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2018 | OriginalPaper | Buchkapitel

Infrared Emission Properties of Cr3+-Doped NiAl2O4 Spinel Ceramics

verfasst von : Gang He, Jiaxi Liu, Xingxing Jiang, Jiangtao Li

Erschienen in: Advanced Functional Materials

Verlag: Springer Singapore

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Abstract

High infrared emissive NiAl2−xCrxO4 (x = 0, 0.1, 0.5, 1.0, 2.0) spinel ceramics were prepared by solid-state reaction method. The phase composition, microstructure, near infrared absorption and infrared emission properties of the prepared samples were investigated. With the addition of Cr3+, the samples maintained a spinel structure, and the grains grow to larger sizes. The absorptivity increased from 0.52 to 0.93 in the near infrared spectral region of 0.75–2.5 μm and the emissivity increased from 0.56 to 0.83 in the infrared spectral region of 3–5 μm with increasing Cr content. The band gap of NiAl2−xCrxO4 spinel ceramics decreased with increasing Cr content based on the calculation of the absorbance test results. The first-principles electronic structure calculations for NiAl2O4 and NiCr2O4 were performed. The high emissive spinel ceramics shows promising applications for energy-saving in high temperature thermal process equipment field.

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Metadaten
Titel
Infrared Emission Properties of Cr3+-Doped NiAl2O4 Spinel Ceramics
verfasst von
Gang He
Jiaxi Liu
Xingxing Jiang
Jiangtao Li
Copyright-Jahr
2018
Verlag
Springer Singapore
DOI
https://doi.org/10.1007/978-981-13-0110-0_68

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