Skip to main content
Erschienen in: Journal of Materials Science: Materials in Electronics 24/2017

09.09.2017

Improving sensing sensitivity of Er/Yb co-doped NaYF4 nanorods via selecting non-thermally-coupled levels

verfasst von: Haoyue Hao, Hongyu Lu, Guanghong Ao, Yinglin Song, Yuxiao Wang, Xueru Zhang

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 24/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The temperature-dependent up-conversion luminescence of the Yb3+-Er3+ doped NaYF4:Er3+/Yb3+ nanorods, which can emit green, red and blue emissions, was investigated under 980 nm laser excitation. Our results showed that the natural log of I 520/I 550, I 654/I 550, I 520/I 407 and I 654/I 407 had well linear relationship with the reciprocal of temperature, suggesting their potential application in temperature measurement. At 471 K, the maximal sensing sensitivities of the above thermometry methods reached 0.007, 0.032, 0.6, 2.7 K−1, respectively. Moreover, the luminescence color shifted from green to yellow with the temperature increasing from 296 to 471 K. The calculated CIE coordinates varied linearly with the temperature, which also can be used in thermometry. These excellent properties make NaYF4:Er3+/Yb3+ nanorods an excellent candidate as a temperature sensor.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat V. Kumar Rai, Temperature sensors and optical sensors. Appl. Phys. B 88(2), 297–303 (2007)CrossRef V. Kumar Rai, Temperature sensors and optical sensors. Appl. Phys. B 88(2), 297–303 (2007)CrossRef
2.
Zurück zum Zitat H. Zheng, B. Chen, H. Yu, J. Zhang, J. Sun, X. Li, M. Sun, B. Tian, S. Fu, H. Zhong, R. Hua, B. Dong, Microwave-assisted hydrothermal synthesis and temperature sensing application of Er3+/Yb3+ doped NaY(WO4)2 microstructures. J. Colloid Interf. Sci. 420, 27–34 (2014)CrossRef H. Zheng, B. Chen, H. Yu, J. Zhang, J. Sun, X. Li, M. Sun, B. Tian, S. Fu, H. Zhong, R. Hua, B. Dong, Microwave-assisted hydrothermal synthesis and temperature sensing application of Er3+/Yb3+ doped NaY(WO4)2 microstructures. J. Colloid Interf. Sci. 420, 27–34 (2014)CrossRef
3.
Zurück zum Zitat X. Wang, Y. Wang, Y. Bu, X. Yan, J. Wang, P. Cai, T. Vu, H.J. Seo, Influence of doping and excitation powers on optical thermometry in Yb3+-Er3+ doped CaWO4. Sci. Rep. 7(43383), 1–9 (2017) X. Wang, Y. Wang, Y. Bu, X. Yan, J. Wang, P. Cai, T. Vu, H.J. Seo, Influence of doping and excitation powers on optical thermometry in Yb3+-Er3+ doped CaWO4. Sci. Rep. 7(43383), 1–9 (2017)
4.
Zurück zum Zitat M.K. Mahata, T. Koppe, K. Kumar, H. Hofsäss, U. Vetter, Demonstration of temperature dependent energy migration in dual-mode YVO4: Ho3+/Yb3+ Nanocrystals for low temperature thermometry. Sci. Rep. 6(36342), 1–11 (2016) M.K. Mahata, T. Koppe, K. Kumar, H. Hofsäss, U. Vetter, Demonstration of temperature dependent energy migration in dual-mode YVO4: Ho3+/Yb3+ Nanocrystals for low temperature thermometry. Sci. Rep. 6(36342), 1–11 (2016)
5.
Zurück zum Zitat H. Lu, H. Hao, G. Shi, Y. Gao, R. Wang, Y. Song, Y. Wang, X. Zhang, Optical temperature sensing in β-NaLuF4:Yb3+/Er3+/Tm3+ based on thermal, quasi-thermal and non-thermal coupling levels. RSC Adv 6(60), 55307–55311 (2017)CrossRef H. Lu, H. Hao, G. Shi, Y. Gao, R. Wang, Y. Song, Y. Wang, X. Zhang, Optical temperature sensing in β-NaLuF4:Yb3+/Er3+/Tm3+ based on thermal, quasi-thermal and non-thermal coupling levels. RSC Adv 6(60), 55307–55311 (2017)CrossRef
6.
