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Journal of Materials Engineering and Performance

Erschienen in:

21.05.2018

Inhibiting Effect of Additives on Pressure Solution of Calcite

verfasst von: V. Traskine, Z. Skvortsova, G. Badun, M. Chernysheva, Ya. Simonov, I. Gazizullin

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 10/2018

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Abstract

The task of protection of cultural heritage requires a better understanding of combined effects of mechanical and chemical factors involved in environmental deterioration of monuments. The present paper deals with extending some known physicochemical methods proposed for inhibiting the decay of unstressed materials to their study during water-assisted deformation. The tests have been carried out on natural limestone samples and calcite powders in CaCO₃ saturated aqueous solutions under static loads causing measurable pressure solution creep. In the solutions containing 1-hydroxyethylidene-1,1-diphosphonic acid, nitrilotriacetic acid, or ethylenediaminetetraacetic acid, the creep rate decreases considerably with increasing concentration of additives. The extent of creep deceleration has been found to be proportional to the independently estimated calcite surface area occupied by adsorbed species. This fact enables us to discriminate the adsorption-induced effect from other variables controlling the pressure solution rate and may be used in screening of compounds able to minimize the environmental impact on marble and limestone objects undergoing mechanical stresses.

Vorheriger Artikel Effect of the Soldering Atmosphere on the Wettability Between Sn4.0Ag0.5Cu (in wt.%) Lead-Free Solder Paste and Various Substrates

Nächster Artikel On the Size Dependence of Molar and Specific Properties of Independent Nano-phases and Those in Contact with Other Phases

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Titel: Inhibiting Effect of Additives on Pressure Solution of Calcite
verfasst von: V. Traskine
Z. Skvortsova
G. Badun
M. Chernysheva
Ya. Simonov
I. Gazizullin
Publikationsdatum: 21.05.2018
Verlag: Springer US
Erschienen in: Journal of Materials Engineering and Performance / Ausgabe 10/2018
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-018-3413-8

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