surf Sci 254:5899–5904CrossRef
29.
Zurück zum Zitat Ji YY, Hong YC, Lee SH, Kim SD, Kim SS (2008) Formation of super-hydrophobic and water-repellency surface with hexamethyldisiloxane (HMDSO) coating on polyethyleneteraphtalate fiber by atmospheric pressure plasma polymerization. Surf Coat Technol 202:5663–5667CrossRef Ji YY, Hong YC, Lee SH, Kim SD, Kim SS (2008) Formation of super-hydrophobic and water-repellency surface with hexamethyldisiloxane (HMDSO) coating on polyethyleneteraphtalate fiber by atmospheric pressure plasma polymerization. Surf Coat Technol 202:5663–5667CrossRef
30.
Zurück zum Zitat Murace H, Fujibayashi T (1997) Characterization of molecular interfaces in hydrophobic systems. Prog Org Coat 31:97–104CrossRef Murace H, Fujibayashi T (1997) Characterization of molecular interfaces in hydrophobic systems. Prog Org Coat 31:97–104CrossRef
31.
Zurück zum Zitat 3M (1996) 3M technical data. Test method, water repellency test II—water/alcohol drop test. 3M, St. Paul 3M (1996) 3M technical data. Test method, water repellency test II—water/alcohol drop test. 3M, St. Paul
32.
Zurück zum Zitat 3M (1996) 3M technical data. Test methods, oil repellency test I. 3M, St. Paul 3M (1996) 3M technical data. Test methods, oil repellency test I. 3M, St. Paul
33.
Zurück zum Zitat Ramaratnam K, Tsyalkovsky V, Klep V, Luzinov I (2007) Ultrahydrophobic textile surface via decorating fibers with monolayer of reactive nanoparticles and non-fluorinated polymer. Chem Commun (43):4510–4512 Ramaratnam K, Tsyalkovsky V, Klep V, Luzinov I (2007) Ultrahydrophobic textile surface via decorating fibers with monolayer of reactive nanoparticles and non-fluorinated polymer. Chem Commun (43):4510–4512
34.
Zurück zum Zitat Avny Y, Rebenfeld L (1986) Chemical modification of polyester fiber surface by amination reactions with multifunctional amines. J Appl Polym Sci 32:4009–4025CrossRef Avny Y, Rebenfeld L (1986) Chemical modification of polyester fiber surface by amination reactions with multifunctional amines. J Appl Polym Sci 32:4009–4025CrossRef
35.
Zurück zum Zitat Naik SG, Bhat NV (1986) Structural and morphological studies of aminolysed poly (ethylene terephthalate) fibre. Polymer 27:233–240CrossRef Naik SG, Bhat NV (1986) Structural and morphological studies of aminolysed poly (ethylene terephthalate) fibre. Polymer 27:233–240CrossRef
36.
Zurück zum Zitat Zeronian SH, Collins MJ (1989) Surface modification of polyester by alkaline treatments. Text Prog 20(2):1–34CrossRef Zeronian SH, Collins MJ (1989) Surface modification of polyester by alkaline treatments. Text Prog 20(2):1–34CrossRef
37.
Zurück zum Zitat Gao L, McCarthy TJ (2006) Arteficial lotus leaf prepared using a 1945 patent and a commercial textile. Langmuir 22:5998–6000CrossRef Gao L, McCarthy TJ (2006) Arteficial lotus leaf prepared using a 1945 patent and a commercial textile. Langmuir 22:5998–6000CrossRef
38.
Zurück zum Zitat Holme I (2007) Innovative technologies for high performance. Textiles Color Technol 123:59–73CrossRef Holme I (2007) Innovative technologies for high performance. Textiles Color Technol 123:59–73CrossRef
39.
Zurück zum Zitat Popoola VA (1988) Polyester formation: aminolytic degradation and proposed mechanisms of the reaction. J Polym Sci 36:1677–1683 Popoola VA (1988) Polyester formation: aminolytic degradation and proposed mechanisms of the reaction. J Polym Sci 36:1677–1683
40.
Zurück zum Zitat Glasoe PK, Kleinberg J, Audrieth LF (1939) Acid catalysis in amines, II.Effect of various butylammonium salts on the aminolysis of ethyl phenylacetate in anhydrous n-butylamine. J Am Chem Soc 61:2387CrossRef Glasoe PK, Kleinberg J, Audrieth LF (1939) Acid catalysis in amines, II.Effect of various butylammonium salts on the aminolysis of ethyl phenylacetate in anhydrous n-butylamine. J Am Chem Soc 61:2387CrossRef
41.
Zurück zum Zitat Hall AJ (1966) Textile Finishing. London, Heywood Books, pp 135–210 Hall AJ (1966) Textile Finishing. London, Heywood Books, pp 135–210
42.
Zurück zum Zitat Inagaki N, Tasaka S, Mori K (1991) Hydrophobic polymer films plasma-polymerized from CF3/hydrocarbon and hexafluroacetone/ hydrocarbon mixtures. J Appl Polym Sci 43:581–588CrossRef Inagaki N, Tasaka S, Mori K (1991) Hydrophobic polymer films plasma-polymerized from CF3/hydrocarbon and hexafluroacetone/ hydrocarbon mixtures. J Appl Polym Sci 43:581–588CrossRef
43.
Zurück zum Zitat Yasuda T, Okuno T, Yoshida K (1988) A study of surface dynamics of polymers. II. Investigation by plasma surface implantation of fluorine-containing moieties. J Polym Sci B Polym Phys 26:1781–1794CrossRef Yasuda T, Okuno T, Yoshida K (1988) A study of surface dynamics of polymers. II. Investigation by plasma surface implantation of fluorine-containing moieties. J Polym Sci B Polym Phys 26:1781–1794CrossRef
Metadaten
Titel
Improvement in hydrophobicity of polyester fabric finished with fluorochemicals via aminolysis and comparing with nano-silica particles
verfasst von
Zahra Mazrouei-Sebdani
Akbar Khoddami
Shadpour Mallakpour
Publikationsdatum
01.06.2011
Verlag
Springer-Verlag
Erschienen in
Colloid and Polymer Science / Ausgabe 9/2011
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-011-2426-8

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