Zurück zum Zitat M. Ding, D. Chen, C. Lu, J. Xi, Z. Ji, Z. Xu, Lanthanide-doped LuF3 mesocrystals for optical thermometry. Mater. Lett. 189, 5–8 (2017)CrossRef M. Ding, D. Chen, C. Lu, J. Xi, Z. Ji, Z. Xu, Lanthanide-doped LuF3 mesocrystals for optical thermometry. Mater. Lett. 189, 5–8 (2017)CrossRef
7.
Zurück zum Zitat Y. Yao, L. Luo, Q. Zuo, W. Li, J. Zhou, The ferroelectric, dielectric and up-conversion photoluminescence properties of ferroelectrics (0.99-x) PbTiO3-xPb(Yb1/2Nb1/2) O3-0.01 Pb (Er1/2Nb1/2)O3. J. Alloy. Compd. 673, 102–106 (2016)CrossRef Y. Yao, L. Luo, Q. Zuo, W. Li, J. Zhou, The ferroelectric, dielectric and up-conversion photoluminescence properties of ferroelectrics (0.99-x) PbTiO3-xPb(Yb1/2Nb1/2) O3-0.01 Pb (Er1/2Nb1/2)O3. J. Alloy. Compd. 673, 102–106 (2016)CrossRef
8.
Zurück zum Zitat L. Li, L. Zheng, W. Xu, Z. Liang, Y. Zhou, Z. Zhang, W. Cao, Optical thermometry based on the red upconversion fluorescence of Er3+ in CaWO4:Yb3+/Er3+ polycrystalline powder. Opt. Lett. 41(7), 1458–1461 (2016)CrossRef L. Li, L. Zheng, W. Xu, Z. Liang, Y. Zhou, Z. Zhang, W. Cao, Optical thermometry based on the red upconversion fluorescence of Er3+ in CaWO4:Yb3+/Er3+ polycrystalline powder. Opt. Lett. 41(7), 1458–1461 (2016)CrossRef
9.
Zurück zum Zitat L. Liu, F. Qin, T. Lv, Z. Zhang, W. Cao, Accurate thermometry based on the red and green fluorescence intensity ratio in NaYF4:Yb,Er nanocrystals for bioapplication. Opt. Lett. 41(20), 4664–4667 (2016)CrossRef L. Liu, F. Qin, T. Lv, Z. Zhang, W. Cao, Accurate thermometry based on the red and green fluorescence intensity ratio in NaYF4:Yb,Er nanocrystals for bioapplication. Opt. Lett. 41(20), 4664–4667 (2016)CrossRef
10.
Zurück zum Zitat H. Lu, H. Hao, Y. Gao, D. Li, G. Shi, Y. Song, Y. Wang, X. Zhang, Optical sensing of temperature based on non-thermally coupled levels and upconverted white light emission of a Gd2(WO4)3 phosphor co-doped with in Ho (III), Tm (III), and Yb (III). Microchim Acta 184(2), 1–6 (2017)CrossRef H. Lu, H. Hao, Y. Gao, D. Li, G. Shi, Y. Song, Y. Wang, X. Zhang, Optical sensing of temperature based on non-thermally coupled levels and upconverted white light emission of a Gd2(WO4)3 phosphor co-doped with in Ho (III), Tm (III), and Yb (III). Microchim Acta 184(2), 1–6 (2017)CrossRef
11.
Zurück zum Zitat G. Yi, H. Lu, S. Zhao, Y. Ge, W. Yang, D. Chen, L.H. Guo, Synthesis, characterization, and biological application of size-controlled nanocrystalline NaYF4:Yb, Er infrared-to-visible up-conversion phosphors. Nano Lett. 4(11), 2191–2196 (2004)CrossRef G. Yi, H. Lu, S. Zhao, Y. Ge, W. Yang, D. Chen, L.H. Guo, Synthesis, characterization, and biological application of size-controlled nanocrystalline NaYF4:Yb, Er infrared-to-visible up-conversion phosphors. Nano Lett. 4(11), 2191–2196 (2004)CrossRef
12.
