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Journal of Sol-Gel Science and Technology

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05.05.2020 | Original Paper: Functional coatings, thin films and membranes (including deposition techniques)

Influence of Ti doping on the microstructural and electrochromic properties of dip-coated nanocrystalline V₂O₅ thin films

verfasst von: Anil Kumar, P. P. Sahay

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2020

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Abstract

The nanocrystalline V₂O₅ thin films were prepared via a dip-coating method by controlled hydrolytic polycondensation of the vanadium (V) oxytriisopropoxide (VO(OC₃H₇)₃) in isopropanol. For Ti doping, titanium (IV) isopropoxide (Ti(OC₃H₇)₄) was used. The as-deposited films after thermal treatment at 500 °C under ambient air for 30 min were subjected to characterizations for their structural, morphological, and electrochromic properties. The X-ray diffraction (XRD) analyses of the films confirm an orthorhombic phase of vanadium pentaoxide (PDF # 41-1426), which is also supported by Fourier transform infrared (FTIR) analyses. The analyses of electrochromic properties of the films divulge that the 5 at% Ti-doped film has the fast switching time (coloration time: 0.59 s and bleaching time: 0.42 s), high net charge density and good electrochromic reversibility. The Nyquist impedance plots have been evaluated by fit and simulation analysis using Nova software, taking into account an equivalent electrical circuit model.

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Titel: Influence of Ti doping on the microstructural and electrochromic properties of dip-coated nanocrystalline V2O5 thin films
verfasst von: Anil Kumar
P. P. Sahay
Publikationsdatum: 05.05.2020
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 1/2020
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-020-05298-9

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