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2016 | OriginalPaper | Buchkapitel

4. Insertion of CO₂ into E–X Bonds

verfasst von : Michele Aresta, Angela Dibenedetto, Eugenio Quaranta

Erschienen in: Reaction Mechanisms in Carbon Dioxide Conversion

Verlag: Springer Berlin Heidelberg

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Abstract

This chapter deals with the “insertion” reactions of carbon dioxide (CO₂) into E–X bonds, where E and X represent several different (sets of) atoms, such as M–H, M–OH, M–C, M–OR, M–O₂, M–N, M–P, C–C, C–N, Si–H, and M–M (M = metal). Such reactions are relevant to catalysis for the formation of new bonds in which CO₂ may be implied (C–C bonds or C–E bonds) and thus to the conversion of CO₂ into added-value chemicals. The insertion product can be thermodynamically and kinetically stable or labile, offering in the latter case the opportunity of a catalytic path.

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Vorheriges Kapitel Interaction of CO2 with Electron-Rich Moieties

Nächstes Kapitel Interaction of CO2 with C–C Multiple Bonds

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Titel: Insertion of CO2 into E–X Bonds
verfasst von: Michele Aresta
Angela Dibenedetto
Eugenio Quaranta
Verlag: Springer Berlin Heidelberg
Buch: Reaction Mechanisms in Carbon Dioxide Conversion
Print ISBN: 978-3-662-46830-2

Electronic ISBN: 978-3-662-46831-9

Copyright-Jahr: 2016
DOI: https://doi.org/10.1007/978-3-662-46831-9_4

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