Zurück zum Zitat M. Tsuda, K. Soga, H. Inoue, S. Inoue, A. Makishima, Effect of Yb3+ doping on upconversion emission intensity and mechanism in Er3+/Yb3+-codoped fluorozirconate glasses under 800 nm excitation. J. Appl. Phys. 86(11), 6143–6149 (1999)CrossRef M. Tsuda, K. Soga, H. Inoue, S. Inoue, A. Makishima, Effect of Yb3+ doping on upconversion emission intensity and mechanism in Er3+/Yb3+-codoped fluorozirconate glasses under 800 nm excitation. J. Appl. Phys. 86(11), 6143–6149 (1999)CrossRef
13.
Zurück zum Zitat J. Huang, B. He, Z. Cheng, L. Zhou, Upconverting PAAm/PNIPAM/NaYF4:Yb:Er hydrogel with enhanced luminescence temperature sensitivity. J. Lumin. 160, 254–257 (2015)CrossRef J. Huang, B. He, Z. Cheng, L. Zhou, Upconverting PAAm/PNIPAM/NaYF4:Yb:Er hydrogel with enhanced luminescence temperature sensitivity. J. Lumin. 160, 254–257 (2015)CrossRef
14.
Zurück zum Zitat A. Sedlmeier, D.E. Achatz, L.H. Fischer, H.H. Gorris, O.S. Wolfbeis, Photon upconverting nanoparticles for luminescent sensing of temperature. Nanoscale 4(44), 7090–7096 (2012)CrossRef A. Sedlmeier, D.E. Achatz, L.H. Fischer, H.H. Gorris, O.S. Wolfbeis, Photon upconverting nanoparticles for luminescent sensing of temperature. Nanoscale 4(44), 7090–7096 (2012)CrossRef
15.
Zurück zum Zitat X. Wang, T. Xu, P. Cai, T. Vu, H.J. Seo, Controlled synthesis, multicolor luminescence, and optical thermometer of bifunctional NaYbF4:Nd3+@NaYF4:Yb3+ active-core/active-shell colloidal nanoparticles. J. Alloy. Compd. 691, 530–536 (2017)CrossRef X. Wang, T. Xu, P. Cai, T. Vu, H.J. Seo, Controlled synthesis, multicolor luminescence, and optical thermometer of bifunctional NaYbF4:Nd3+@NaYF4:Yb3+ active-core/active-shell colloidal nanoparticles. J. Alloy. Compd. 691, 530–536 (2017)CrossRef
16.
Zurück zum Zitat M. Pollnau, D.R. Gamelin, S.R. Lüthi, H.U. Güdel, M.P. Hehlen, Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems. Phys. Rev. B 61(5), 3337 (2000)CrossRef M. Pollnau, D.R. Gamelin, S.R. Lüthi, H.U. Güdel, M.P. Hehlen, Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems. Phys. Rev. B 61(5), 3337 (2000)CrossRef
17.
Zurück zum Zitat D.T. Klier, M.U. Kumke, Upconversion NaYF4:Yb:Er nanoparticles co-doped with Gd3+ and Nd3+ for thermometry on the nanoscale. RSC Adv. 5(82), 67149–67156 (2015)CrossRef D.T. Klier, M.U. Kumke, Upconversion NaYF4:Yb:Er nanoparticles co-doped with Gd3+ and Nd3+ for thermometry on the nanoscale. RSC Adv. 5(82), 67149–67156 (2015)CrossRef
18.
Zurück zum Zitat W. Gao, H. Zheng, Q. Han, E. He, F. Gao, R. Wang, Enhanced red upconversion luminescence by codoping Ce3+ in β-NaY (Gd0.4)F4:Yb3+/Ho3+ nanocrystals. J. Mater. Chem. C 2, 5327–5334 (2014)CrossRef W. Gao, H. Zheng, Q. Han, E. He, F. Gao, R. Wang, Enhanced red upconversion luminescence by codoping Ce3+ in β-NaY (Gd0.4)F4:Yb3+/Ho3+ nanocrystals. J. Mater. Chem. C 2, 5327–5334 (2014)CrossRef
19.
Zurück zum Zitat J.F. Suyver, J. Grimm, M.K. Van Veen, D. Biner, K.W. Krämer, H.U. Güdel, Upconversion spectroscopy and properties of NaYF4 doped with Er3+, Tm3+ and/or Yb3+. J. Lumin. 117, 1–12 (2006)CrossRef J.F. Suyver, J. Grimm, M.K. Van Veen, D. Biner, K.W. Krämer, H.U. Güdel, Upconversion spectroscopy and properties of NaYF4 doped with Er3+, Tm3+ and/or Yb3+. J. Lumin. 117, 1–12 (2006)CrossRef
20.
Zurück zum Zitat B. Dong, R.N. Hua, B.S. Cao, Z.P. Li, Y.Y. He, Z.Y. Zhang, O.S. Wolfbeis, Size dependence of the upconverted luminescence of NaYF4:Er,Yb microspheres for use in ratiometric thermometry. Phys. Chem. Chem. Phys. 16(37), 20009–20012 (2014)CrossRef B. Dong, R.N. Hua, B.S. Cao, Z.P. Li, Y.Y. He, Z.Y. Zhang, O.S. Wolfbeis, Size dependence of the upconverted luminescence of NaYF4:Er,Yb microspheres for use in ratiometric thermometry. Phys. Chem. Chem. Phys. 16(37), 20009–20012 (2014)CrossRef
21.
Zurück zum Zitat D. Li, Q. Shao, Y. Dong, J. Jiang, Thermal sensitivity and stability of NaYF4:Yb3+, Er3+ upconversion nanowires, nanorods and nanoplates. Mater. Let. 110, 233–236 (2013)CrossRef D. Li, Q. Shao, Y. Dong, J. Jiang, Thermal sensitivity and stability of NaYF4:Yb3+, Er3+ upconversion nanowires, nanorods and nanoplates. Mater. Let. 110, 233–236 (2013)CrossRef
22.
Zurück zum Zitat S. Sinha, M.K. Mahata, K. Kumar, S.P. Tiwari, V.K. Rai, Dualistic temperature sensing in Er3+/Yb3+ doped CaMoO4 upconversion phosphor. Spectrochim Actra A 173, 369–375 (2017)CrossRef S. Sinha, M.K. Mahata, K. Kumar, S.P. Tiwari, V.K. Rai, Dualistic temperature sensing in Er3+/Yb3+ doped CaMoO4 upconversion phosphor. Spectrochim Actra A 173, 369–375 (2017)CrossRef
23.
Zurück zum Zitat M.K. Mahata, K. Kumar, V.K. Rai, Er3+-Yb3+ doped vanadate nanocrystals: a highly sensitive thermographic phosphor and its optical nanoheater behavior. Sens. Actuat. B-Chem. 209, 775–780 (2015)CrossRef M.K. Mahata, K. Kumar, V.K. Rai, Er3+-Yb3+ doped vanadate nanocrystals: a highly sensitive thermographic phosphor and its optical nanoheater behavior. Sens. Actuat. B-Chem. 209, 775–780 (2015)CrossRef
24.
Zurück zum Zitat Y. Yang, C. Mi, F. Yu, X. Su, C. Guo, G. Li, J. Zhang, L. Liu, Y. Liu, X. Li, Optical thermometry based on the upconversion fluorescence from Yb3+/Er3+ codoped La2O2S phosphor. Ceram. Int. 40(7), 9875–9880 (2014)CrossRef Y. Yang, C. Mi, F. Yu, X. Su, C. Guo, G. Li, J. Zhang, L. Liu, Y. Liu, X. Li, Optical thermometry based on the upconversion fluorescence from Yb3+/Er3+ codoped La2O2S phosphor. Ceram. Int. 40(7), 9875–9880 (2014)CrossRef
25.
Zurück zum Zitat Y. Chen, X.Y. Liu, G.H. Chen, T. Yang, C.L. Yuan, C.R. Zhou, J.W. Xu, Up-conversion luminescence and temperature sensing characteristics of Er3+/Yb3+ co-doped phosphate glasses. J. Mater. Sci. (2017). doi:10.1007/s10854-017-7454-9 CrossRef Y. Chen, X.Y. Liu, G.H. Chen, T. Yang, C.L. Yuan, C.R. Zhou, J.W. Xu, Up-conversion luminescence and temperature sensing characteristics of Er3+/Yb3+ co-doped phosphate glasses. J. Mater. Sci. (2017). doi:10.​1007/​s10854-017-7454-9 CrossRef
26.
Zurück zum Zitat S. Zhou, S. Jiang, X. Wei, Y. Chen, C. Duan, M. Yin, Optical thermometry based on upconversion luminescence in Yb3+/Ho3+ co-doped NaLuF4. J. Alloy. Compd. 588, 654–657 (2014)CrossRef S. Zhou, S. Jiang, X. Wei, Y. Chen, C. Duan, M. Yin, Optical thermometry based on upconversion luminescence in Yb3+/Ho3+ co-doped NaLuF4. J. Alloy. Compd. 588, 654–657 (2014)CrossRef
27.
Zurück zum Zitat V. Lojpur, M. Nikolic, L. Mancic, O. Milosevic, M.D. Dramicanin, Y2O3:Yb, Tm and Y2O3:Yb, Ho powders for low-temperature thermometry based on up-conversion fluorescence. Ceram. Inter 39(2), 1129–1134 (2013)CrossRef V. Lojpur, M. Nikolic, L. Mancic, O. Milosevic, M.D. Dramicanin, Y2O3:Yb, Tm and Y2O3:Yb, Ho powders for low-temperature thermometry based on up-conversion fluorescence. Ceram. Inter 39(2), 1129–1134 (2013)CrossRef
28.
Zurück zum Zitat S. Zheng, W. Chen, D. Tan, J. Zhou, Q. Guo, W. Jiang, C.X. Liu, J. Xu, Qiu, Lanthanide-doped NaGdF4 core-shell nanoparticles for non-contact self-referencing temperature sensors. Nanoscale 6(11), 5675–5679 (2014)CrossRef S. Zheng, W. Chen, D. Tan, J. Zhou, Q. Guo, W. Jiang, C.X. Liu, J. Xu, Qiu, Lanthanide-doped NaGdF4 core-shell nanoparticles for non-contact self-referencing temperature sensors. Nanoscale 6(11), 5675–5679 (2014)CrossRef
29.
Zurück zum Zitat Q. Zuo, L. Luo, Y. Yao, High dielectric, piezoelectric, upconversion photoluminescence and low-temperature sensing properties in Ba0.7Sr0.3TiO3-BaZr0.2Ti0.8O3:Ho/Yb ceramics. J. Electron. Mater. 45, 970–975 (2016)CrossRef Q. Zuo, L. Luo, Y. Yao, High dielectric, piezoelectric, upconversion photoluminescence and low-temperature sensing properties in Ba0.7Sr0.3TiO3-BaZr0.2Ti0.8O3:Ho/Yb ceramics. J. Electron. Mater. 45, 970–975 (2016)CrossRef
Metadaten
Titel
Improving sensing sensitivity of Er/Yb co-doped NaYF4 nanorods via selecting non-thermally-coupled levels
verfasst von
Haoyue Hao
Hongyu Lu
Guanghong Ao
Yinglin Song
Yuxiao Wang
Xueru Zhang
Publikationsdatum
09.09.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 24/2017
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-7803-8

Weitere Artikel der Ausgabe 24/2017

Journal of Materials Science: Materials in Electronics 24/2017 Zur Ausgabe

Neuer Inhalt